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Rotational transitions in vibrationally excited AlO and TiO -- two possible precursors of dust -- were observed in the 300 GHz range (1 mm wavelength) towards the oxygen rich AGB stars R Dor and IK Tau with ALMA, and vibrationally excited AlO was observed towards the red supergiant VY CMa with the SMA. The $J=11 to 10$ transition of TiO in the $v=1~{rm{and}}~2$ levels, and the $N = 9 to 8$ transition in the $v=2$ level of AlO were identified towards R Dor; the $J=11 to 10$ line of TiO was identified in the $v=1$ level towards IK Tau; and two transitions in the $v=1~{rm{and}}~2$ levels of AlO were identified towards VY CMa. The newly-derived high vibrational temperature of TiO and AlO in R Dor of $1800 pm 200$ K, and prior measurements of the angular extent confirm that the majority of the emission is from a region within $lesssim2R_{star}$ of the central star. A full radiative transfer analysis of AlO in R Dor yielded a fractional abundance of $sim$3% of the solar abundance of Al. From a similar analysis of TiO a fractional abundance of $sim78$% of the solar abundance of Ti was found. The observations provide indirect evidence that TiO is present in a rotating disk close to the star. Further observations in the ground and excited vibrational levels are needed to determine whether AlO, TiO, and TiO$_2$ are seeds of the Al$_2$O$_3$ dust in R Dor, and perhaps in the gravitationally bound dust shells in other AGB stars with low mass loss rates.
The circumstellar ammonia (NH$_3$) chemistry in evolved stars is poorly understood. Previous observations and modelling showed that NH$_3$ abundance in oxygen-rich stars is several orders of magnitude above that predicted by equilibrium chemistry. In
We report the first detection of pure rotational transitions of TiO and TiO_2 at (sub-)millimeter wavelengths towards the red supergiant VY CMa. A rotational temperature, T_rot, of about 250 K was derived for TiO_2. Although T_rot was not well constr
Aluminium monoxide, AlO, is likely efficiently depleted from the gas around oxygen-rich evolved stars to form alumina clusters and dust seeds. Its presence in the extended atmospheres of evolved stars has been derived from optical spectroscopy. More
We report the serendipitous detection with ALMA of the vibrationally-excited pure-rotational CO transition $v=1, J=3-2$ towards five asymptotic giant branch (AGB) stars, $o$ Cet, R Aqr, R Scl, W Aql, and $pi^1$ Gru. The observed lines are formed in t
We investigate the occurrence of crystalline silicates in oxygen-rich evolved stars across a range of metallicities and mass-loss rates. It has been suggested that the crystalline silicate feature strength increases with increasing mass-loss rate, im