اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدElectron correlation induced transverse delocalization and longitudinal confinement in excited states of phenyl-substituted polyacetylenes
62
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
Electron-electron interactions in general lead to both ground state and excited state confinement. We show, however, that in phenyl-substituted polyacetylenes electron-electron interactions cause enhanced delocalization of quasiparticles in the optically excited state from the backbone polyene chain into the phenyl groups, which in turn leads to enhanced confinement in the chain direction. This co-operative delocalization--confinement lowers the energy of the one-photon state and raises the relative energy of the lowest two-photon state. The two-photon state is slightly below the optical state in mono-phenyl substituted polyacetylenes, but above the optical state in di-phenyl substituted polyacetylenes, thereby explaining the strong photoluminescence of the latter class of materials. We present a detailed mechanism of the crossover in the energies of the one- and two-photon states in these systems. In addition, we calculate the optical absorption spectra over a wide wavelength region, and make specific predictions for the polarizations of low and high energy transitions that can be tested on oriented samples. Within existing theories of light emission from $pi$-conjugated polymers, strong photoluminescence should be restricted to materials whose optical gaps are larger than that of trans-polyacetylene. The present work show that conceptually at least, it is possible to have light emission from systems with smaller optical gaps.
قيم البحث
اقرأ أيضاً
We propose a realization of the one-dimensional random dimer model and certain N-leg generalizations using cold atoms in an optical lattice. We show that these models exhibit multiple delocalization energies that depend strongly on the symmetry prope
rties of the corresponding Hamiltonian and we provide analytical and numerical results for the localization length as a function of energy. We demonstrate that the N-leg systems possess similarities with their 1D ancestors but are demonstrably distinct. The existence of critical delocalization energies leads to dips in the momentum distribution which serve as a clear signal of the localization-delocalization transition. These momentum distributions are different for models with different group symmetries and are identical for those with the same symmetry.
Using a positive semidefinite operator technique one deduces exact ground states for a zig-zag hexagon chain described by a non-integrable Hubbard model with on-site repulsion. Flat bands are not present in the bare band structure, and the operators
$hat B^{dagger}_{mu,sigma}$ introducing the electrons into the ground state, are all extended operators and confined in the quasi 1D chain structure of the system. Consequently, increasing the number of carriers, the $hat B^{dagger}_{mu,sigma}$ operators become connected i.e. touch each other on several lattice sites. Hence the spin projection of the carriers becomes correlated in order to minimize the ground state energy by reducing as much as possible the double occupancy leading to a ferromagnetic ground state. This result demonstrates in exact terms in a many-body frame that the conjecture made at two-particle level by G. Brocks et al. [Phys.Rev.Lett.93,146405,(2004)] that the Coulomb interaction is expected to stabilize correlated magnetic ground states in acenes is clearly viable, and opens new directions in the search for routes in obtaining organic ferromagnetism. Due to the itinerant nature of the obtained ferromagnetic ground state, the systems under discussion may have also direct application possibilities in spintronics.
We study the (de)localization phenomena of one-component lattice fermions in spin backgrounds. The O(3) classical spin variables on sites fluctuate thermally through the ordinary nearest-neighbor coupling. Their complex two-component (CP$^1$-Schwinge
r boson) representation forms a composite U(1) gauge field on bond, which acts on fermions as a fluctuating hopping amplitude in a gauge invariant manner. For the case of antiferromagnetic (AF) spin coupling, the model has close relationship with the $t$-$J$ model of strongly-correlated electron systems. We measure the unfolded level spacing distribution of fermion energy eigenvalues and the participation ratio of energy eigenstates. The results for AF spin couplings suggest a possibility that, in two dimensions, all the energy eigenstates are localized. In three dimensions, we find that there exists a mobility edge, and estimate the critical temperature $T_{ss LD}(delta)$ of the localization-delocalization transition at the fermion concentration $delta$.
Variational methods have proven to be excellent tools to approximate ground states of complex many body Hamiltonians. Generic tools like neural networks are extremely powerful, but their parameters are not necessarily physically motivated. Thus, an e
fficient parametrization of the wave-function can become challenging. In this letter we introduce a neural-network based variational ansatz that retains the flexibility of these generic methods while allowing for a tunability with respect to the relevant correlations governing the physics of the system. We illustrate the success of this approach on topological, long-range correlated and frustrated models. Additionally, we introduce compatible variational optimization methods for exploration of low-lying excited states without symmetries that preserve the interpretability of the ansatz.
The non-equilibrium dynamics of matter excited by light may produce electronic phases that do not exist in equilibrium, such as laser-induced high-$T_c$ superconductivity. Here we simulate the dynamics of a metal driven at $t=0$ by a pump that excite
s dipole-active vibrational modes that couple quadratically to electrons, and study the evolution of its electronic and vibrational observables. We provide evidence for enhancement of local electronic correlations, including double occupancy, accompanied by rapid loss of long-range spatial phase coherence. Concurrently, the onsite vibrational reduced density matrix evolves from its initial coherent state to one with a predominantly diagonal structure whose distribution qualitatively resembles the coherent state Poisson character. This rapid loss of coherence controls the electronic dynamics as the system evolves towards a correlated electron-phonon long-time state. We show that a simple model based on an effective disorder potential generated by the oscillator dephasing dynamics for the electrons provides an explanation for the flattening in momentum of electronic correlations. Our results provide a basis within which to understand correlation dynamics of vibrationally coupled electrons in pump-probe experiments.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
