اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدTheory of Viscosity of Confined Fluids in Small / Nano Systems (Theory of Interfacial Viscosity)
68
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
In this paper we present the molecular theory of viscosity of confined fluids in small or nano systems. This theory is also applicable to the interfacial viscosity. The basis of this research work is the Enskog kinetic theory and the Boussinesq constitutive equation. The Enskog kinetic theory is first transformed into a two-dimensional form. Then the potential energy collisional transfer part of the flux vector and the contribution to the surface pressure tensor due to collisional transfer are derived. Then the kinetic energy part of the flux vector and consequently the contribution to the surface pressure tensor due to flow of molecules is obtained. The microscopic expression of total surface pressure tensor is obtained by adding of the potential energy collisional transfer part and the kinetic energy contribution. Then the expression of interfacial shear and dilatational viscosities are concluded by the comparison of corresponding terms of the two microscopic and macroscopic surface pressure tensor equations. Finally the dimensionless forms of interfacial shear viscosity, interfacial dilatational viscosity and the surface tension equations are derived and they are plotted versus the reduced superficial number density.
قيم البحث
اقرأ أيضاً
The shear viscosity in the dilute regime of a model for confined granular matter is studied by simulations and kinetic theory. The model consists on projecting into two dimensions the motion of vibrofluidized granular matter in shallow boxes by modif
ying the collision rule: besides the restitution coefficient that accounts for the energy dissipation, there is a separation velocity that is added in each collision in the normal direction. The two mechanisms balance on average, producing stationary homogeneous states. Molecular dynamics simulations show that in the steady state the distribution function departs from a Maxwellian, with cumulants that remain small in the whole range of inelasticities. The shear viscosity normalized with stationary temperature presents a clear dependence with the inelasticity, taking smaller values compared to the elastic case. A Boltzmann-like equation is built and analyzed using linear response theory. It is found that the predictions show an excellent agreement with the simulations when the correct stationary distribution is used but a Maxwellian approximation fails in predicting the inelasticity dependence of the viscosity. These results confirm that transport coefficients depend strongly on the mechanisms that drive them to stationary states.
Relativistic high energy heavy ion collision cross sections have been interpreted in terms of almost ideal liquid droplets of nuclear matter. The experimental low viscosity of these nuclear fluids have been of considerable recent quantum chromodynami
c interest. The viscosity is here discussed in terms of the string fragmentation models wherein the temperature dependence of the nuclear fluid viscosity obeys the Vogel-Fulcher-Tammann law.
Transport properties of dense fluids are fundamentally challenging, because the powerful approaches of equilibrium statistical physics cannot be applied. Polar fluids compound this problem, because the long-range interactions preclude the use of a si
mple effect-diameter approach based solely on hard spheres. Here, we develop a kinetic theory for dipolar hard-sphere fluids that is valid up to high density. We derive a mathematical approximation for the radial distribution function at contact directly from the equation of state, and use it to obtain the shear viscosity. We also perform molecular-dynamics simulations of this system and extract the shear viscosity numerically. The theoretical results compare favorably to the simulations.
We study shear stress relaxation for a gelling melt of randomly crosslinked, interacting monomers. We derive a lower bound for the static shear viscosity $eta$, which implies that it diverges algebraically with a critical exponent $kge 2 u-beta$. Her
e, $ u$ and $beta$ are the critical exponents of percolation theory for the correlation length and the gel fraction. In particular, the divergence is stronger than in the Rouse model, proving the relevance of excluded-volume interactions for the dynamic critical behaviour at the gel transition. Precisely at the critical point, our exact results imply a Mark-Houwink relation for the shear viscosity of isolated clusters of fixed size.
A mean-field density-functional model for three-phase equilibria in fluids (or other soft condensed matter) with two spatially varying densities is analyzed analytically and numerically. The interfacial tension between any two out of three thermodyna
mically coexisting phases is found to be captured by a surprisingly simple analytic expression that has a geometric interpretation in the space of the two densities. The analytic expression is based on arguments involving symmetries and invariances. It is supported by numerical computations of high precision and it agrees with earlier conjectures obtained for special cases in the same model. An application is presented to three-phase equilibria in the vicinity of a tricritical point. Using the interfacial tension expression and employing the field variables compatible with tricritical point scaling, the expected mean-field critical exponent is derived for the vanishing of the critical interfacial tension as a function of the deviation of the noncritical interfacial tension from its limiting value, upon approach to a critical endpoint in the phase diagram. The analytic results are again confirmed by numerical computations of high precision.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
