اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدSuperconductivity and multiple pressure-induced phases in BaPt$_2$As$_2$
301
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
The newly discovered BaPt$_2$As$_2$ shows a structural distortion at around 275~K, followed by the emergence of superconductivity at lower temperatures. Here we identify the presence of charge density wave (CDW) order at room temperature and ambient pressure using single crystal x-ray diffraction, with both a superlattice and an incommensurate modulation, where there is a change of the superlattice structure below $simeq$ 275~K. Upon applying pressure, BaPt$_2$As$_2$ shows a rich temperature-pressure phase diagram with multiple pressure-induced transitions at high temperatures, the emergence or disappearance of which are correlated with sudden changes in the superconducting transition temperature $T_c$. These findings demonstrate that BaPt$_2$As$_2$ is a promising new system for studying competing interactions and the relationship between high-temperature electronic instabilities and superconductivity.
قيم البحث
اقرأ أيضاً
We successfully synthesized the BaPt$_2$As$_2$ single crystals and studied their structural and physical properties at low temperatures. BaPt$_2$As$_2$ crystallizes in the CaBe$_2$Ge$_2$-type tetragonal structure (P4/nmm) at room temperature and unde
rgoes a first-order structural transition at $T_Ssimeq 275$ K, which is likely associated with a charge-density-wave (CDW) instability. BCS-type superconductivity with two subsequent transitions at $T_{c1}=1.67$K and $T_{c2}$=1.33K are observed in this compound. Thus, BaPt$_2$As$_2$ may serve as a new system for studying the interplay of superconductivity and the CDW order.
A series of 122 phase BaFe$_{2-x}$Ni$_x$As$_2$ ($x$ = 0, 0.055, 0.096, 0.18, 0.23) single crystals were grown by self flux method and a dome-like Ni doping dependence of superconducting transition temperature is discovered. The transition temperature
$T_c^{on}$ reaches a maximum of 20.5 K at $x$ = 0.096, and it drops to below 4 K as $x$ $geq$ 0.23. The negative thermopower in the normal state indicates that electron-like charge carrier indeed dominates in this system. This Ni-doped system provides another example of superconductivity induced by electron doping in the 122 phase.
We have carried out high-field resistivity measurements up to 27,T in EuFe$_2$As$_2$ at $P$,=,2.5,GPa, a virtually optimal pressure for the $P$-induced superconductivity, where $T_mathrm{c}$,=,30,K. The $B_mathrm{c2}-T_mathrm{c}$ phase diagram has be
en constructed in a wide temperature range with a minimum temperature of 1.6 K ($approx 0.05 times T_mathrm{c}$), for both $B parallel ab$ ($B_mathrm{c2}^mathrm{ab}$) and $B parallel c$ ($B_mathrm{c2}^mathrm{c}$). The upper critical fields $B_mathrm{c2}^mathrm{ab}$(0) and $B_mathrm{c2}^mathrm{c}$(0), determined by the onset of resistive transitions, are 25 T and 22 T, respectively, which are significantly smaller than those of other Fe-based superconductors with similar values of $T_mathrm{c}$. The small $B_mathrm{c2}(0)$ values and the $B_mathrm{c2}(T)$ curves with positive curvature around 20 K can be explained by a multiple pair-breaking model that includes the exchange field due to the magnetic Eu$^{2+}$ moments. The anisotropy parameter, $Gamma=B_mathrm{c2}^{ab}/B_mathrm{c2}^{c}$, in EuFe$_2$As$_2$ at low temperatures is comparable to that of other 122 Fe-based systems.
The crystal structure, superconducting properties, and electronic structure of a novel superconducting 122-type antimonide, BaPt$_2$Sb$_2$, have been investigated by measurements of powder X-ray diffraction patterns, electrical resistivity, ac magnet
ic susceptibility, specific heat as well as ab-initio calculations. This material crystallizes in a new-type of monoclinic variant of the CaBe$_2$Ge$_2$-type structure, in which Pt$_2$Sb$_2$ layers consisting of PtSb$_4$ tetrahedra and Sb$_2$Pt$_2$ layers consisting of SbPt$_4$ tetrahedra are stacked alternatively and Ba atoms are located between the layers. Measurements of electrical resistivity, ac magnetic susceptibility and specific heat revealed that BaPt$_2$Sb$_2$ is a superconducting material with a $T_{rm c}$ of 1.8 K. The electronic heat capacity coefficient $gamma_{rm n}$ and Debye temperature $theta_{rm D}$ were 8.6(2) mJ/mol K$^2$ and 146(4) K, where the figures in parentheses represent the standard deviation. The upper critical field $mu_{rm 0}H_{rm c2}(0)$ and the Ginzburg-Landau coherent length $xi(0)$ were determined to be 0.27 T and 35 nm. Calculations showed that it has two three-dimensional Fermi surfaces (FSs) and two two-dimensional FSs, leading to anisotropic transport properties. The d-states of the Pt atoms in the Pt2Sb2 layers mainly contribute to $N(E_{rm F})$. A comparison between experimental and calculated results indicates that BaPt$_2$Sb$_2$ is a superconducting material with moderate coupling.
We report the discovery of two-phase unconventional superconductivity in CeRh$_2$As$_2$. Using thermodynamic probes, we establish that the superconducting critical field of its high-field phase is as high as 14 T, remarkable in a material whose trans
ition temperature is 0.26 K. Furthermore, a $c$-axis field drives a transition between two different superconducting phases. In spite of the fact that CeRh$_2$As$_2$ is globally centrosymmetric, we show that local inversion-symmetry breaking at the Ce sites enables Rashba spin-orbit coupling to play a key role in the underlying physics. More detailed analysis identifies the transition from the low- to high-field states to be associated with one between states of even and odd parity.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
