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Work extraction from the Gibbs ensemble by a cyclic operation is impossible, as represented by the second law of thermodynamics. On the other hand, the eigenstate thermalization hypothesis (ETH) states that just a single energy eigenstate can describe a thermal equilibrium state. Here we attempt to unify these two perspectives and investigate the second law at the level of individual energy eigenstates, by examining the possibility of extracting work from a single energy eigenstate. Specifically, we performed numerical exact diagonalization of a quench protocol of local Hamiltonians and evaluated the number of work-extractable energy eigenstates. We found that it becomes exactly zero in a finite system size, implying that a positive amount of work cannot be extracted from any energy eigenstate, if one or both of the pre- and the post-quench Hamiltonians are non-integrable. We argue that the mechanism behind this numerical observation is based on the ETH for a non-local observable. Our result implies that quantum chaos, characterized by non-integrability, leads to a stronger version of the second law than the conventional formulation based on the statistical ensembles.
We experimentally realize protocols that allow to extract work beyond the free energy difference from a single electron transistor at the single thermodynamic trajectory level. With two carefully designed out-of-equilibrium driving cycles featuring k
We use exact diagonalization to study the eigenstate thermalization hypothesis (ETH) in the quantum dimer model on the square and triangular lattices. Due to the nonergodicity of the local plaquette-flip dynamics, the Hilbert space, which consists of
Under unitary time evolution, expectation values of physically reasonable observables often evolve towards the predictions of equilibrium statistical mechanics. The eigenstate thermalization hypothesis (ETH) states that this is also true already for
The local quench of a Fermi gas, giving rise to the Fermi edge singularity and the Anderson orthogonality catastrophe, is a rare example of an analytically tractable out of equilibrium problem in condensed matter. It describes the universal physics w
We discuss work performed on a quantum two-level system coupled to multiple thermal baths. To evaluate the work, a measurement of photon exchange between the system and the baths is envisioned. In a realistic scenario, some photons remain unrecorded