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تسجيل مستخدم جديدWeak spin interactions in Mott insulating La2O2Fe2OSe2
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Identifying and characterizing the parent phases of iron-based superconductors is an important step towards understanding the mechanism for their high temperature superconductivity. We present an investigation into the magnetic interactions in the Mott insulator La2O2Fe2OSe2. This iron oxyselenide adopts a 2-k magnetic structure with low levels of magnetic frustration. This magnetic ground state is found to be dominated by next-nearest neighbor interactions J2 and J2 and the magnetocrystalline anisotropy of the Fe2+ site, leading to 2D-Ising-like spin S=2 fluctuations. In contrast to calculations, the values are small and confine the spin excitations below ~ 25 meV. This is further corroborated by sum rules of neutron scattering. This indicates that superconductivity in related materials may derive from a weakly coupled and unfrustrated magnetic structure.
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Motivated by the presence of an unquenched orbital angular momentum in CoO, a team at Chalk River, including a recently hired research officer Roger Cowley, performed the first inelastic neutron scattering experiments on the classic Mott insulator [S
akurai $textit{et al.}$ 1968 Phys. Rev. $mathbf{167}$ 510]. Despite identifying magnon modes at the zone boundary, the team was unable to parameterise the low energy magnetic excitation spectrum below $Trm{_{N}}$ using conventional pseudo-bosonic approaches. It would not be for another 40 years that Roger, now at Oxford and motivated by the discovery of the high-$T_{c}$ cuprate superconductors [Bednorz & Muller 1986 Z. Phys. B $mathbf{64}$ 189], would make another attempt at the parameterisation of the magnetic excitation spectrum that had previously alluded him. Upon his return to CoO, Roger found a system embroiled in controversy, with some of its most fundamental parameters still remaining undetermined. Faced with such a formidable task, Roger performed a series of inelastic neutron scattering experiments in the early 2010s on both CoO and a magnetically dilute structural analogue MgO. These experiments would prove instrumental in the determination of both single-ion [Cowley $textit{et al.}$ 2013 Phys. Rev. B $mathbf{88}$ 205117] and cooperative magnetic parameters [Sarte $textit{et al.}$ 2018 Phys. Rev. B $mathbf{98}$ 024415] for CoO. Both these sets of parameters would eventually be used in a spin-orbit exciton model [Sarte $textit{et al.}$ 2019 Phys. Rev. B $mathbf{100}$ 075143], developed by his longtime friend and collaborator Bill Buyers, to successfully parameterise the complex spectrum that both measured at Chalk River almost 50 years prior. The story of CoO is of one that has come full circle, one filled with both spectacular failures and intermittent, yet profound, little victories.
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