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We investigate the limits of effectiveness of classical spin simulations for predicting free induction decays (FIDs) measured by solid-state nuclear magnetic resonance (NMR) on systems of quantum nuclear spins. The specific limits considered are associated with the range of interaction, the size of individual quantum spins and the long-time behavior of the FID signals. We compare FIDs measured or computed for lattices of quantum spins (mainly spins 1/2) with the FIDs computed for the corresponding lattices of classical spins. Several cases of excellent quantitative agreement between quantum and classical FIDs are reported along with the cases of gradually decreasing quality of the agreement. We formulate semi-empirical criteria defining the situations, when classical simulations are expected to accurately reproduce quantum FIDs. Our findings indicate that classical simulations may be a quantitatively accurate tool of first principles calculations for a broad class of macroscopic systems, where individual quantum microscopic degrees of freedom are far from the classical limit.
We consider the effect of non-secular resonances for interacting nuclear spins in solids which were predicted theoretically to exist in the presence of strong static and strong radio-frequency magnetic fields. These resonances imply corrections to th
Recently developed quantum algorithms suggest that in principle, quantum computers can solve problems such as simulation of physical systems more efficiently than classical computers. Much remains to be done to implement these conceptual ideas into a
We investigate the evolution of entanglement in multiple-quantum (MQ) NMR experiments in crystals with pairs of close nuclear spins-1/2. The initial thermodynamic equilibrium state of the system in a strong external magnetic field evolves under the n
The time evolution of quantum many-body systems is one of the least understood frontiers of physics. The most curious feature of such dynamics is, generically, the growth of quantum entanglement with time to an amount proportional to the system size
A phenomenological theory of spin-lattice relaxation of multiple-quantum coherences in systems of two dipolar coupled spins at low temperatures is developed. Intensities of multiple-quantum NMR coherences depending on the spin-lattice relaxation time