اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدThe effect of spin-lattice relaxation on multiple-quantum NMR coherences in solids
147
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
A phenomenological theory of spin-lattice relaxation of multiple-quantum coherences in systems of two dipolar coupled spins at low temperatures is developed. Intensities of multiple-quantum NMR coherences depending on the spin-lattice relaxation time are obtained. It is shown that the theory is also applicable to finite spin chains when the approximation of nearest neighbour interaction is used. An application of this theory to an estimation of the influence of decoherence processes on quantum entanglement and its fluctuations is briefly discussed.
قيم البحث
اقرأ أيضاً
Dymanics of spin dimers in multiple quantum NMR experiment is studied on the 5-qubit superconducting quantum processor of IBM {Quantum Experience} for the both {pure} ground and thermodynamic equilibrium (mixed) initial states. The work can be consid
ered as a first step towards an application of quantum computers to solving problems of magnetic resonance. This article is dedicated to Prof. Klaus Mobius and Prof. Kev Salikhov on the occasion of their 85th birthdays.
A general expression is derived for the dipolar NMR spin-lattice relaxation rate $1/T_1$ of a system exhibiting Brownian dynamics in a discrete and finite configuration space. It is shown that this approach can be particularly useful to model the proton relaxation rate in molecular rotors.
A connection of the Wigner-Yanase skew information and multiple quantum (MQ) NMR coherences is considered at different temperatures and evolution times of nuclear spins with dipole-dipole interactions in MQ NMR experiments in solids. It is shown that
the Wigner-Yanase skew information at temperature $T$ is equal to the double second moment of the MQ NMR spectrum at the double temperature for any evolution times. A comparison of the many-spin entanglement obtained with the Wigner-Yanase information and the Fisher information is conducted.
We investigate the limits of effectiveness of classical spin simulations for predicting free induction decays (FIDs) measured by solid-state nuclear magnetic resonance (NMR) on systems of quantum nuclear spins. The specific limits considered are asso
ciated with the range of interaction, the size of individual quantum spins and the long-time behavior of the FID signals. We compare FIDs measured or computed for lattices of quantum spins (mainly spins 1/2) with the FIDs computed for the corresponding lattices of classical spins. Several cases of excellent quantitative agreement between quantum and classical FIDs are reported along with the cases of gradually decreasing quality of the agreement. We formulate semi-empirical criteria defining the situations, when classical simulations are expected to accurately reproduce quantum FIDs. Our findings indicate that classical simulations may be a quantitatively accurate tool of first principles calculations for a broad class of macroscopic systems, where individual quantum microscopic degrees of freedom are far from the classical limit.
Quantum correlations are investigated theoretically in a two-spin system with the dipole-dipole interactions in the NMR multiple-pulse spin-locking experiments. We consider two schemes of the multiple-pulse spin-locking. The first scheme consists of
$pi/2$-pulses only and the delays between the pulses can differ. The second scheme contains $varphi$-pulses ($0<varphi<pi$) and has equal delays between them. We calculate entanglement for both schemes for an initial separable state. We show that entanglement is absent for the first scheme at equal delays between $pi/2$-pulses at arbitraty temperatures. Entanglement emerges after several periods of the pulse sequence in the second scheme at $varphi=pi/4$ at milliKelvin temperatures. The necessary number of the periods increases with increasing temperature. We demonstrate the dependence of entanglement on the number of the periods of the multiple-pulse sequence. Quantum discord is obtained for the first scheme of the multiple-pulse spin-locking experiment at different temperatures.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
