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تسجيل مستخدم جديدUniversality of Block Copolymer Melts
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Simulations of five different coarse-grained models of symmetric diblock copolymer melts are compared to demonstrate a universal (i.e., model-independent) dependence of the free energy on the invariant degree of polymerization $overline{N}$, and to study universal properties of the order-disorder transition (ODT). The ODT appears to exhibit two regimes: Systems of very long chains ($overline{N} gtrsim 10^{4}$) are well described by the Fredrickson-Helfand theory, which assumes weak segregation near the ODT. Systems of smaller but experimentally relevant values, $overline{N} lesssim 10^4$, undergo a transition between strongly segregated disordered and lamellar phases that, though universal, is not adequately described by any existing theory.
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