The idea of magnetic monopoles in spin ice has enjoyed much success at intermediate temperatures, but at low temperatures a description in terms of monopole dynamics alone is insufficient. Recently, numerical simulations were used to argue that magne
tic impurities account for this discrepancy by introducing a magnetic equivalent of residual resistance in the system. Here we propose that oxygen deficiency is the leading cause of magnetic impurities in as-grown samples, and we determine the defect structure and magnetism in Y2Ti2O(7-delta) using diffuse neutron scattering and magnetization measurements. These defects are eliminated by oxygen annealing. The introduction of oxygen vacancies causes Ti4+ to transform to magnetic Ti3+ with quenched orbital magnetism, but the concentration is anomalously low. In the spin-ice material Dy2Ti2O7 we find that the same oxygen-vacancy defects suppress moments on neighbouring rare-earth sites, and that these magnetic distortions dramatically slow down the long-time monopole dynamics at sub-Kelvin temperatures.
We study topological order in a toric code in three spatial dimensions, or a 3+1D Z_2 gauge theory, at finite temperature. We compute exactly the topological entropy of the system, and show that it drops, for any infinitesimal temperature, to half it
s value at zero temperature. The remaining half of the entropy stays constant up to a critical temperature Tc, dropping to zero above Tc. These results show that topologically ordered phases exist at finite temperatures, and we give a simple interpretation of the order in terms of fluctuating strings and membranes, and how thermally induced point defects affect these extended structures. Finally, we discuss the nature of the topological order at finite temperature, and its quantum and classical aspects.
We study a quantum phase transition between a phase which is topologically ordered and one which is not. We focus on a spin model, an extension of the toric code, for which we obtain the exact ground state for all values of the coupling constant that
takes the system across the phase transition. We compute the entanglement and the topological entropy of the system as a function of this coupling constant, and show that the topological entropy remains constant all the way up to the critical point, and jumps to zero beyond it. Despite the jump in the topological entropy, the transition is second order as detected via any local observable.
We calculate exactly the von Neumann and topological entropies of the toric code as a function of system size and temperature. We do so for systems with infinite energy scale separation between magnetic and electric excitations, so that the magnetic
closed loop structure is fully preserved while the electric loop structure is tampered with by thermally excited electric charges. We find that the entanglement entropy is a singular function of temperature and system size, and that the limit of zero temperature and the limit of infinite system size do not commute. From the entanglement entropy we obtain the topological entropy, which is shown to drop to half its zero-temperature value for any infinitesimal temperature in the thermodynamic limit, and remains constant as the temperature is further increased. Such discontinuous behavior is replaced by a smooth decreasing function in finite-size systems. If the separation of energy scales in the system is large but finite, we argue that our results hold at small enough temperature and finite system size, and a second drop in the topological entropy should occur as the temperature is raised so as to disrupt the magnetic loop structure by allowing the appearance of free magnetic charges. We interpret our results as an indication that the underlying magnetic and electric closed loop structures contribute equally to the topological entropy (and therefore to the topological order) in the system. Since each loop structure emph{per se} is a classical object, we interpret the quantum topological order in our system as arising from the ability of the two structures to be superimposed and appear simultaneously.
