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Test area deformations are used to analyse vapour-liquid interfaces of Lennard-Jones particles by molecular dynamics simulation. For planar vapour-liquid interfaces the change in free energy is captured by the average of the corresponding change in energy, the leading-order contribution. This is consistent with the commonly used mechanical (pressure tensor) route for the surface tension. By contrast for liquid drops one finds a large second-order contribution associated with fluctuations in energy. Both the first- and second-order terms make comparable contributions, invalidating the mechanical relation for the surface tension of small drops. The latter is seen to increase above the planar value for drop radii of ~8 particle diameters, followed by an apparent weak maximum and slow decay to the planar limit, consistent with a small negative Tolman length.
In spite of its key role in compact star physics, the surface tension of quark matter is not well comprehended yet. In this work we analyze the behavior of the surface tension of three-flavor quark matter in the outer and inner core of cold deleptoni
We propose a methodology to measure the mechanical properties of membranes from their fluctuations and apply this to optical microscopy measurements of giant unilamellar vesicles of lipids. We analyze the effect of the projection of thermal shape und
In a reaction-diffusion system, fluctuations in both diffusion and reaction events, have important effects on the steady-state statistics of the system. Here, we argue through extensive lattice simulations, mean-field type arguments, and the Doi-Peli
For a wide range of modern soft functional materials the selective transport of sub-nanometer-sized molecules (`penetrants) through a stimuli-responsive polymeric membrane is key to the desired function. In this study, we investigate the diffusion pr
Surface stress and surface energy are two fundamental parameters that determine the surface properties of any material. While it is commonly believed that the surface stress and surface energy of liquids are identical, the relationship between the tw