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We report Cu- and F-NMR studies on a four-layered high-temperature superconductor Ba2Ca3Cu4O8F2(0234F(2.0)) with apical fluorine (F-1), an undoped 55 K-superconductor with a nominal Cu2+ valence on average. We reveal that this compound exhibits the antiferromagnetism (AFM) with a Neel temperature TN=100 K despite being a Tc= 55 K-superconductor. Through a comparison with a related tri-layered cuprate Ba2Ca2Cu3O6F2 (0223F(2.0)), it is demonstrated that electrons are transferred from the inner plane (IP) to the outer plane (OP) in 0234F(2.0) and 0223F(2.0), confirming the self-doped high-temperature superconductivity (HTSC) having electron and hole doping in a single compound. Remarlably, uniform mixing of AFM and HTSC takes place in both the electron-doped OPs and the hole-doped IPs in 0234F(2.0).
In order to investigate the electronic state of Ce-free and Ce-underdoped high-Tc cuprates with the so-called T structure, we have performed muon-spin-relaxation (muSR) and specific-heat measurements of Ce-free T-La_1.8_Eu_0.2_CuO_4+d_ (T-LECO) polyc
In this review article, we show our recent results relating to the undoped (Ce-free) superconductivity in the electron-doped high-Tc cuprates with the so-called T structure. For an introduction, we briefly mention the characteristics of the electron-
We have performed a systematic angle-resolved photoemission study of as-grown and oxygen-reduced Pr$_{2-x}$Ce$_x$CuO$_4$ and Pr$_{1-x}$LaCe$_{x}$CuO$_4$ electron-doped cuprates. In contrast to the common belief, neither the band filling nor the band
We consider a model of the pseudogap specifically designed to describe the underdoped cuprates and which exhibits particle-hole asymmetry. The presence of electron pockets, besides the usual hole pockets, leads to the appearance of new vectors beyond
In order to understand the origin of superconductivity, it is crucial to ascertain the nature and origin of the primary carriers available to participate in pairing. Recent quantum oscillation experiments on high Tc cuprate superconductors have revea