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An experiment was conducted for two seasons 2015 -2016, to study the effect of treated waste water (TWW) on some fodder crops productivity at Salamieh Research Center (GCSAR), on triticale and sesbania crops within crop rotation. This experiment w as conducted with collaboration between (ACSAD) and (GCSAR). The experimental design was split plot design with three replicates, using drip irrigation (DI) and surface irrigation (SI) systems with two treatments namely fresh water (FW) and (TWW). Soil and water were analyzed before cultivation.
This research aims to: Determination of optimal pH values to reach the highest efficiency of chromium removal in industrial wastewater from tanneries by chemical deposition. Access to close concentration of the permitted concentration of chromium in treated tannery wastewater according to Syrian Standard No. 2580/2002 (Table 1).
Fixed bed adsorption columns packed with natural zeolite were used to study the kinetics of heavy metals removal from the single component solutions of Vanadium, Nikle, Zinc, and Lead. The system parameters studied include solution flow rate and be d height. The effect of competing cations was also studied to establish the effectiveness of natural zeolite in treating Industrial wastewater under continuous conditions using fixed bed columns. The metal loaded natural zeolite was regenerated using NaCl . The results from column studies showed that the Slower flow rates gave better removal efficiencies compared to faster ones, Longer bed heights also resulted in greater adsorption efficiencies. The bed depth service time (BDST) model was successfully used to simulate experimental results at 30 % breakthrough. This model provides the necessary parameters needed for fixed bed column design, the factor R2 ranged between 0.91 – 0.95. Natural zeolite was exposed to 3 cycles of adsorption and desorption. The efficiency of the column in removing heavy metals was high, The results indicate that natural zeolite can be regenerated and re-used in removing heavy metals from solution.
This research was aimed to assess the pollution from Tartous Cement Factory of some heavy metal by using of the bark of olive trees and Lichens as Bio-indicators. The olive trees was chosen as that predominant vegetation type in the study area. Bar k samples of olive trees and the lichens were collected from several villages surrounding the Cement Factory at different distances (1-2-3-4-5-6-7) km from the center of the Cement Factory in the eastern and north-eastern region of the Cement plant (where the prevailing winds in the region is western and southern Western). The results showed that the concentration of heavy elements in the bark of olive trees and lichens (ppm) take the same trend even thought there are differences in concentration between them by the overall average for all sites was as follows: iron > manganese > copper > lead. We note the high concentration of iron in bark of olive trees compared to lichens, but the rest of the elements it was statistically identical. The results also showed a significant correlation between the concentrations of manganese element in each of the bark and Lichens, and the existence of a negative correlation between the concentration of manganese and distance for both Lichens and bark. Concerning the altitude above sea level the results showed existence of significant and negative correlation with all of Iron, Manganese and Lead in Lichens.
Poly(vinyl alcohol)(PVA)/cellulose acetate(CA) composite membranes were preparedfor metal ions removal from water. The top layer was modified by polyethylene glycol and glycerin,then irradiated with 32[J/cm2] photo dose to improve adequate selecti vity for metal ions separation. The flux of water increased with increasingoperating pressure, and the maximum value of flux was 200[L/m2.h] at 4[bar] for the membrane(PVA68/PEG17/G15), but this membrane tear after applying pressure above 4[bar], while composite and CA membranes served for long time at pressures higher than (4[bar]). The rejection of ions decreased as the feed water pressure increased. The maximum percent retention of ions was found to be 97% for Pb+2, 96% for Cu+2, and 95% for Co+2at pressure of 2[bar] in composite membrane.
The study was carried out on the sorption of heavy metals (Pb+2, Zn+2) under static conditions from single- and multicomponent aqueous solutions by Syrian Zeolite mineral extracted from south Syria. The removal has an ion-exchange nature and consis ts of three stages: the adsorption on the surface of microcrystals, the inversion stage, and the moderate adsorption in the interior of the microcrystal, The study showed that equilibrium time is 6 hours, and The slight difference between adsorption capacity of the Zeolite toward lead, zinc from single- and multicomponent solutions may testify to individual sorption centers of the zeolite for each metal. The maximum sorption capacity toward pb2+ is determined as 33.89 mg/g at an equilibrium concentration of 261.07 mg/L and toward Zn+2 as 29.18 mg/g at 309.818 mg/L. Langmuir and Freundlich Adsorption Isotherms were used to evaluate natural zeolite adsorption performance for Lead, Zinc. These Isotherms were able to provide suitable fit with experimental data, the factor R2 ranged between 0.95 – 0.99, with better fit to Langmuir Isotherm.
The study was carried out to remove of heavy metals (V+5, Ni+2) under static conditions from aqueous solutions by Syrian Zeolite mineral extracted from south of Syria. The results revealed that operational conditions such as initial solution pH and concentration, adsorbent particle size, the presence of competing cations, are able to affect the adsorption capacity and efficiency of natural zeolite.
This research was performed to study the effect of sewage water on the surface water of the Addelbeh Valley stream, and groundwater on both sides of the stream in Tartous Cement Factory area. Water samples were taken from the factory water outlet and Addelbeh Valley water to study the content of pollutants. We also took groundwater samples from selected wells on both sides of the waterway in the studied area. We repeated that process every two months for a full hydrological cycle from July 2013 to May 2014. We found a great increase in content of the industrial drainage water include oils and heavy metals especially iron, copper and zinc. For example: iron concentration in sewage water exceeded 150 mg/l in all samples. Besides sewage water and stream water contained high concentrations of ammonia and nitrite versus low concentration of nitrate, unlike water wells samples. The study revealed increased EC and salts concentration markedly in wells water due to its adjacency to the sea.
In this research we studied and measured the response and absorbance for some metals (zinc, copper, iron, aluminum) which are exposed to the direct light and painted with black, which has a high absorbance and low emittance, and with different thickn esses (to obtain black bodies) with higher absorption. we took the measurement on the painted metals for each thickness of the paint in the laboratory first using tow lamps 30 watt and 100 watt to compare the absorption of these metals of the radiation from these two lamps with the absorption of the solar radiation and make sure that the absorption is similar of the two situations, then we took the measurements in AL- Kadmous Area which is 900m above sea level using direct solar radiation , and we found the relationship between the absorbance and the paint thickness.
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