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Exploiting Electrical Transients to Reveal Charge Loss Mechanism of Junction Solar Cells

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 نشر من قبل Qingbo Meng
 تاريخ النشر 2019
  مجال البحث فيزياء
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Electrical transients enabled by optical excitation and electric detection provide a distinctive opportunity to study the charge transport, recombination and even the hysteresis of a solar cell in a much wider time window ranging from nanoseconds to seconds. However, controversies on how to exploit these investigations to unravel the charge loss mechanism of the cell have been ongoing. Herein, a new methodology of quantifying the charge loss within the bulk absorber or at the interfaces and the defect properties of junction solar cells has been proposed after the conventional tail-state framework is firstly demonstrated to be unreasonable. This methodology has been successfully applied in the study of commercialized silicon and emerging Cu2ZnSn(S, Se)4 and perovskite solar cells herein and should be universal to other photovoltaic device systems with similar structures. Overall, this work provides an alluring route for comprehensive investigation of dynamic physics processes and charge loss mechanism of junction solar cells and possesses potential applications for other optoelectronic devices.



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