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تسجيل مستخدم جديدNeutron Diffraction Studies on La2-xDyxCa2xBa2Cu4+2xOz Superconductors
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Structural studies on Dy-substituted La-2125 type superconductors have been carried out by neutron diffraction experiments at room temperature using a monochromatic neutron beam of wavelength lambda = 1.249 Angstroms. A series of samples with La2-xDyxCa2xBa2Cu4+2xOz stoichiometric composition, for x = 0.1 - 0.5, have been studied for their structural properties. A tetragonal Y-123 unit cell was taken as the starting model for the Rietveld analysis. All the samples fit into the starting model, exhibiting no structural transition taking place with increasing dopant concentration. The results of Rietveld analysis and structural properties are discussed in detail.
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The La-2125 type La2-xDyxCa2xBa2Cu4+2xOz (0.1 < x < 0.5; LDBO) compounds have been synthesized and studied for their structural and superconducting properties by room temperature neutron diffraction, high field dc magnetization, four-probe resistivit
y and iodometric double titration. The Rietveld analysis of the neutron diffraction data reveals tetragonal structure for all the samples, which crystallizes into La-123 type tetragonal structure in P4/mmm space group. Iodometric double titrations were performed to determine the oxygen content values and calculate mobile charge carrier (holes) density. The superconducting transition temperatures (Tc) increases from ~ 20 K for x = 0.1 to a maximum of 75 K for x = 0.5. Flux pinning force (Fp) and critical current density (Jc), calculated from the low temperature hysteresis loops, also increases with increasing dopant concentration. The paper presents the studies on structure and superconducting properties of all LDBO compounds in light of the role of calcium in inducing superconductivity in the tetragonal non-superconducting oxide.
Polycrystalline La2-xPrxCa2xBa2Cu4+2xOz (LPCaBCO) compounds with x = 0.1 - 0.5 were synthesized by solid-state reaction method and studied by room temperature X-ray diffraction, dc resistivity, dc magnetization and iodometry. The superconducting tran
sition temperatures in these tetragonal triple perovskite compounds increases from 32 to 62 K (Tconset values) with increasing dopant concentration. The mixing of rare earth La3+ and Pr3+/4+ ions at rare earth site (La3+) along with substitution of divalent Ca2+ results in the shrinkage of unit cell volume. The contraction of unit cell volume due to larger ion being substituted by smaller ions, gives rise to creation of pinning centers in the unit cell leading to increase in critical current density and flux pinning
We have grown cubic centimetre-size crystals of YBa2Cu3Ox suitable for neutron studies, by a top-seeded melt-growth technique. Growth conditions were optimized with an eye toward maximizing phase purity. It was found that the addition of 2% Y2BaCuO5
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A review of high-pressure studies on Fe-pnictide superconductors is given. The pressure effects on the magnetic and superconducting transitions are discussed for different classes of doped and undoped FeAs-compounds, ROFeAs (R = rare earth), AeFe2As2
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We present local structural evidence supporting the presence of charge inhomogeneities in the CuO2 planes of underdoped La2-xSrxCuO4. High-resolution atomic pair distribution functions have been obtained from neutron powder diffraction data over the
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