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In this research electrochemical treatment was used to treat Al-Sin water that feed Banias thermal station boilers for generate electricity , this recycled pure water minimize corrosion and wear of turbine, the current of (2A) and (12V) was applied by Transformer on metal electrodes of aluminum. The electrochemical treatment efficiency was studied. Results revealed that the turbidity decreased for about (98%), and that total dissolved solids (TDS) and conductivity were reduced by about (61%) and (70.8%) respectively after one hour of treatment process.
In this research, the electrochemical reduction of hydrogen process and the factors affecting the reduction potential have been studied in this research. The effect of acid concentration on the shifting of the volt-ampero-metric curves that expres s the reduction process and so its effect on both the reduction potential value of hydronium ions on drop mercury electrode, and the speed value of reduction reaction was studied. Then an amount of pyridine as organic substance was added to a specific volume of acid in a specific concentration to figure out the relationship between the amount of pyridine added and the cathode current of the reaction to find out the effect of added pyridine on the reaction speed and the relationship between the amount of added pyridine and the hydrogen reduction potential. Pyridine was added to amount of acid to study the effect of theaddition on the hydrogen reduction over potential.
Welded joints corrosion phenomena for some kinds of stainless steels and nickel alloy was studied in polluted phosphoric acid 37.7%H3Po4 using electrochemical techniques like Tafel polarization. Corrosion rate of base metal and weld metal had calcu lated & compared among these alloys. Laboratory Test results showed the change in both corrosion rate and corrosion current densities (Icorr) for tested alloys, and there is a clear difference between base metal and weld metal in most of tested alloys , which lead to high corrosion rates of welded joint, and change in its properties then gets out of service in some service conditions. The stainless steel 904L has low corrosion rates and low difference in corrosion rates between base metal and weld metal, so it may be the most suitable alloy, among all the studied alloys, for exploitation in polluted phosphoric acid 37.7%H3Po4 produced at the General Fertilizer Company in Homs city.
This research showed the great importance for following studies of the effect of polluted phosphoric acid, produced in General Fertilizer Company, on the high corrosion resisting alloys, to reach suitable alloys for equipments and machines used for its production, because of its high corrosion rates that create many corrosion problems in these equipments and machines.
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