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2D Ruddlesden Popper perovskites have been extensively studied for their exceptional optical and electronic characteristics while only a few studies have shed light on their mechanical properties. The existing literature mainly discusses the mechanical strength of single crystal perovskites, however a systematic study towards structure tunability of 2D perovskite thin films is still missing. In this study, we report the effect of number of inorganic layers `n on elastic modulus of Butylammonium based 2D, quasi-2D perovskites and 3D perovskite using nanoindentation technique. The experimental results have also been substantiated using first principle density functional theory calculations. Understanding the mechanical behaviour of 2D Ruddlesden Popper perovskites thin films in comparison with conventional 3D perovskite offers intriguing insights into the atomic layer dependent properties and paves the path for next generation mechanically durable novel devices.
Perovskite solar cells with record power conversion efficiency are fabricated by alloying both hybrid and fully inorganic compounds. While the basic electronic properties of the hybrid perovskites are now well understood, key electronic parameters fo
Behaving like atomically-precise two-dimensional quantum wells with non-negligible dielectric contrast, the layered HOIPs have strong electronic interactions leading to tightly bound excitons with binding energies on the order of 500 meV. These stron
The previously developed bistable amphoteric native defect (BAND) model is used for a comprehensive explanation of the unique photophysical properties and for understanding the remarkable performance of perovskites as photovoltaic materials. It is sh
The development of next generation perovskite-based optoelectronic devices relies critically on the understanding of the interaction between charge carriers and the polar lattice in out-of-equilibrium conditions. While it has become increasingly evid
The electronic orbital characteristics at the band edges plays an important role in determining the electrical, optical and defect properties of perovskite photovoltaic materials. It is highly desirable to establish the relationship between the under