اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدReversible A <-> B reaction - diffusion process with initially mixed reactants: boundary layer function approach
174
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
The reversible A <-> B reaction-diffusion process, when species A and B are initially mixed and diffuse with different diffusion coefficients, is investigated using the boundary layer function method. It is assumed that the ratio of the characteristic time of the reaction to the characteristic time of diffusion is taken as a small parameter of the task. It was shown that diffusion-reaction process can be considered as a quasi-equilibrium process. Despite this fact the contribution of the reaction in changes of the species concentration is comparable with the diffusion contributions. Moreover the ratios of the reaction and diffusion contributions are independent of time and coordinate. The dependence of the reaction rate on the initial species distribution is analyzed. It was firstly obtained that the number of the reaction zones is determined by the initial conditions and changes with time. The asymptotic long-time behaviour of the reaction rate also dependents on the initial distribution.
قيم البحث
اقرأ أيضاً
We propose the deterministic rate equation of three-species in the reaction - diffusion system. For this case, our purpose is to carry out the decay process in our three-species reaction-diffusion model of the form $A+B+Cto D$. The particle density a
nd the global reaction rate are also shown analytically and numerically on a two-dimensional square lattice with the periodic boundary conditions. Especially, the crossover of the global reaction rate is discussed in both early-time and long-time regimes.
Diffusion is often accompanied by a reaction or sorption which can induce temperature inhomogeneities. Monte Carlo simulations of Lennard-Jones atoms in zeolite NaCaA are reported with a hot zone presumed to be created by a reaction. Our simulations
show that localised hot regions can alter both the kinetic and transport properties. Further, enhancement of the diffusion constant is greater for larger barrier height, a surprising result of considerable significance to many chemical and biological processes. We find an unanticipated coupling between reaction and diffusion due to the presence of hot zone in addition to that which normally exists via concentration.
We study the quantum quench in two coupled Tomonaga-Luttinger Liquids (TLLs), from the off-critical to the critical regime, relying on the conformal field theory approach and the known solutions for single TLLs. We consider a squeezed form of the ini
tial state, whose low energy limit is fixed in a way to describe a massive and a massless mode, and we encode the non-equilibrium dynamics in a proper rescaling of the time. In this way, we compute several correlation functions, which at leading order factorize into multipoint functions evaluated at different times for the two modes. Depending on the observable, the contribution from the massive or from the massless mode can be the dominant one, giving rise to exponential or power-law decay in time, respectively. Our results find a direct application in all the quench problems where, in the scaling limit, there are two independent massless fields: these include the Hubbard model, the Gaudin-Yang gas, and tunnel-coupled tubes in cold atoms experiments.
The change from the diffusion-limited to the reaction-limited cooperative behaviour in reaction-diffusion systems is analysed by comparing the universal long-time behaviour of the coagulation-diffusion process on a chain and on the Bethe lattice. On
a chain, this model is exactly solvable through the empty-interval method. This method can be extended to the Bethe lattice, in the ben-Avraham-Glasser approximation. On the Bethe lattice, the analysis of the Laplace-transformed time-dependent particle-density is analogous to the study of the stationary state, if a stochastic reset to a configuration of uncorrelated particles is added. In this stationary state logarithmic corrections to scaling are found, as expected for systems at the upper critical dimension. Analogous results hold true for the time-integrated particle-density. The crossover scaling functions and the associated effective exponents between the chain and the Bethe lattice are derived.
We consider the finite volume approximation of a reaction-diffusion system with fast reversible reaction. We deduce from a priori estimates that the approximate solution converges to the weak solution of the reaction-diffusion problem and satisfies e
stimates which do not depend on the chemical kinetics factor. It follows that the solution converges to the solution of a nonlinear diffusion problem, as the size of the volume elements and the time steps converge to zero while the kinetic rate tends to infinity.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
