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We study the asymptotic behaviour of a gradient system in a regime in which the driving energy becomes singular. For this system gradient-system convergence concepts are ineffective. We characterize the limiting behaviour in a different way, by proving $Gamma$-convergence of the so-called energy-dissipation functional, which combines the gradient-system components of energy and dissipation in a single functional. The $Gamma$-limit of these functionals again characterizes a variational evolution, but this limit functional is not the energy-dissipation functional of any gradient system. The system in question describes the diffusion of a particle in a one-dimensional double-well energy landscape, in the limit of small noise. The wells have different depth, and in the small-noise limit the process converges to a Markov process on a two-state system, in which jumps only happen from the higher to the lower well. This transmutation of a gradient system into a variational evolution of non-gradient type is a model for how many one-directional chemical reactions emerge as limit of reversible ones. The $Gamma$-convergence proved in this paper both identifies the `fate of the gradient system for these reactions and the variational structure of the limiting irreversible reactions.
A nonlinear parabolic equation of sixth order is analyzed. The equation arises as a reduction of a model from quantum statistical mechanics, and also as the gradient flow of a second-order information functional with respect to the $L^2$-Wasserstein
In this paper we introduce a general abstract formulation of a variational thermomechanical model, by means of a unified derivation via a generalization of the principle of virtual powers for all the variables of the system, including the thermal one
We prove the existence of weak solutions to a system of two diffusion equations that are coupled by a pointwise volume constraint. The time evolution is given by gradient dynamics for a free energy functional. Our primary example is a model for the d
An extended Maxwell viscoelastic model with a relaxation parameter is studied from mathematical and numerical points of view. It is shown that the model has a gradient flow property with respect to a viscoelastic energy. Based on the gradient flow st
We consider a Fokker-Planck equation which is coupled to an externally given time-dependent constraint on its first moment. This constraint introduces a Lagrange-multiplier which renders the equation nonlocal and nonlinear. In this paper we exploit