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تحضير وتوصيف الحفاز V-MCM-41 وفعاليته الحفزية في تفاعل أكسدة جزئية لمركب عضوي

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 Publication date 2017
  fields Chemistry
and research's language is العربية
 Created by Shamra Editor




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عبد العزيز بيطار كيمياء السطوح والحفازات منشورات جامعة البعث
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A silicate catalyst prepared which has a mezopore type (MCM-41) ,by manner that condensation where the interaction between Tetra Ethyl Ortho Silicate (TEOS) with 3-Mercapto Propyl Tri-methoxy Silane (MPTS), in the presence of superficial active su bstance {Cetyl Trimethyl Ammonium Bromide(C 16 TAB)}at room temperature. The process of changing the surface hydophilic of the catalyst has done by using substance( Hexa methyl disilazane), which symbolized by the symbol (HMDS).
It is found that the ferric ions, as a catalyst, have a weak effect on the oxidation of luminol "triaminophtal hydrazid" by (DPCA) and through chemiluminescence reaction. For increasing the catalytic activity of ferric ions we used organic and non organic compounds. The best compound was o – phenathroline. It forms two different complexes with ferric (A) and ferrous (B) ions (A, B). The formation of hydrolyzed mixture of the complexes (Ph-Fe3+) depends on the pH. We found that (Ph-Fe3+) complex was very effective in chime-luminescence process above mentioned.
The Umayyad state has raised on a basic support represented by Arab discrimination . In time the prospect of the Islamic call has expended . The Arab Islamic world parties have expended to include Arabs and non Arabs of different races . the suppor ters have become as second center in the literary status and the social treatment on both . The political parties have noticed that there is a type of a complaint of the supporter so they attracted them to it . This discrimination has extended to include the Arabs themselves so they sided with the tribe bloc and persecuted others . The conflict has been between Arabs and non Arabs and between Arabs themselves Yemen and Al-Qaysiyah,This was one of the reasons for the deterioration of the Umayyad state and its fall .
This research aims to analyze the wholesale prices for both types of table grape Helwani and Baladi in AL-Hal`s Market in Damascus city, being the main center for selling grapes of south area in Syria. It has been done as a sector research for one season 2003, as will as the applied selling techniques in this market were determined. The maximum and minimum prices for both categories were recorded depending on some commission traders, producers, guarantors and exporters, daily and round the season, which the beginning and end for each were determined. Centralization and deviation measurements; in addition to correlation coefficient for prices averages for both the two prices and the two weekly prices range were calculated. The correlation with each other, the correlation of each with time, and the regression functions for previous relations were defined.
أجري هذا البحث بهدف التحري عن بكتريا العصية الشمعية وعزلها من بعض الاغذية المحلية الجاهزة للأكل ( المقبلات الغذائية ) كمتبل الباذنجان والحمص بالطحينية والسلطات الجاهزةوالنودلز المباعة في الاسواق السورية
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