اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدAsymmetric temperature equilibration with heat flow from cold to hot in a quantum thermodynamic system
108
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
A model computational quantum thermodynamic network is constructed with two variable temperature baths coupled by a linker system, with an asymmetry in the coupling of the linker to the two baths. It is found in computational simulations that the baths come to thermal equilibrium at different bath energies and temperatures. In a sense, heat is observed to flow from cold to hot. A description is given in which a recently defined quantum entropy $S^Q_{univ}$ for a pure state universe continues to increase after passing through the classical equilibrium point of equal temperatures, reaching a maximum at the asymmetric equilibrium. Thus, a second law account $Delta S^Q_{univ} ge 0$ holds for the asymmetric quantum process. In contrast, a von Neumann entropy description fails to uphold the entropy law, with a maximum near when the two temperatures are equal, then a decrease $Delta S^{vN} < 0$ on the way to the asymmetric equilibrium.
قيم البحث
اقرأ أيضاً
For a thermodynamic system obeying both the equipartition theorem in high temperature and the third law in low temperature, the curve showing relationship between the specific heat and the temperature has two common behaviors: it terminates at zero w
hen the temperature is zero Kelvin and converges to a constant as temperature is higher and higher. Since it is always possible to find the characteristic temperature $T_{C}$ to mark the excited temperature as the specific heat almost reaches the equipartition value, it is reasonable to find a temperature in low temperature interval, complementary to $T_{C}$. The present study reports a possibly universal existence of the such a temperature $vartheta$, defined by that at which the specific heat falls textit{fastest} along with decrease of the temperature. For the Debye model of solids, above the temperature $vartheta$ the Debyes law starts to fail.
In systems described by the scattering theory, there is an upper bound, lower than Carnot, on the efficiency of steady-state heat to work conversion at a given output power. We show that interacting systems can overcome such bound and saturate, in th
e thermodynamic limit, the much more favorable linear-response bound. This result is rooted in the possibility for interacting systems to achieve the Carnot efficiency at the thermodynamic limit without delta-energy filtering, so that large efficiencies can be obtained without greatly reducing power.
The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a trade-off relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines. Here, we exam
ine the interplay of quantum system coherences and heat current fluctuations on the validity of the thermodynamics uncertainty relation in the quantum regime. To achieve the current statistics, we perform a full counting statistics simulation of the Redfield quantum master equation. We focus on steady-state quantum absorption refrigerators where nonzero coherence between eigenstates can either suppress or enhance the cooling power, compared with the incoherent limit. In either scenario, we find enhanced relative noise of the cooling power (standard deviation of the power over the mean) in the presence of system coherence, thereby corroborating the thermodynamic uncertainty relation. Our results indicate that fluctuations necessitate consideration when assessing the performance of quantum coherent thermal machines.
There is a renewed interest in the derivation of statistical mechanics from the dynamics of closed quantum systems. A central part of this program is to understand how far-from-equilibrium closed quantum system can behave as if relaxing to a stable e
quilibrium. Equilibration dynamics has been traditionally studied with a focus on the so-called quenches of large-scale many-body systems. Alternatively, we consider here the equilibration of a molecular model system describing the double proton transfer reaction in porphine. Using numerical simulations, we show that equilibration in this context indeed takes place and does so very rapidly ($sim !! 200$fs) for initial states induced by pump-dump laser pulse control with energies well above the synchronous tunneling barrier.
We study quench dynamics and equilibration in one-dimensional quantum hydrodynamics, which provides effective descriptions of the density and velocity fields in gapless quantum gases. We show that the information content of the large time steady stat
e is inherently connected to the presence of ballistically moving localised excitations. When such excitations are present, the system retains memory of initial correlations up to infinite times, thus evading decoherence. We demonstrate this connection in the context of the Luttinger model, the simplest quantum hydrodynamic model, and in the quantum KdV equation. In the standard Luttinger model, memory of all initial correlations is preserved throughout the time evolution up to infinitely large times, as a result of the purely ballistic dynamics. However nonlinear dispersion or interactions, when separately present, lead to spreading and delocalisation that suppress the above effect by eliminating the memory of non-Gaussian correlations. We show that, for any initial state that satisfies sufficient clustering of correlations, the steady state is Gaussian in terms of the bosonised or fermionised fields in the dispersive or interacting case respectively. On the other hand, when dispersion and interaction are simultaneously present, a semiclassical approximation suggests that localisation is restored as the two effects compensate each other and solitary waves are formed. Solitary waves, or simply solitons, are experimentally observed in quantum gases and theoretically predicted based on semiclassical approaches, but the question of their stability at the quantum level remains to a large extent an open problem. We give a general overview on the subject and discuss the relevance of our findings to general out of equilibrium problems.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
