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The existence of polyexcitons, the $N$-body complexes of excitons for $N > 2$ in 3D bulk systems, has been controversial for more than 40 years since its first theoretical suggestion. We investigated the stability of fundamental excitonic complexes in diamond numerically with the stochastic variational method (SVM) and an explicitly correlated Gaussian (ECG) basis. The electron-hole many-body system is described by an effective mass Hamiltonian. Our model includes the effective mass anisotropy and multiple valley and band degrees of freedom. We show that the excitons, trions, biexcitons, charged biexcitons, and triexcitons are stable in diamond. Numerical calculations reproduce from 81% to 86% of the experimentally reported binding energies for neutral bound states.
The diamond and zinc-blende semiconductors are well-known and have been widely studied for decades. Yet, their electronic structure still surprises with unexpected topological properties of the valence bands. In this joint theoretical and experimenta
Two-dimensional electrons in AlAs quantum wells occupy multiple conduction-band minima at the X- points of the Brillouin zone. These valleys have large effective mass and g-factor compared to the stan-dard GaAs electrons, and are also highly anisotro
The double-resonance (DR) Raman process is a signature of all sp2 carbon material and provide fundamental information of the electronic structure and phonon dispersion in graphene, carbon nanotubes and different graphite-type materials. We have perfo
We study the problem of glassy relaxations in the presence of an external field in the highly controlled context of a spin-glass simulation. We consider a small spin glass in three dimensions (specifically, a lattice of size L=8, small enough to be e
We theoretically investigate how each orbital and valley play a role for high thermoelectric performance of SnSe. In the hole-doped regime, two kinds of valence band valleys contribute to its transport properties: one is the valley near the U-Z line,