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The circumstellar ammonia (NH$_3$) chemistry in evolved stars is poorly understood. Previous observations and modelling showed that NH$_3$ abundance in oxygen-rich stars is several orders of magnitude above that predicted by equilibrium chemistry. In this article, we characterise the spatial distribution and excitation of NH$_3$ in the O-rich circumstellar envelopes (CSEs) of four diverse targets: IK Tau, VY CMa, OH 231.8+4.2, and IRC +10420 with multi-wavelength observations. We observed the 1.3-cm inversion line emission with the Very Large Array (VLA) and submillimetre rotational line emission with the Heterodyne Instrument for the Far-Infrared (HIFI) aboard Herschel from all four targets. For IK Tau and VY CMa, we observed the rovibrational absorption lines in the $ u_2$ band near 10.5 $mu$m with the Texas Echelon Cross Echelle Spectrograph (TEXES) at the NASA Infrared Telescope Facility (IRTF). We also attempted to search for the rotational transition within the $v_2=1$ state near 2 mm with the IRAM 30m Telescope towards IK Tau. Non-LTE radiative transfer modelling, including radiative pumping to the vibrational state, was carried out to derive the radial distribution of NH$_3$ in these CSEs. Our modelling shows that the NH$_3$ abundance relative to molecular hydrogen is generally of the order of $10^{-7}$, which is a few times lower than previous estimates that were made without considering radiative pumping and is at least 10 times higher than that in the C-rich CSE of IRC +10216. Incidentally, we also derived a new period of IK Tau from its $V$-band light curve. NH$_3$ is again detected in very high abundance in O-rich CSEs. Its emission mainly arises from localised spatial-kinematic structures that are probably denser than the ambient gas. Circumstellar shocks in the accelerated wind may contribute to the production of NH$_3$. (Abridged abstract)
The HIFI instrument on board of the Herschel Space Observatory (HSO) has been very successful in detecting molecular lines from circumstellar envelopes around evolved stars, like massive red supergiants, Asymptotic Giant Branch (AGB) and post-AGB sta
In order to determine the composition of the dust in the circumstellar envelopes of oxygen-rich asymptotic giant branch (AGB) stars we have computed a grid of modust radiative-transfer models for a range of dust compositions, mass-loss rates, dust sh
Aluminium monoxide, AlO, is likely efficiently depleted from the gas around oxygen-rich evolved stars to form alumina clusters and dust seeds. Its presence in the extended atmospheres of evolved stars has been derived from optical spectroscopy. More
Rotational transitions in vibrationally excited AlO and TiO -- two possible precursors of dust -- were observed in the 300 GHz range (1 mm wavelength) towards the oxygen rich AGB stars R Dor and IK Tau with ALMA, and vibrationally excited AlO was obs
For decades ever since the early detection in the 1990s of the emission spectral features of crystalline silicates in oxygen-rich evolved stars, there is a long-standing debate on whether the crystallinity of the silicate dust correlates with the ste