Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userContribution in the removal Lead and Copper from industrial water by using natural Phosphate of Syria
مساهمة في إزالة الرصاص و النحاس من المياه الصناعية باستخدام الفوسفات الخام السورية
1544
1 19
0
(
0
)
Created by
Shamra Editor
Ask ChatGPT about the research
درست تغيرات معامل توزع الرصاص و النحاس في منظومة ذات طورين [سائل (مياه ملوثة بالرصاص و النحاس) - صلب (فوسفات خام سورية )] و ذلك بتابعية العوامل التالية زمن خلط الطورين, الحجم الحبيبي للطورالصلب, تغير قيم الأس الهيدروجيني PH, تركيز العنصر الملوث, تركيز عنصر الكالسيوم كعنصر منافس للمواقع المتاحة على الطور الصلب, النسبة v/m كنسبة تمثل حجم الطور المائي على كتلة الطور الصلب. تراوحت نسبة إزالة الرصاص من عينات المحاليل المائية المحضرة مخبريا ﹰ91,57-99,95 % و كانت أفضل الشروط للحصول على أعلى نسبة إزالة للرصاص كالتالي: درجة حموضة تتراوح بين 6,63-10,11 و زمن خلط للطورين يصل إلى 60m و بنسبة V/m تبلغ .1000 و تراوحت نسبة إزالة النحاس من عينات المحاليل المائية المحضرة مخبرياﹰ -95,27 99,96% و كانت أفضل الشروط للحصول على أعلى نسبة إزالة للنحاس كالتالي: درجة حموضة تتراوح بين 7,89-11,01 و زمن خلط للطورين يصل 60m و بنسبة V/mتبلغ.1000 جرى تطبيق الشروط المثالية التي تم الحصول عليها مخبرياﹰ على عينات مأخوذه من مياه الدخل لوحدة المعالجة في شركة مصفاة بانياس و مياه دريناج مأخوذه من الشركة السورية لنقل النفط فكانت نسبة الإزالة للرصاص ( (100%,99 % و كانت نسبة إزالة النحاس ( (100%,98 % .
The changes in coefficient of distribution of lead and cupper has been studied in system with two phases, liquid water contaminated with lead and copper-solid (natural Phosphate of Syria) correlation of the following factors: Time of mixing phases, size of the developed steel ,change the values of PH ,concentration of elemental lead and concentration of element capper ,the concentration of calcium as a competitor to the occupation of sites available on the solid phase, the ratio V\m presents the water phase size on the mass of phase ,the Percentage removal of lead from aqueous samples prepared in the laboratory91,57-99,95% were the best conditions for a vast proportion removed can be summarized as follows: PH=[6,63-10,11], Time of mixing phases =60 minutes and V/m=1000. The Percentage removal of copper from aqueous samples prepared in the laboratory 95,27 -99,96 % were the best conditions for a vast proportion removed can be summarized as follows: PH= [7,89-11,01] , Time of mixing phases =60 minutes and V/m=1000. Ideal conditions have been applied that were obtained according to laboratory tests on water samples from industrial input to Banias refinery and water samples from industrial drainage to Syrian company for oil transport after Removal for lead was( 100%,99 %). Removal for copper was( 100%,98 %) .
References used
Saxena,S;Souza, S.F. D. Heavy Metal Pollution Abatement Using Rock Phosphate Mineral. Heavy metal pollution using Founder’s Day Special Issue, 2005 ,94- 99
Sarioglu,M; Atay,U.A.Removal of copper from aqueous solution by phosphate rock .Desalination181,2005,303-311
Mouflih,M;Aklil,A. Removal of lead from aqueous solution by naturalphosphate Hydrometallurgy 81,2006, 219-225
rate research
Read More
The study was carried out on the sorption of heavy metals (Pb+2, Zn+2) under static
conditions from single- and multicomponent aqueous solutions by Syrian Zeolite mineral
extracted from south Syria. The removal has an ion-exchange nature and consis
ts of three
stages: the adsorption on the surface of microcrystals, the inversion stage, and the
moderate adsorption in the interior of the microcrystal, The study showed that equilibrium
time is 6 hours, and The slight difference between adsorption capacity of the Zeolite
toward lead, zinc from single- and multicomponent solutions may testify to individual
sorption centers of the zeolite for each metal. The maximum sorption capacity toward pb2+
is determined as 33.89 mg/g at an equilibrium concentration of 261.07 mg/L and toward
Zn+2 as 29.18 mg/g at 309.818 mg/L. Langmuir and Freundlich Adsorption Isotherms
were used to evaluate natural zeolite adsorption performance for Lead, Zinc. These
Isotherms were able to provide suitable fit with experimental data, the factor R2 ranged
between 0.95 – 0.99, with better fit to Langmuir Isotherm.
Studied the distribution coefficient of elemental copper and lead contaminants in the aqueous phase using a Bi-phase system: solid phase (the sands of Palmyra) and liquid phase (water containing the former two elements), where they were sampling sand
samples from different regions in Palmyra to investigate for possible use as an adsorbent for elemental copper the lead from contaminated water, and after adjustment for certain transactions from time mixing phases, granular size, concentration of hydrogen ions, the concentration of the contaminated ingredient, the concentration of rival element (calcium) in addition to the ratio v / m in order to get the best rate for removal of these elements. The removal rate of copper componentamounted to 99.9% using four sites samples of sand a Palmyra, (al qareaten - the third leg to pump crude oil T3 - Alhl field - the valley between Mount aldahek and Sokhna) For lead removal ratio stood at 76.35% for the qareaten and 87.75% of the station the third to pump crude oil and 95 0.0% of the field Alhl and 96.25% of the valley between Mount aldahek and Sukhna. The application of the conditions that we have obtained in the laboratory to industrial water samples from the water income for the unity of treatment in Banias refinery and Water Company Drinaj of the Syrian Company for Oil Transport and the ratio of the removal of lead in the four samples ranging from ( 97.79 - 100)% for water Banias Refinery Company ranged between (83.89 - 88.08)% for water Syrian Company for Oil Transport, while the percentage of removal of the copper in the four samples ranging from (96.52 - 99.37)% for water Banias refinery Company and ranged ratio remove copper from the Syrian Company for Oil Transport water between (82.66 - 96.28)% in four samples.
This study aims to use the ash formed from the burning of firewood and the different
pruning residues to remove the hardness of water
Soda ash was characterized using different techniques, including XRD,flame
spectroscopy , volume titration and ot
hers.
These methods aim to determine the composition of the ash and the components
which are contributing to the removal process.
The optimum mixing time was determined using certain amount of soda ash to the
hard water and the water hardness was determined in the rang of time (0.5, 1, 2, 3, 4 and
5h) where the ideal time was 3 hours.
The removal ratios were determined when the mixing time of the two phases was 3
h, and adding directly the following quantities of ash (0.5,1,2,3,5,7,10,15,20,25) g to 200
ml of highly hardened water. The removal rate was increased by increasing the amount of
added ash. The removal rate was approximately 50% when 1 g of ash was used and the
complete removal rate of 100% was achieved when the amount of ash was 25 g.
studied the elimination of lead using natural zeolite by studding the the best
conditions to removal lead in a system with two phase: liquid (contaminated water with
lead)-solid (natural zeolite), correlation of the following factors: time of mixin
g phase,
granular size of solid phase, change of pH values, concentration of the calcium element as
a competitor element for the available sites for occupation on the solid phase, the ratio V/m
represents the size of the aqueous phase to the mass of the solid phase and concentration of
lead element.
On the other hand, the possibility of using natural zeolite as a template for storaging
dangerous materials such as lead, has been studied by changing water quality, pH and
temperature.
The results of this research show that and under the following experimental
conditions: time of mixing=4hour, mix of granular size of solid phase, pH< 8,
concentration of calcium = 20 ppm,V/m=100 and concentration of lead = 1000 ppm , the
rate of lead removal range from 60% to 99%.
On the other hand, the results of this research show that changing water quality has
no impact on the ability of natural zeolite for storaging lead as a hazardous waste, while
pH changes have minor effects on this ability of retention and an effect for the high
temperatures on the template was also observed.
The study was carried out to remove of heavy metals (V+5, Ni+2)
under static conditions from aqueous solutions by Syrian Zeolite
mineral extracted from south of Syria. The results revealed that
operational conditions such as initial solution pH and concentration,
adsorbent particle size, the presence of competing cations, are able
to affect the adsorption capacity and efficiency of natural zeolite.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
