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Register a new userDetermination of lead and cadmium concentration in some protected and unprotected agricultural products
تحديد تركيز الرصاص و الكادميوم في بعض المنتجات الزراعية الساحلية المحمية و غير المحمية
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أحمد طاهر أحمد( باحث )
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تم تحديد تركيز الرصاص و الكادميوم في عدد من المنتجات الزراعية المحمية و غير المحمية (بندورة، و فليفلة، و ملفوف، و بقدونس) بهدف مقارنة قدرتها على تجميع هذين العنصرين، و ذلك بسبب كون هذه المزروعات متأثرة بالأنشطة البشرية و الصناعية. بعد جمع العينات تم تهضيمها بوساطة حمض الآزوت، و من ثم الكشف عن الرصاص و الكادميوم باستخدام تقنية الامتصاص الذري. أظهرت النتائج أن تراكيز هذين العنصرين في العينات المتأتية من الزراعات المحمية أقل من تلك المتأتية من الزراعات غير المحمية كون تلك الأخيرة معرضة مباشرة لتلوث الهواء الجوي، مما يزيد من إمكانية تراكمها في تلك المزروعات، كما أظهرت النتائج أن تركيز الرصاص في العينات كافة أعلى من تركيز الكادميوم، و هي ضمن الحدود الطبيعية في نوع كهذا من المنتجات الزراعية.
In this study, the concentration of Pb and Cd was determined in some agricultural products in order to compare this concentration and to know the capacity of these products to accumulate these two elements. The samples were digested by nitric acid and the elements were determined by the atomic absorption spectroscopy. The results showed that the concentration of lead and cadmium in protected products was less than the concentration in unprotected products, and the concentration of lead was more than the cadmium, these results can be explained by the extensive use of lead and the unprotected agriculture products were exposed to the air pollution more than the protected products.
References used
STANLEY, E. M. Environmental chemistry. 7th. ed., CRC press LLC, New York & London , 2000 ,876
ISSAEV, L. K. Control of chemical and biological environmental parameters. St- Petersburg (1998), 852 pp
Glantz, M. H. Climate Affairs- A primer. , Island Press, Washington & London, 2003, 291
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This study estimated the levels of lead and cadmium in 12 chocolate and cocoa
samples from latakia markets by atomic absorption spectrometry . Most of the samples,
were well known Syrian trademarks.
The results showed that concentration of lead in
samples of dark chocolate ranged
between 0.061 and 0.49 mg\ kg ,and in samples of cocoa between 0,10 and 0,51 mg\ kg,
but it was much less 0.01 - 0. 16 mg\ kg in white chocolate and Imported chocolates.
concentration of cadmium in samples of dark chocolate ranged between 0.01 and 0.24 mg\
kg and in samples of cocoa between 0.03 and 0.231 mg\ kg. but it was also less in white
chocolate and imported chocolates 0.01 - 0.051 mg\ kg.
The results indicated that dark chocolates have higher concentrations of lead and
cadmium than white chocolates and that the levels of lead and cadmium are generally
higher than the common levels in developed countries ,and thus. might be a significant
source of lead and cadmium ingestion, Raw materials should be checked before use for
metal contents in order to decrease the concentrations of these metals in final chocolate
products..
The aim of the present study was to determine the levels of lead and cadmium in the
meat, liver and kidney of sheep exposed in the local markets of the city of Latakia, and to
compare the results with those reported by other countries and with the
maximum
acceptable levels for human consumption, Lead and cadmium were determined by atomic
absorption spectrometry (AAS).
The mean concentrations of lead in meat, liver and kidney were 0.043, 0.284 and
0.118 mg/kg fresh weights, respectively, while mean concentrations of cadmium were
0.017, 0.173 and 0.252 mg/kg fresh weights, respectively. Statistical analysis showed a
significant difference in lead and cadmium concentrations between liver and kidney and in
meat.
Carried out a laboratory experiment in order kinetics study of adsorption
of cadmium and lead in the soil, using soil columns experiment, with the
use of concentration 26.25 mg / l for cadmium, and 27.81 mg / l for lead,
and two degrees of pH 5.5, 0.7, with the use of five parameters.
The study investigated the possibility of removing heavy metal ions (Cd, Pb) from
aqueous solutions using adsorption method on the citrus peel (orange), which is a solid
waste available in abundance especially in the Syrian coast as well as easy to
use at low
cost. The optimal conditions for the simultaneous adsorption of the ions (Cd 2+, Pb 2+) on
the surface of orange peel (dry, soft) were determined.The concetration of ions was
determined using (DPASV) method Which is characterized by Sensitivity and high
accurawcy. The results showed that the optimum adsorption conditions were at pH = 5 ,
equleibrium time = 60 min, and the initial concentration is ( C0 = 50-200) ppm,The
application of the Langmuir and Frienlish models showed that Frienlish model is best fited
for expressing the adsorption of Pb ions on the surface of dry and soft orange peel and for
expressing the adsorption of Cd ions on the surface of soft orange peel , Langmuir model
is best fited for expressing the adsorption of Cd ions on the surface of dry orange peel.
The method applied its selected terms to realistic samples of processed and industrial
waste water, which showed a unique response as a purification method for the water
media.
A total of 294 samples of raw-unpasteurized bovine milk and variety of
dairy products (hard cheese, sweet cheese, cream cheese and cream), were
collected from local markets in Lattakia city as well as 44 samples of used water
(clear potable water
collected before used in cheese preparing processes) and
preserving water (turbid water collected from hard cheese preserving tanks).
All samples were analyzed for E.coli O157: H7 detection.
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