تم في هذا البحث تحضير مسرى معجونة الكربون المعدلة بمعقد الكوبالت (II)
مع 1-(2-بيريديل آزو)-2-نفتول (PAN) كمادة فعالة كهربائيا و المنتقي لشاردة الكوبالت. تبين من خلال الدراسة أن المسرى ذو التركيب (47%) فحم غرافيتي., و (47%) مادة ملدنة و (6%) مادة فعالة كهربائيا هو الأفضل.
A new carbon paste electrode (CPE) for Co2+ ion modified with
complex of Cobalt(II) with 1-(2-pyridylazo)-2-naphthol (PAN) as
electroactive 84aterial was prepared. The best performances were
obtained by carbon paste electrode with the composition Graphit
powder (47%), DOPH as plasticizer (47%) and Co-PAN as
electroactive material (6%)
References used
PALEOLOGOS E. K., PRODROMIDIS M. I., GIOKAS D. L., CH. PAPPAS A., M. I. KARAYANNIS, (2002), Highly selective spectrophotometric determination of trace cobalt and development of a reagentless fiber-optic sensor, Analytica Chimica Acta. Vol. 467, pp. 205–215
SCHULTZ F. A., KUWANA T., (1965), Chemical and Biological Sensors and Analytical Methods II,. Electroanal Chem. Vol.10, pp 95
CHEEK G. T., NELSON R. F., (1978), Studies on the Polythiophene(PT)/GC Electrode for the Determination of Some Metals by Differential Pulse Anodic Stripping Voltammetry (DPASV), Anal. Lett. A, Vol.11, pp 393
A sensitive, simple, selective spectrophotometric method has been developed for determination Cobalt (II) with 1-(2-pyridylazo)-2 naphthol (PAN). This method ralies on the formation of stable red colored complex at pH=4.1 which has an absorption maximum at 580nm.
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