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Thermoelectric energy conversion is a direct but low-efficiency process, which precludes the development of long-awaited wide-scale applications. As a breakthrough permitting a drastic performance increase is seemingly out of reach, we fully reconsider the problem of thermoelectric coupling enhancement. The corner stone of our approach is the observation that heat engines are particularly efficient when their operation involves a phase transition of their working fluid. We derive and compute the thermoelastic coefficients of various systems, including Bose and Fermi gases, and fluctuation Cooper pairs. Combination of these coefficients yields the definition of the thermodynamic figure of merit, the divergence of which at $finite$ temperature indicates that conditions are fulfilled for the best possible use of the thermoelectric working fluid. Here, this situation occurs in the fluctuation regime only, as a consequence of the increased compressibility of the working fluid near its phase transition. Our results and analysis clearly show that efforts in the field of thermoelectricity can now be productively directed towards systems where electronic phase transitions are possible.
We investigate strong-coupling properties of a two-dimensional ultracold Fermi gas in the normal state. Including pairing fluctuations within the framework of a $T$-matrix approximation, we calculate the distribution function $n({boldsymbol Q})$ of C
Thermoelectric materials (TMs) can uniquely convert waste heat into electricity, which provides a potential solution for the global energy crisis that is increasingly severe. Bulk Cu2Se, with ionic conductivity of Cu ions, exhibits a significant enha
We examine the basic mode structure of atomic Cooper pairs in an inhomogeneous Fermi gas. Based on the properties of Bogoliubov quasi-particle vacuum, the single particle density matrix and the anomalous density matrix share the same set of eigenfunc
A prominent band centered at around 1000-1300 cm-1 and associated with resonant enhancement of two-phonon Raman scattering is reported in multiferroic BiFeO3 thin films and single crystals. A strong anomaly in this band occurs at the antiferromagneti
Temperature dependent electrical resistivity, crystal structure and heat capacity measurements reveal a resistivity drop and metal to semiconductor transition corresponding to first order structural phase transition near 400 K in Ca3Co4O9. The lattic