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Register a new userChemical Inhibition for Steel Corrosion In Acidic Media, Using Vanillin
التثبيط الكيميائي لتآكل الحديد في الوسط الحمضي باستخدام الفانيلين
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درس في هذا البحث تثبيط تآكل حديد الترانسمسيون Transmission في محلول 1M HCl بوجود الفانيلين في درجات الحرارة (20-30-40-50-60) عند تراكيز ضمن المجال (ppm (500-100 لمدة ساعتين باستخدام طريقة الانخفاض في الوزن .
The corrosion inhibition of transmision steel in 1M HCl solution in the presence of Vanillin at temperature (20,30,40,50,60)°C at concentration between (100-500) ppm for two hours were studied using weight loss method.
Artificial intelligence review:
Research summary
تناول البحث دراسة تثبيط تآكل الحديد في وسط حمضي باستخدام الفانيلين كمثبط. تم استخدام طريقة الانخفاض في الوزن لتحديد معدل التآكل في محلول حمض الهيدروكلوريك بتركيز 1M عند درجات حرارة مختلفة (20-60 درجة مئوية) وتركيزات مختلفة من الفانيلين (100-500 جزء في المليون) لمدة ساعتين. أظهرت النتائج أن كفاءة التثبيط تزداد بزيادة تركيز الفانيلين ودرجة الحرارة، حيث بلغت الكفاءة العظمى حوالي 87% عند درجة حرارة 60 درجة مئوية وتركيز 500 جزء في المليون. تم حساب المعايير التنشيطية لعملية التآكل مثل طاقة التنشيط، تغير الأنتالبية، وتغير الأنتروبية، وأظهرت النتائج أن امتزاز الفانيلين يتبع قانون لانغميور. خلصت الدراسة إلى أن الفانيلين يمكن استخدامه كمثبط فعال لتآكل الحديد في الأوساط الحمضية، وأنه يمتاز بكونه مادة صديقة للبيئة وغير سامة.
Critical review
دراسة نقدية: تعتبر هذه الدراسة مهمة في مجال حماية المعادن من التآكل، حيث تقدم حلاً بيئيًا واقتصاديًا باستخدام الفانيلين كمثبط لتآكل الحديد. ومع ذلك، يمكن توجيه بعض النقد البناء للدراسة. أولاً، لم يتم التطرق إلى تأثير الفانيلين على أنواع أخرى من المعادن، مما يحد من تطبيق النتائج على الحديد فقط. ثانيًا، لم يتم دراسة تأثير الفانيلين على المدى الطويل، حيث أن التآكل عملية مستمرة وقد تتغير كفاءة التثبيط بمرور الوقت. ثالثًا، كان من الممكن تحسين الدراسة بإجراء تجارب في ظروف بيئية مختلفة مثل وجود شوائب أو ملوثات في الوسط الحمضي. وأخيرًا، يمكن أن تكون الدراسة أكثر شمولية إذا تم مقارنة الفانيلين بمثبطات أخرى مستخدمة في الصناعة لتحديد مدى تفوقه أو نقصه.
Questions related to the research
-
ما هي الطريقة المستخدمة في الدراسة لتحديد معدل تآكل الحديد؟
استخدمت الدراسة طريقة الانخفاض في الوزن لتحديد معدل تآكل الحديد.
-
ما هي أعلى كفاءة تثبيط تم الوصول إليها في الدراسة؟
أعلى كفاءة تثبيط تم الوصول إليها كانت حوالي 87% عند درجة حرارة 60 درجة مئوية وتركيز 500 جزء في المليون من الفانيلين.
-
ما هو القانون الذي يتبعه امتزاز الفانيلين على سطح الحديد؟
امتزاز الفانيلين على سطح الحديد يتبع قانون لانغميور.
-
ما هي المعايير التنشيطية التي تم حسابها في الدراسة؟
تم حساب طاقة التنشيط، تغير الأنتالبية، وتغير الأنتروبية كمعايير تنشيطية في الدراسة.
References used
POPOV B, 2015 Evaluation of corrosion Corrosion Engineering ,Elsevier B.V. , Columbia , 1-28
POPOV B, 2015. Thermodynamics in the Electrochemical Reactions of Corrosion, Corrosion Engineering ,Elsevier B.V. , Columbia , 29
FARHAN A , et al. , 2014 A Study Of Corrosion Behavior Of Low Carbon Steel In Acidic And Basic Washing Water Of Crude Oil Solution At Different Temperatures J. Baghdad for Sci,Vol.11(4) , 1510-1518
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concentration between (10-6- 10-4) M for two hours were studied
using weight loss method.
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that were subjected to the area during the research, representing by
rainfall precipitation in
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This study founds an increasing in the salinity values in the Al- Bassa coastal area of
summer in 2014, ranging between(665.6-6432mg/l)after increasing daily pumping rates, in
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between 490-950 mg / l. The geochemistry of Na/Cl indicates values less than 0.84 in
most water samples during the summer, while in autumn this percentage was higher than
0.84 in most samples ,to be an indicator for marine water.
Marfona cultivar were chemical mutagen using 20, 30 and 40 mM of Ethyl Methane
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tuberosum L.) tolerance to salinity. Plants Marfona mutagen from M5 and unmutagen were
cultured with Spunta and Falouka Cvs in 2015. Plants were later subjected to another
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with unmutant for Marfona, Spunta and Falouka in plant height varied from 68 to 41 cm
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cm and leaf area varied from 235 to 84 cm2. However, produced tubers number varied
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The Inula ext
racts were choosen as a plant inhibitor to cover the iron samples and
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The best conditions for (Inula-seawater) extract were : (PH=7 , time =24 hours ,
concent ration = 10%).
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the treatment and after it were as follows:
The velocity of the corrosion in the iron samples (before the treatment with the
extract) in 120 days:
- in the laboratory tanks was 0.78 mg/cm2 .day, but after the treatment was 0.23
mg/cm2.day
-in the drizzle area was 0.80 mg/cm2.day, but after the treatment was 0.47
mg/cm2.day
-in the waves area was 0.75 mg/cm2.day , but after the treatment was 0.41
mg/cm2.day
- in the depth area was 0.79 mg/cm2.day , but after the treatment was 0.21
mg/cm2.day.
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