In this work we elaborate on two recently discovered invariance principles, according to which transport coefficients are, to a large extent, independent of the microscopic definition of the densities and currents of the conserved quantities being tr
ansported (energy, momentum, mass, charge). The first such principle, gauge invariance, allows one to define a quantum adiabatic energy current from density-functional theory, from which the heat conductivity can be uniquely defined and computed using equilibrium ab initio molecular dynamics. When combined with a novel topological definition of atomic oxidation states, gauge invariance also sheds new light onto the mechanisms of charge transport in ionic conductors. The second principle, convective invariance, allows one to extend the analysis to multi-component systems. These invariance principles can be combined with new spectral analysis methods for the current time series to be fed into the Green-Kubo formula to obtain accurate estimates of transport coefficients from relatively short molecular dynamics simulations.
Thouless quantization of adiabatic particle transport permits to associate an integer topological charge with each atom of an electronically gapped material. If these charges are additive and independent of atomic positions, they provide a rigorous d
efinition of atomic oxidation states and atoms can be identified as integer-charge carriers in ionic conductors. Whenever these conditions are met, charge transport is necessarily convective, i.e. it cannot occur without substantial ionic flow, a transport regime that we dub trivial. We show that the topological requirements that allow these conditions to be broken are the same that would determine a Thouless pump mechanism if the system were subject to a suitably defined time-periodic Hamiltonian. The occurrence of these requirements determines a non-trivial transport regime whereby charge can flow without any ionic convection, even in electronic insulators. These results are first demonstrated with a couple of simple molecular models that display a quantum pump mechanism upon introduction of a fictitious time dependence of the atomic positions along a closed loop in configuration space. We finally examine the impact of our findings on the transport properties of non-stoichiometric alkali-halide melts, where the same topological conditions that would induce a quantum pump mechanism along certain closed loops in configuration space also determine a non-trivial transport regime such that most of the total charge current results to be uncorrelated from the ionic ones.
Multiparty quantum cryptography based on distributed entanglement will find its natural application in the upcoming quantum networks. The security of many multipartite device-independent (DI) protocols, such as DI conference key agreement, relies on
bounding the von Neumann entropy of the parties outcomes conditioned on the eavesdroppers information, given the violation of a multipartite Bell inequality. We consider three parties testing the Mermin-Ardehali-Belinskii-Klyshko (MABK) inequality and certify the privacy of their outcomes by bounding the conditional entropy of a single partys outcome and the joint conditional entropy of two parties outcomes. From the former bound, we show that genuine multipartite entanglement is necessary to certify the privacy of a partys outcome, while the latter significantly improve previous results. We obtain the entropy bounds thanks to two general results of independent interest. The first one drastically simplifies the quantum setup of an $N$-partite Bell scenario. The second one provides an upper bound on the violation of the MABK inequality by an arbitrary $N$-qubit state, as a function of the states parameters.
The intrinsic luminosity of Uranus is a factor of 10 less than that of Neptune, an observation that standard giant planetary evolution models, which assume negligible viscosity, fail to capture. Here we show that more than half of the interior of Ura
nus is likely to be in a solid state, and that thermal evolution models that account for this high viscosity region satisfy the observed faintness of Uranus by storing accretional heat deep in the interior. A frozen interior also explains the quality factor of Uranus required by the evolution of the orbits of its satellites.
The impact of the inner structure and thermal history of planets on their observable features, such as luminosity or magnetic field, crucially depends on the poorly known heat and charge transport properties of their internal layers. The thermal and
electric conductivities of different phases of water (liquid, solid, and super-ionic) occurring in the interior of ice giant planets, such as Uranus or Neptune, are evaluated from equilibrium ab initio molecular dynamics, leveraging recent progresses in the theory and data analysis of transport in extended systems. The implications of our findings on the evolution models of the ice giants are briefly discussed
Conference key agreement (CKA), or multipartite key distribution, is a cryptographic task where more than two parties wish to establish a common secret key. A composition of bipartite quantum key distribution protocols can accomplish this task. Howev
er, the existence of multipartite quantum correlations allows for new and potentially more efficient protocols, to be applied in future quantum networks. Here, we review the existing quantum CKA protocols based on multipartite entanglement, both in the device-dependent and the device-independent scenario.
Quantum networks will provide multi-node entanglement over long distances to enable secure communication on a global scale. Traditional quantum communication protocols consume pair-wise entanglement, which is sub-optimal for distributed tasks involvi
ng more than two users. Here we demonstrate quantum conference key agreement, a quantum communication protocol that exploits multi-partite entanglement to efficiently create identical keys between N users with up to N-1 rate advantage in constrained networks. We distribute four-photon Greenberger-Horne-Zeilinger (GHZ) states generated by high-brightness, telecom photon-pair sources across up to 50 km of fibre, implementing multi-user error correction and privacy amplification on resulting raw keys. Under finite-key analysis, we establish $1.15times10^6$ bits of secure key, which are used to encrypt and securely share an image between the four users in a conference transmission. We have demonstrated a new protocol tailored for multi-node networks leveraging low-noise, long-distance transmission of GHZ states that will pave the way forward for future multiparty quantum information processing applications.
The intense research activity on Twin-Field (TF) quantum key distribution (QKD) is motivated by the fact that two users can establish a secret key by relying on single-photon interference in an untrusted node. Thanks to this feature, variants of the
protocol have been proven to beat the point-to-point private capacity of a lossy quantum channel. Here we generalize the main idea of the TF-QKD protocol introduced by Curty et al. to the multipartite scenario, by devising a conference key agreement (CKA) where the users simultaneously distill a secret conference key through single-photon interference. The new CKA is better suited to high-loss scenarios than previous multipartite QKD schemes and it employs for the first time a W-class state as its entanglement resource. We prove the protocols security in the finite-key regime and under general attacks. We also compare its performance with the iterative use of bipartite QKD protocols and show that our truly multipartite scheme can be advantageous, depending on the loss and on the state preparation.
Twin-Field (TF) quantum key distribution (QKD) is a major candidate to be the new benchmark for far-distance QKD implementations, since its secret key rate can overcome the repeaterless bound by means of a simple interferometric measurement. Many var
iants of the original protocol have been recently proven to be secure. Here, we focus on the TF-QKD type protocol proposed by Curty et al [preprint arXiv:1807.07667], which can provide a high secret key rate and whose practical feasibility has been demonstrated in various recent experiments. The security of this protocol relies on the estimation of certain detection probabilities (yields) through the decoy-state technique. Analytical bounds on the relevant yields have been recently derived assuming that both parties use the same set of decoy intensities, thus providing sub-optimal key rates in asymmetric-loss scenarios. Here we derive new analytical bounds when the parties use either three or four independent decoy intensity settings each. With the new bounds we optimize the protocols performance in asymmetric-loss scenarios and show that the protocol is robust against uncorrelated intensity fluctuations affecting the parties lasers.
We perform explicit time-dependent classical and quantum propagation of a spatially indirect exciton (SIX) driven by surface acoustic waves (SAWs) in a semiconductor heterostructure device. We model the SIX dynamics at different levels of description
, from the Euler-Lagrange propagation of structureless classical particles to unitary Schrodinger propagation of an electron-hole wave packet in a mean field and to the full quantum propagation of the two-particle complex. A recently proposed beyond mean-field self-energy approach, adding internal virtual transitions to the c.m. dynamics, has been generalized to time-dependent potentials and turns out to describe very well full quantum calculations, while being orders of magnitude numerically less demanding. We show that SAW-driven SIXs are a sensitive probe of scattering potentials in the devices originating, for example, from single impurities or metallic gates, due to competing length and energy scales between the SAW elastic potential, the scattering potential, and the internal electron-hole dynamic of the SIX. Comparison between different approximations allow us to show that internal correlation of the electron-hole pair is crucial in scattering from shallow impurities, where tunneling plays a major role. On the other hand, scattering from broad potentials, i.e., with length scales exceeding the SIX Bohr radius, is well described as the classical dynamics of a pointlike SIX. Recent experiments are discussed in light of our calculations.
