We identify that both the dynamic core polarization and dynamic orbital deformation are important in the orientation-dependent high-harmonic generation of CO molecules subjected to intense few cycle laser fields. These polarization dynamics allow for
the observation of strong orientation effects and dynamic minimum in the harmonic spectra. The generated attosecond pulses can be greatly affected by these multielectron effects. This work sheds light on future development of dynamic orbital imaging on attosecond time scale.
The ionization of two-active-electron systems by intense laser fields is investigated theoretically. In comparison with time-dependent Hartree-Fock and exact two electron simulation, we show that the ionization rate is overestimated in SAE approximat
ion. A modified single-active-electron model is formulated by taking into account of the dynamical core polarization. Applying the new approach to Ca atoms, it is found that the polarization of the core can be considered instantaneous and the large polarizability of the cation suppresses the ionization by 50% while the photoelectron cut-off energy increases slightly. The existed tunneling ionization formulation can be corrected analytically by considering core polarization.
The orientation-dependent strong-field ionization of CO molecules is investigated using the fully propagated three-dimensional time-dependent Hartree-Fock theory. The full ionization results are in good agreement with recent experiments. The comparis
ons between the full method and single active orbital (SAO) method show that although the core electrons are generally more tightly bounded and contribute little to the total ionization yields, their dynamics cannot be ignored, which effectively modify the behaviors of electrons in the highest occupied molecular orbital. By incorporating it into the SAO method, we identify that the dynamic core polarization plays an important role in the strong-field tunneling ionization of CO molecules, which is helpful for future development of tunneling ionization theory of molecules beyond single active electron approximation.
A generalization of non-perturbative QED model for high harmonic generation is developed for the multi-mode optical field case. By introducing classical-field-dressed quantized Volkov states analytically, a formula to calculate HHG for hydrogen-like
atom in ultrashort intense laser pulse is obtained, which has a simple intuitive interpretation. The dressed state QED model indicates a new perspective to understand HHG, for example, the presence of the weak even-order harmonic photons, which has been verified by both theoretical analysis and numerical computation. Long wavelength approximation and strong field approximation are involved in the development of the formalism.
