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Defects are generally regarded to have negative impact on carrier recombination, charge-transport and ion migration in perovskite materials, which thus lower the efficiency and stability of perovskite optoelectronic devices. Meanwhile, lots of efforts which focused on minimizing defects have greatly promoted the application of perovskite materials. Then, can defects be positive in perovskite optoelectronic devices? Herein, relying on in-depth understanding of defect-associated effects in semiconductors, trapping of photo-generated carriers by defects is applied to enlarge photoconductive gain in perovskite photodetector. The record photoconductive gain, gain-bandwidth product and detection limit were achieved in the photodetector. Exceeding the general concept that defects are harmful, we identify a new view that the defects can be positive in perovskite optoelectronic devices.
Topological insulators are innovative materials with semiconducting bulk together with surface states forming a Dirac cone, which ensure metallic conduction in the surface plane. Therefore, topological insulators represent an ideal platform for optoe
The implementation of aberration-corrected electron beam lithography (AC-EBL) in a 200 keV scanning transmission electron microscope (STEM) is a novel technique that could be used for the fabrication of quantum devices based on 2D atomic crystals wit
The previously developed bistable amphoteric native defect (BAND) model is used for a comprehensive explanation of the unique photophysical properties and for understanding the remarkable performance of perovskites as photovoltaic materials. It is sh
Two-dimensional Ruddlesden-Popper hybrid lead halide perovskites have become a major topic in perovskite optoelectronics. Here, we aim to unravel the ultrafast dynamics governing the evolution of charge carriers and excitons in these materials. Using
It is thought that growing large, oriented grains of perovskite can lead to more efficient devices. We study MAPbI3 films fabricated via Flash Infrared Annealing (FIRA) consisting of highly oriented, large grains. Domains observed in the SEM are ofte