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Register a new userPreparation and Caractarization Of Silica Aerogel By Using Sol-gel method
تحضير و دراسة بنيوية لإيروجل أكسيد السيليسيوم بطريقة sol-gel
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تم في هذا العمل تحضير عدة عينات من أكسيد السيليسيوم على شكل كسيروجل اويروجل بدءاً من مواد أولية مختلفة و باعتماد طرق مختلفة للتجفيف. حيث حضر جزء من العينات باستخدام سيليكات الصوديوم المائية (الماء الزجاجي) كمادة أولية و هي مادة اقتصادية رخيصة الثمن، بينما حضرت العينات الباقية باستخدام تترا إيتوكسي سيلان.
During this study, various types of silicon oxide were prepared as aerogel and xerogel using multiple precursors and different drying technics. Some of these samples were prepared from Sodium silicate (waterglass) Na2SiO3 as a precursor which is a cheap material, while others were prepared using tetraethoxysilane (TEOS).
References used
G.M. Pajonk, Aerogel Catalysts: Applied Catalysis, 72 (1991) 217-266
S. Bhagat, Y. Kim, K. Suh, Y. Ahn, J. Yeo and J. Han, "Superhydrophobic silica aerogel powders with simultaneous surface modification, solvent exchange and sodium ion removal from hydrogels", Microporous and Mesoporous Materials, vol. 112, no. 1-3, pp. 504-509, 2008
H. Liu, W. Sha, A. Cooper and M. Fan, "Preparation and characterization of a novel silica aerogel as adsorbent for toxic organic compounds", Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 347, no. 1-3, pp. 38-44, 2009
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In this research, several samples of silicon oxide were prepared in the form of aerogel and xerogel, starting from different raw materials and using different drying methods. Where a part of the samples was prepared using aqueous sodium silicate (gla
ss water) (Na2SiO3) as a raw material, which is an economical and cheap material, while the rest of the samples were prepared using tetraethoxysilane (TEOS). Some of these samples were surface modified before drying using Trimethylchlorosilane, which is high Price (TMCS) by replacing the surface silanol groups (Si-OH) with alkyl. As for the remaining samples, which were prepared without surface modification, we succeeded in obtaining aerogel with a lower preparation cost and very close characteristics to the samples prepared by surface modification.
The Xerogel alumina catalyst was prepared by sol-gel
method in non-aqueous milieu, and the aerogel alumina
catalyst was prepared in the same method but it was dried at
by supercritical conditions. These catalysts were characterized
by XRD, BET, a
nd chemical adsorption methods. The
obtained results were compared to show the effect of
preparation process on the structural properties of the alumina.
Besides these results were compared with some oxides
supported on alumina, and the effect of distribution of these
oxides on the properties of alumina was investigated too.
Surface protective thin layers of high temperature oxidation resistant aluminum
oxide Al2O3, have been prepared by the sol-gel processing, using the spin coating
method. In order to increase layer thickness, corundum suspension was added to
the al
umina sol.
Phenol derivatives have been reacted with aryl halides under
heterogeneous basic catalyst (Amberlyst-21) using 5 mol% Cu(I)
Complex as catalyst, [CuClPPh3]4. The typical reaction has been
performed between p-cresol and bromobenzene. This reaction
is
achieved in o-xylene as solvent. However, the catalyst complex
does not dissolve in toluene rather it acts as heterogeneous catalyst.
Therefore, it is filtrated at the end of the reaction and reused several
times. Accordingly, new compounds were prepared by reacting one
of the bromoaryl derivatives with paracetamol. It is anticipated that
the synthesized compounds may have pharmaceutical application as
non-steroidial anti-inflammatory drugs (NSAIDs).
الهدف من البحث:
تصميم و تنفيذ منظومة توضيع بالترذيذ فوق الصوتي باستعمال جهاز ترذيذ منزلي
لتوليد الرطوبة، بغية الحصول على حمُسات كيميائية بوليميرية ذات بنى نانوية بدءاً من
مُلول البولي بيرول الناقل المصطنع بالأكسدة الكيميائية وفق نسب مولية مختلفة.
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