Constitutive laws underlie most physical processes in nature. However, learning such equations in heterogeneous solids (e.g., due to phase separation) is challenging. One such relationship is between composition and eigenstrain, which governs the che
mo-mechanical expansion in solids. In this work, we developed a generalizable, physically-constrained image-learning framework to algorithmically learn the chemo-mechanical constitutive law at the nanoscale from correlative four-dimensional scanning transmission electron microscopy and X-ray spectro-ptychography images. We demonstrated this approach on Li$_X$FePO$_4$, a technologically-relevant battery positive electrode material. We uncovered the functional form of composition-eigenstrain relation in this two-phase binary solid across the entire composition range (0 $leq$ X $leq$ 1), including inside the thermodynamically-unstable miscibility gap. The learned relation directly validates Vegards law of linear response at the nanoscale. Our physics-constrained data-driven approach directly visualizes the residual strain field (by removing the compositional and coherency strain), which is otherwise impossible to quantify. Heterogeneities in the residual strain arise from misfit dislocations and were independently verified by X-ray diffraction line profile analysis. Our work provides the means to simultaneously quantify chemical expansion, coherency strain and dislocations in battery electrodes, which has implications on rate capabilities and lifetime. Broadly, this work also highlights the potential of integrating correlative microscopy and image learning for extracting material properties and physics.
We propose an anti-parity-time (anti-PT ) symmetric non-Hermitian Su-Schrieffer-Heeger (SSH) model, where the large non-Hermiticity constructively creates nontrivial topology and greatly expands the topological phase. In the anti-PT -symmetric SSH mo
del, the gain and loss are alternatively arranged in pairs under the inversion symmetry. The appearance of degenerate point at the center of the Brillouin zone determines the topological phase transition, while the exceptional points unaffect the band topology. The large non-Hermiticity leads to unbalanced wavefunction distribution in the broken anti-PT -symmetric phase and induces the nontrivial topology. Our findings can be verified through introducing dissipations in every another two sites of the standard SSH model even in its trivial phase, where the nontrivial topology is solely induced by the dissipations.
Symmetry plays fundamental role in physics and the nature of symmetry changes in non-Hermitian physics. Here the symmetry-protected scattering in non-Hermitian linear systems is investigated by employing the discrete symmetries that classify the rand
om matrices. The even-parity symmetries impose strict constraints on the scattering coefficients: the time-reversal (C and K) symmetries protect the symmetric transmission or reflection; the pseudo-Hermiticity (Q symmetry) or the inversion (P) symmetry protects the symmetric transmission and reflection. For the inversion-combined time-reversal symmetries, the symmetric features on the transmission and reflection interchange. The odd-parity symmetries including the particle-hole symmetry, chiral symmetry, and sublattice symmetry cannot ensure the scattering to be symmetric. These guiding principles are valid for both Hermitian and non-Hermitian linear systems. Our findings provide fundamental insights into symmetry and scattering ranging from condensed matter physics to quantum physics and optics.
We report a global effect induced by the local complex field, associated with the spin-exchange interaction. High-order exceptional point up to ($N+1$)-level coalescence is created at the critical local complex field applied to the $N$-size quantum s
pin chain. The ($N+1$)-order coalescent level is a saturated ferromagnetic ground state in the isotropic spin system. Remarkably, the final state always approaches the ground state for an arbitrary initial state with any number of spin flips; even if the initial state is orthogonal to the ground state. Furthermore, the switch of macroscopic magnetization is solely driven by the time and forms a hysteresis loop in the time domain. The retentivity and coercivity of the hysteresis loop mainly rely on the non-Hermiticity. Our findings highlight the cooperation of non-Hermiticity and the interaction in quantum spin system, suggest a dynamical framework to realize magnetization, and thus pave the way for the non-Hermitian quantum spin system.
Degeneracy (exceptional) points embedded in energy band are distinct by their topological features. We report different hybrid two-state coalescences (EP2s) formed through merging two EP2s with opposite chiralities that created from the type III Dira
c points emerging from a flat band. The band touching hybrid EP2, which is isolated, is induced by the destructive interference at the proper match between non-Hermiticity and synthetic magnetic flux. The degeneracy points and different types of exceptional points are distinguishable by their topological features of global geometric phase associated with the scaling exponent of phase rigidity. Our findings not only pave the way of merging EPs but also shed light on the future investigations of non-Hermitian topological phases.
Knot theory provides a powerful tool for the understanding of topological matters in biology, chemistry, and physics. Here knot theory is introduced to describe topological phases in the quantum spin system. Exactly solvable models with long-range in
teractions are investigated, and Majorana modes of the quantum spin system are mapped into different knots and links. The topological properties of ground states of the spin system are visualized and characterized using crossing and linking numbers, which capture the geometric topologies of knots and links. The interactivity of energy bands is highlighted. In gapped phases, eigenstate curves are tangled and braided around each other forming links. In gapless phases, the tangled eigenstate curves may form knots. Our findings provide an alternative understanding of the phases in the quantum spin system, and provide insights into one-dimension topological phases of matter.
We propose a two-dimensional non-Hermitian Chern insulator with inversion symmetry, which is anisotropic and has staggered gain and loss in both x and y directions. In this system, conventional bulk-boundary correspondence holds. The Chern number is
a topological invariant that accurately predicts the topological phase transition and the existence of helical edge states in the topologically nontrivial gapped phase. In the gapless phase, the band touching points are isolated and protected by the symmetry. The degenerate points alter the system topology, and the exceptional points can destroy the existence of helical edge states. Topologically protected helical edge states exist in the gapless phase for the system under open boundary condition in one direction, which are predicted by the winding number associated with the vector field of average values of Pauli matrices. The winding number also identifies the detaching points between the edge states and the bulk states in the energy bands. The non-Hermiticity also supports a topological phase with zero Chern number, where a pair of in-gap helical edge states exists. Our findings provide insights into the symmetry protected non-Hermitian topological insulators.
Non-Hermiticity can vary the topology of system, induce topological phase transition, and even invalidate the conventional bulk-boundary correspondence. Here, we show the introducing of non-Hermiticity without affecting the topological properties of
the original chiral symmetric Hermitian systems. Conventional bulk-boundary correspondence holds, topological phase transition and the (non)existence of edge states are unchanged even though the energy bands are inseparable due to non-Hermitian phase transition. Chern number for energy bands of the generalized non-Hermitian system in two dimension is proved to be unchanged and favorably coincides with the simulated topological charge pumping. Our findings provide insights into the interplay between non-Hermiticity and topology. Topological phase transition independent of non-Hermitian phase transition is a unique feature that beneficial for future applications of non-Hermitian topological materials.
The discovery of novel topological phase advances our knowledge of nature and stimulates the development of applications. In non-Hermitian topological systems, the topology of band touching exceptional points is very important. Here we propose a real
-energy topological gapless phase arising from exceptional points in one dimension, which has identical topological invariants as the topological gapless phase arising from degeneracy points. We develop a graphic approach to characterize the topological phases, where the eigenstates of energy bands are mapped to the graphs on a torus. The topologies of different phases are visualized and distinguishable; and the topological gapless edge state with amplification appropriate for topological lasing exists in the nontrivial phase. These results are elucidated through a non-Hermitian Su-Schrieffer-Heeger ladder. Our findings open new way for identifying topology phase of matter from visualizing the eigenstates.
While doping is widely used for tuning physical properties of perovskites in experiments, it remains a challenge to exactly know how doping achieves the desired effects. Here, we propose an empirical and computationally tractable model to understand
the effects of doping with Fe-doped BaTiO$_{3}$ as an example. This model assumes that the lattice sites occupied by Fe ion and its nearest six neighbors lose their ability to polarize, giving rise to a small cluster of defective dipoles. Employing this model in Monte-Carlo simulations, many important features like reduced polarization and the convergence of phase transition temperatures, which have been observed experimentally in acceptor doped systems, are successfully obtained. Based on microscopic information of dipole configurations, we provide insights into the driving forces behind doping effects and propose that active dipoles, which exist in proximity to the defective dipoles, can account for experimentally observed phenomena. Close attention to these dipoles are necessary to understand and predict doping effects.
