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We report the temperature dependence of the transport critical current density (Jc) in textured Sr1-xKxFe2As2/Fe (Sr122) tapes fabricated by an ex situ powder-in-tube process. Critical currents were measured in magnetic fields up to 0-15 T and/or the temperature range 4.2-30 K by using a dc four-probe method. It was found that textured Sr122 tapes heat-treated at low temperatures showed higher transport Jc performance due to much improved intergrain connections. At temperatures of 20 K, easily obtained using a cryocooler, Jc reached ~ 10^4 A/cm^2 in self field, which is the highest transport value of ferropnictide wires and tapes reported so far. Magneto-optical imaging observations further revealed significant and well distributed global Jc at 20 K in our tapes. These results demonstrate that 122 type superconducting tapes are promising for high-field applications at around 20 K.
A significant enhancement of Jc and Hirr in MgB2 tapes has been achieved by the in situ powder-in-tube method utilizing hollow carbon spheres (HCS) as dopants. At 4.2 K, the transport Jc for the 850C sintered samples reached 3.1x10^4, and 1.4x10^4 A/ cm^2 at 10 and 12 T, respectively, and were better than those of optimal nano-SiC doped tapes. Furthermore, the Hirr for doped sample was raised up to 16.8 T at 10 K due to the carbon substitution effect. The results demonstrate that HCS is one of the most promising dopants besides nano-carbon and SiC for the enhancement of current capacity for MgB2 in high fields.
We report on significant flux pinning enhancement in MgB2/Fe tapes that has been easily obtained by a simple and cheap route using acetone as both an efficient ball-milling medium and liquid additive through the in situ method. Results showed that th e highly reactive C released from the decomposition of the acetone substituted into B sites, accompanied by the grain refinement effect due to the acetone doping. At 4.2 K, the transport Jc for the 5 wt % acetone doped tapes sintered at 700C reached up to 2.4x10^4 A/cm^2 at 10 T, which is even higher than that of the nano-C added samples heated at 900C.
A safe, simple and easily scaleable one-step sintering method is proposed to fabricate newly discovered superconductors of SmO1-xFxFeAs. Superconducting transition with the onset temperature of 54.6 K and high critical fields Hc2(0) >=200 T were conf irmed in SmO1-xFxFeAs with x = 0.3. At 5 K and self field, critical current density Jc estimated from the magnetization hysteresis using the whole sample size and the average particle size reached 8.5x10^3 and 1.2x10^6 A/cm^2, respectively. Moreover, the Jc exhibited a very weak dependence on magnetic field. Microstructural characterizations revealed that the whole sample Jc improvement could be achieved by either perfect texture or optimization of fabrication process in this strongly-layered superconductor. Our results clearly demonstrated that one-step synthesis technique is unique and versatile and hence can be tailored easily for other rare earth derivatives of REFeAsO superconductors.
MgB2 is a promising superconductor for important large-scale applications for both high field magnets and cryocooler-cooled magnet operated at temperatures around 20 K. In this work, by utilizing C60 as a viable alternative dopant, we demonstrate a s imple and industrially scaleable rout that yields a 10-15-fold improvement in the in-high-field current densities of MgB2 tape conductors. For example, a Jc value higher than 4x10^4 A/cm^2 (4.2 K, 10 T), which exceeds that for NbTi superconductor, can be realized on the C60 doped MgB2 tapes. It is worth noting that this value is even higher than that fabricated using strict high energy ball milling technique under Ar atmosphere. At 20 K, Hirr was about 10 T for C60 doped MgB2 tapes. A large amount of nanometer-sized precipitates and grain boundaries were found in MgB2 matrix. The special physical and chemical characteristic of C60, in addition to its C containing intrinsic essence, is a key point in enhancing the superconducting performance of MgB2 tapes.
The effect of the quality of starting powders on the microstructure and superconducting properties of in-situ processed Fe-sheathed MgB2 tapes has been investigated. Three different types of commercial atomized spherical magnesium powder and two diff erent purities of amorphous boron powder were employed. When using the 10-micrometre magnesium as precursor powders, the Mg reacted with boron more uniformly and quickly, thus the uniformity of the fabricated MgB2 was improved and the grain size of the MgB2 was decreased, hence significant critical current density (Jc) enhancements were achieved for MgB2 tapes. Jc at 4.2 K for MgB2 tapes made from the 10 um Mg and high purity boron powders was at least a factor of ten higher than values measured for MgB2 samples made from all other starting powders. At 20 K, 5 T, the typical Jc values of the tapes were over 1.0x10^4 A/cm^2 and were much better than those of tape samples reported recently.
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