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Electronic topology in metallic kagome compounds is under intense scrutiny. We present transport experiments in Na2/3CoO2 in which the Na order differentiates a Co kagome sub-lattice in the triangular CoO2 layers. Hall and magnetoresistance (MR) data under high fields give evidence for the coexistence of light and heavy carriers. At low Ts, the dominant light carrier conductivity at zero field is suppressed by a B-linear MR suggesting Dirac like quasiparticles. Lifshitz transitions induced at large B and T unveil the lower mobility carriers. They display a negative B^2 MR due to scattering from magnetic moments likely pertaining to a flat band. We underline an analogy with heavy Fermion physics.
We report a study on the magnetotransport properties and on the Fermi surfaces (FS) of the ZrSi(Se,Te) semimetals. Density Functional Theory (DFT) calculations, in absence of spin orbit coupling (SOC), reveal that both the Se and the Te compounds dis play Dirac nodal lines (DNL) close to the Fermi level $varepsilon_F$ at symmorphic and non-symmorphic positions, respectively. We find that the geometry of their FSs agrees well with DFT predictions. ZrSiSe displays low residual resistivities, pronounced magnetoresistivity, high carrier mobilities, and a butterfly-like angle-dependent magnetoresistivity (AMR), although its DNL is not protected against gap opening. As in Cd$_3$As$_2$, its transport lifetime is found to be 10$^2$ to 10$^3$ times larger than its quantum one. ZrSiTe, which possesses a protected DNL, displays conventional transport properties. Our evaluation indicates that both compounds most likely are topologically trivial. Nearly angle-independent effective masses with strong angle dependent quantum lifetimes lead to the butterfly AMR in ZrSiSe.
We present a detailed quantum oscillatory study on the Dirac type-II semimetallic candidates PdTe$_{2}$ and PtTe$_{2}$ emph{via} the temperature and the angular dependence of the de Haas-van Alphen (dHvA) and Shubnikov-de Haas (SdH) effects. In high quality single crystals of both compounds, i.e. displaying carrier mobilities between $10^3$ and $10^4$ cm$^2$/Vs, we observed a large non-saturating magnetoresistivity (MR) which in PtTe$_2$ at a temperature $T = 1.3$ K, leads to an increase in the resistivity up to $5 times 10^{4}$ % under a magnetic field $mu_0 H = 62$ T. These high mobilities correlate with their light effective masses in the range of 0.04 to 1 bare electron mass according to our measurements. For PdTe$_{2}$ the experimentally determined Fermi surface cross-sectional areas show an excellent agreement with those resulting from band-structure calculations. Surprisingly, this is not the case for PtTe$_{2}$ whose agreement between calculations and experiments is relatively poor even when electronic correlations are included in the calculations. Therefore, our study provides a strong support for the existence of a Dirac type-II node in PdTe$_2$ and probably also for PtTe$_2$. Band structure calculations indicate that the topologically non-trivial bands of PtTe$_2$ do not cross the Fermi-level ($varepsilon_F$). In contrast, for PdTe$_2$ the Dirac type-II cone does intersect $varepsilon_F$, although our calculations also indicate that the associated cyclotron orbit on the Fermi surface is located in a distinct $k_z$ plane with respect to the one of the Dirac type-II node. Therefore it should yield a trivial Berry-phase.
Weyl type-II fermions are massless quasiparticles that obey the Weyl equation and which are predicted to occur at the boundary between electron- and hole-pockets in certain semi-metals, i.e. the (W,Mo)(Te,P)$_2$ compounds. Here, we present a study of the Fermi-surface of WP$_2$ emph{via} the Shubnikov-de Haas (SdH) effect. Compared to other semi-metals WP$_2$ exhibits a very low residual resistivity, i.e. $rho_0 simeq 10$ n$Omega$cm, which leads to perhaps the largest non-saturating magneto-resistivity $(rho(H))$ reported for any compound. For the samples displaying the smallest $rho_0$, $rho(H)$ is observed to increase by a factor of $2.5 times 10^{7}$ $%$ under $mu_{0}H = 35$ T at $T = 0.35$ K. The angular dependence of the SdH frequencies is found to be in very good agreement with the first-principle calculations when the electron- and hole-bands are slightly shifted with respect to the Fermi level, thus supporting the existence of underlying Weyl type-II points in WP$_2$.
The electronic structure of WTe$_2$ and orthorhombic $gamma-$MoTe$_2$, are claimed to contain pairs of Weyl type-II points. A series of ARPES experiments claim a broad agreement with these predictions. We synthesized single-crystals of MoTe$_2$ throu gh a Te flux method to validate these predictions through measurements of its bulk Fermi surface (FS) emph{via} quantum oscillatory phenomena. We find that the superconducting transition temperature of $gamma-$MoTe$_2$ depends on disorder as quantified by the ratio between the room- and low-temperature resistivities, suggesting the possibility of an unconventional superconducting pairing symmetry. Similarly to WTe$_2$, the magnetoresistivity of $gamma-$MoTe$_2$ does not saturate at high magnetic fields and can easily surpass $10^{6}$ %. Remarkably, the analysis of the de Haas-van Alphen (dHvA) signal superimposed onto the magnetic torque, indicates that the geometry of its FS is markedly distinct from the calculated one. The dHvA signal also reveals that the FS is affected by the Zeeman-effect precluding the extraction of the Berry-phase. A direct comparison between the previous ARPES studies and density-functional-theory (DFT) calculations reveals a disagreement in the position of the valence bands relative to the Fermi level $varepsilon_F$. Here, we show that a shift of the DFT valence bands relative to $varepsilon_F$, in order to match the ARPES observations, and of the DFT electron bands to explain some of the observed dHvA frequencies, leads to a good agreement between the calculations and the angular dependence of the FS cross-sectional areas observed experimentally. However, this relative displacement between electron- and hole-bands eliminates their crossings and, therefore, the Weyl type-II points predicted for $gamma-$MoTe$_2$.
The field-induced ordering transition in the quantum spin system NiCl$_2$$cdot$4SC(NH$_2$)$_2$ is studied by means of neutron diffraction, AC magnetometry and relaxation calorimetry. The interpretation of the data is strongly influenced by a finite d istribution of transition fields in the samples, which was present but disregarded in previous studies. Taking this effect into account, we find that the order-parameter critical exponent is inconsistent with the BEC universality class even at temperatures below 100 mK. All results are discussed in comparison with previous measurements and with recent similar studies of disordered Ni(Cl$_{1-x}$Br$_x$)$_2$$cdot$4SC(NH$_2$)$_2$.
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