Fixed bed adsorption columns packed with natural zeolite were used to study the
kinetics of heavy metals removal from the single component solutions of Vanadium, Nikle,
Zinc, and Lead. The system parameters studied include solution flow rate and be
d height.
The effect of competing cations was also studied to establish the effectiveness of natural
zeolite in treating Industrial wastewater under continuous conditions using fixed bed
columns. The metal loaded natural zeolite was regenerated using NaCl . The results from
column studies showed that the Slower flow rates gave better removal efficiencies
compared to faster ones, Longer bed heights also resulted in greater adsorption
efficiencies. The bed depth service time (BDST) model was successfully used to simulate
experimental results at 30 % breakthrough. This model provides the necessary parameters
needed for fixed bed column design, the factor R2 ranged between 0.91 – 0.95. Natural
zeolite was exposed to 3 cycles of adsorption and desorption. The efficiency of the column
in removing heavy metals was high, The results indicate that natural zeolite can be
regenerated and re-used in removing heavy metals from solution.
The study was carried out on the sorption of heavy metals (Pb+2, Zn+2) under static
conditions from single- and multicomponent aqueous solutions by Syrian Zeolite mineral
extracted from south Syria. The removal has an ion-exchange nature and consis
ts of three
stages: the adsorption on the surface of microcrystals, the inversion stage, and the
moderate adsorption in the interior of the microcrystal, The study showed that equilibrium
time is 6 hours, and The slight difference between adsorption capacity of the Zeolite
toward lead, zinc from single- and multicomponent solutions may testify to individual
sorption centers of the zeolite for each metal. The maximum sorption capacity toward pb2+
is determined as 33.89 mg/g at an equilibrium concentration of 261.07 mg/L and toward
Zn+2 as 29.18 mg/g at 309.818 mg/L. Langmuir and Freundlich Adsorption Isotherms
were used to evaluate natural zeolite adsorption performance for Lead, Zinc. These
Isotherms were able to provide suitable fit with experimental data, the factor R2 ranged
between 0.95 – 0.99, with better fit to Langmuir Isotherm.
The study was carried out to remove of heavy metals (V+5, Ni+2)
under static conditions from aqueous solutions by Syrian Zeolite
mineral extracted from south of Syria. The results revealed that
operational conditions such as initial solution pH and concentration,
adsorbent particle size, the presence of competing cations, are able
to affect the adsorption capacity and efficiency of natural zeolite.
This study aims to determine the concentrations of some heavy metals that are present in the crude oil and in liquid waste of the crude oil desalting unit .The extraction method (liquid-solid) is used for concentrating and extraction these compounds
from the
saltwater samples .Samples were collected from the unit’s discharging points and from the subsequent treatment stages .A suitable analytical method was used to extract these metals
from both of crude oil and the oil refineries᾿ liquid wastes.
The objective of this study is to observe the fate of these wastes from the discharging points of desalting unit and through physical – chemical – biological treatment stages and dawn to the receiving water (Mediterranean sea). The results showed that Syrian crude oil contains a combination of heavy metals which includes : (Vanadium – Nickel – Iron – Zinc – Manganese – Copper – Cadmium – Lead - Chromium and Cobalt) .Vanadium showed the highest concentration followed by Nickel and Iron subsequently ,the total efficiency of the treatment plant achieved the following efficiencies : 41.06% (Vanadium), 44.92% (Nickel) and 39.34% ( Iron) ,then the concentration of these discharges where compared with those in marine system to show the possible adverse effects of these compounds on the surrounding biosphere.
