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This research study the effect of the proportion of the media (water - alcohol ) to determine where the arsenic used alcohol ( methanol _ ethanol _ propanol ) Using a Potentiometric method. It conducted the calibration process for the specific size o f the solution studied a specific size of the standard solution of iodine Using a Potentiometric method , after the application of analytical conditions and technical optimal to determine arsenic , and then we studied the effect of mixing ratio on the detection limit for arsenic in mixed media (water _ Alcohol ) . The study showed that the value of the detection limit of arsenic vary with the type of alcohol used and accounted for in the reaction medium , it reached to (1× 10-7 M) in media (75:25 water _ methanol ) , but when you use a media ( 75:25 water _ ethanol ) arrived to the limit of detection (1×10-4 M ), As for propanol arrived to the limit of detection (1×10-3 M). where the value reached detection limit of arsenic to (1× 10-5 M) in media ( 50:50 water _ methanol ) , but when you use a media ( 50:50 water _ ethanol ) arrived to the limit of detection (1×10-3 M ), As for propanol arrived to the limit of detection (1×10-2 M). The study showed that the use of the ratio ( 75:25 water _ alcohol ) gave a higher value limit of detection and therefore better results . Was calculated as the standard deviation and standard deviation percentile confidence limit in addition to the feedback that indicates the efficiency of the method of determining the concentration of arsenic detection limit for each medium.
This research aims to study the effect of certain analytical conditions to determine the arsenic in in mixed media (water _ alcohol ) where the user either alcohol ( methanol, ethanol , propanol using a Potentiometric, and then selected as conditi ons optimal certified for this determine. The effect of each of the (PH value, type, concentration electrolyte, effect of crippling electrolytes) to determine the arsenic in mixed media ( 50:50 water _ alcohol ) and calibration using a standard solution of iodine.In addition to that, there are technical conditions must be tuned to determine the actual value of the end point calibration and data processing of standard solution (initial velocity and deceleration near the end point calibration). The study showed that the PH value appropriate for calibration of arsenic with iodine (pH=8), also found that the response process of arsenic on the electrode platinum has been excellent when using NaHCO3 as electrolyte with concentration of 1 M, which has been successfully used to quantify arsenic As+3, where the value reached detection limit of arsenic to (1×10-5M) in media (50:50water _ methanol ) , but when you use a media ( 50:50 water _ ethanol ) arrived to the limit of detection (1×10-3 M ), As for propanol arrived to the limit of detection (1×10-2 M). Was calculated as the standard deviation and standard deviation percentile confidence limit in addition to the feedback that indicates the efficiency of the method of determining the concentration of arsenic and detection limit for each medium.
In this study, we review the possibility of production both ethanol and methanol from OMW(OMW: Olive Mill Wastewater), fermented using pathogenic bacteria and isolated marine bacteria. The results showed that when using Salmonella sp. bacteria, the highest values of methanol (5658.308 μg /l) appear at 7.5% concentration of the OMW, and the higher concentration of ethanol (49.132 μg/l) at a concentration of 17.5% fermentation of OMW. While Pseudomonas sp. produced the highest concentration of methanol (603.76μ g/l) and ethanol (688.71μg /l) at 17.5% for OMW. The results of this research showedthe ability of the bacteria isolated from sea water in producing the above mentioned alcohols; for example the X3 bacteria displayed a direct correlation between high concentrations of OMW (15 , 35 , 50)% and the high concentrations of produced methanol (UL, 130.406μg/l, 1353.244μg/l ), apposite to ethanol which was under the detection limits (under limited: UL).
This study was conducted at the laboratories of the Faculty of Agriculture, Damascus University and the National Commission of Biotechnology in 2012 to investigate he possibility of Production of bioethanol using local isolate of Saccharomyces cer evisiae from raw sugar refining molasses and to determine the effect of different temperatures, pH and concentration of Dry matter (Brix degree) in molasses on the amount of ethanol produced. A local isolate (R1) of Saccharomyces cerevisiae selected previously due to its superiority in ethanol production was taken from wine brewing residues and exposed to different temperatures (20, 25, 30 and 35OC), pH (4, 4.5, 5 and 5.5) and the Brix degrees (16, 20, 24 and 28%) during fermentation. Results revealed that the best amount of ethanol was produced at temperature of 30 º C, pH 5, and Brix degree in molasses 16%.
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