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In this paper samples of poly vinyl chloride PVC ,pure, irradiated with Gama rays, were prepared by casting method in room temperature and light, and under atmosphere pressure. It was observed from this research that irradiation made real effect on some of the studied optical properties, the irradiation increased the transmittance while the electronic transitions kind remained indirect before and after the irradiation.
CdTe Thin films were deposited on glass substrates by thermal evaporation method. The geometric thickness was calculated using interferometric method based on reflectance curve recorded with the spectrophotometer. The XRD analysis and optical char acterizations of CdTe films with different optical thicknesses reveals that the structure of the films is polycrystalline with preferential orientation (111). The structure constant (a), crystallite size (D), dislocation density (δ) and strain (ε) were calculated, and it is observed that the crystallite size increases but micro-strain and dislocation density decreases with increases in thin film thickness. The overall absorbance has been increased with the film thickness and the direct band gap was obtained. It decreases with the increase in the thickness of the films.
In this paper we present the preparation of PbS nanocrystalline thin films using Chemical Bath Deposition (CBD) technique. We have performed this work in order to study the photoconductivity of PbS semi-conductor thin films. The details of the pre paration method are described. Thickness of deposited films has been determined using mechanical and optical methods. From the optical absorption measurements we have determined the band gap values. Using the first approximation parabolic bands model and the obtained values of band gaps, we have determined the size of PbS nanocrystallites. Also, we have investigated the electrical and photoelectrical behaviors of the PbS films. Our study shows that the size of PbS thin films nanocrystallites affects the photoconductive properties of the material. Furthermore, investigations show that there are two different sizes of grains located in two different layers, the first one, with grain’s size of about 25nm, concerns the part of PbS deposited directly on the glass substrate and the second layer, with grain’s size of about 70nm, concerns the PbS deposited on the first layer.
CdTe Thin films were deposited on silicon substrates by thermal evaporation method. The geometric thickness was calculated using interferometric method based on reflectance curve recorded with the spectrophotometer. The Reflection of High-Energy E lectron Diffraction (RHEED) patterns and XRD analysis reveals that the structure of the films are polycrystalline with preferential orientation (111). The structure constant (a), crystallite size (D), dislocation density (δ) and strain (ε) were calculated, and it is observed that the crystallite size increases but micro-strain and dislocation density decreases with increases in thin film thickness. The composition of the samples was determined by Energy Dispersive X-ray Analysis (EDX) and it is found that the wt.% of Cd increases and the wt.% of Te decreases with the increases of film thickness due to the re-evaporation of Te.
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