Methylammonium lead iodide (CH3NH3PbI3) based solar cells have shown impressive power conversion efficiencies of above 20%. However, the microscopic mechanism of the high photovoltaic performance is yet to be fully understood. Particularly, the dynam
ics of CH3NH3+ cations and their impact on relevant processes such as charge recombination and exciton dissociation are still poorly understood. Here, using elastic and quasi-elastic neutron scattering techniques and group theoretical analysis, we studied rotational modes of the CH3NH3+ cation in CH3NH3PbI3. Our results show that, in the cubic (T > 327K) and tetragonal (165K < T < 327K) phases, the CH3NH3+ ions exhibit four-fold rotational symmetry of the C-N axis (C4) along with three-fold rotation around the C-N axis (C3), while in orthorhombic phase (T < 165K) only C3 rotation is present. Around room temperature, the characteristic relaxation times for the C4 rotation is found to be ps while for the C3 rotation ps. The -dependent rotational relaxation times were fitted with Arrhenius equations to obtain activation energies. Our data show a close correlation between the C4 rotational mode and the temperature dependent dielectric permittivity. Our findings on the rotational dynamics of CH3NH3+ and the associated dipole have important implications on understanding the low exciton binding energy and slow charge recombination rate in CH3NH3PbI3 which are directly relevant for the high solar cell performance.
SN 2014J in M82 is the closest detected Type Ia supernova (SN Ia) in at least 28 years and perhaps in 410 years. Despite its small distance of 3.3 Mpc, SN 2014J is surprisingly faint, peaking at V = 10.6 mag, and assuming a typical SN Ia luminosity,
we infer an observed visual extinction of A_V = 2.0 +/- 0.1 mag. But this picture, with R_V = 1.6 +/- 0.2, is too simple to account for all observations. We combine 10 epochs (spanning a month) of HST/STIS ultraviolet through near-infrared spectroscopy with HST/WFC3, KAIT, and FanCam photometry from the optical to the infrared and 9 epochs of high-resolution TRES spectroscopy to investigate the sources of extinction and reddening for SN 2014J. We argue that the wide range of observed properties for SN 2014J is caused by a combination of dust reddening, likely originating in the interstellar medium of M82, and scattering off circumstellar material. For this model, roughly half of the extinction is caused by reddening from typical dust (E(B-V ) = 0.45 mag and R_V = 2.6) and roughly half by scattering off LMC-like dust in the circumstellar environment of SN 2014J.
We present griz light curves of 146 spectroscopically confirmed Type Ia Supernovae ($0.03 < z <0.65$) discovered during the first 1.5 years of the Pan-STARRS1 Medium Deep Survey. The Pan-STARRS1 natural photometric system is determined by a combinati
on of on-site measurements of the instrument response function and observations of spectrophotometric standard stars. We find that the systematic uncertainties in the photometric system are currently 1.2% without accounting for the uncertainty in the HST Calspec definition of the AB system. A Hubble diagram is constructed with a subset of 113 out of 146 SNe Ia that pass our light curve quality cuts. The cosmological fit to 310 SNe Ia (113 PS1 SNe Ia + 222 light curves from 197 low-z SNe Ia), using only SNe and assuming a constant dark energy equation of state and flatness, yields $w=-1.120^{+0.360}_{-0.206}textrm{(Stat)} ^{+0.269}_{-0.291}textrm{(Sys)}$. When combined with BAO+CMB(Planck)+$H_0$, the analysis yields $Omega_{rm M}=0.280^{+0.013}_{-0.012}$ and $w=-1.166^{+0.072}_{-0.069}$ including all identified systematics (see also Scolnic et al. 2014). The value of $w$ is inconsistent with the cosmological constant value of $-1$ at the 2.3$sigma$ level. Tension endures after removing either the BAO or the $H_0$ constraint, though it is strongest when including the $H_0$ constraint. If we include WMAP9 CMB constraints instead of those from Planck, we find $w=-1.124^{+0.083}_{-0.065}$, which diminishes the discord to $<2sigma$. We cannot conclude whether the tension with flat $Lambda$CDM is a feature of dark energy, new physics, or a combination of chance and systematic errors. The full Pan-STARRS1 supernova sample with $sim!!$3 times as many SNe should provide more conclusive results.
We report on our discovery and observations of the Pan-STARRS1 supernova (SN) PS1-12sk, a transient with properties that indicate atypical star formation in its host galaxy cluster or pose a challenge to popular progenitor system models for this clas
s of explosion. The optical spectra of PS1-12sk classify it as a Type Ibn SN (c.f. SN 2006jc), dominated by intermediate-width (3x10^3 km/s) and time variable He I emission. Our multi-wavelength monitoring establishes the rise time dt = 9-23 days and shows an NUV-NIR SED with temperature > 17x10^3 K and a peak rise magnitude of Mz = -18.9 mag. SN Ibn spectroscopic properties are commonly interpreted as the signature of a massive star (17 - 100 M_sun) explosion within a He-enriched circumstellar medium. However, unlike previous Type Ibn supernovae, PS1-12sk is associated with an elliptical brightest cluster galaxy, CGCG 208-042 (z = 0.054) in cluster RXC J0844.9+4258. The expected probability of an event like PS1-12sk in such environments is low given the measured infrequency of core-collapse SNe in red sequence galaxies compounded by the low volumetric rate of SN Ibn. Furthermore, we find no evidence of star formation at the explosion site to sensitive limits (Sigma Halpha < 2x10^-3 M_sun/yr/kpc^2). We therefore discuss white dwarf binary systems as a possible progenitor channel for SNe Ibn. We conclude that PS1-12sk represents either a fortuitous and statistically unlikely discovery, evidence for a top-heavy IMF in galaxy cluster cooling flow filaments, or the first clue suggesting an alternate progenitor channel for Type Ibn SNe.
We describe observed properties of the Type Iax class of supernovae (SNe Iax), consisting of SNe observationally similar to its prototypical member, SN 2002cx. The class currently has 25 members, and we present optical photometry and/or optical spect
roscopy for most of them. SNe Iax are spectroscopically similar to SNe Ia, but have lower maximum-light velocities (2000 < |v| < 8000 km/s), typically lower peak magnitudes (-14.2 > M_V,peak > -18.9 mag), and most have hot photospheres. Relative to SNe Ia, SNe Iax have low luminosities for their light-curve shape. There is a correlation between luminosity and light-curve shape, similar to that of SNe Ia, but offset from that of SNe Ia and with larger scatter. Despite a host-galaxy morphology distribution that is highly skewed to late-type galaxies without any SNe Iax discovered in elliptical galaxies, there are several indications that the progenitor stars are white dwarfs (WDs): evidence of C/O burning in their maximum-light spectra, low ejecta masses, strong Fe lines in their late-time spectra, a lack of X-ray detections, and deep limits on massive stars and star formation at the SN sites. However, two SNe Iax show strong He lines in their spectra. The progenitor system and explosion model that best fits all of the data is a binary system of a C/O WD that accretes matter from a He star and has a significant deflagration. At least some of the time, this explosion will not disrupt the WD. We estimate that in a given volume there are 31^+17_-13 SNe Iax for every 100 SNe Ia, and for every 1 M_sun of iron generated by SNe Ia at z = 0, SNe Iax generate 0.052^+0.017_-0.014 M_sun. Being the largest class of peculiar SNe, thousands of SNe Iax will be discovered by LSST. Future detailed observations of SNe Iax should further our understanding of both their progenitor systems and explosions as well as those of SNe Ia.
We present the first maximum-light ultraviolet (UV) through near-infrared (NIR) Type Ia supernova (SN Ia) spectrum. This spectrum of SN 2011iv was obtained nearly simultaneously by the Hubble Space Telescope at UV/optical wavelengths and the Magellan
Baade telescope at NIR wavelengths. These data provide the opportunity to examine the entire maximum-light SN Ia spectral-energy distribution. Since the UV region of a SN Ia spectrum is extremely sensitive to the composition of the outer layers of the explosion, which are transparent at longer wavelengths, this unprecedented spectrum can provide strong constraints on the composition of the SN ejecta, and similarly the SN explosion and progenitor system. SN 2011iv is spectroscopically normal, but has a relatively fast decline (Delta m_15 (B) = 1.69 +/- 0.05 mag). We compare SN 2011iv to other SNe Ia with UV spectra near maximum light and examine trends between UV spectral properties, light-curve shape, and ejecta velocity. We tentatively find that SNe with similar light-curve shapes but different ejecta velocities have similar UV spectra, while those with similar ejecta velocities but different light-curve shapes have very different UV spectra. Through a comparison with explosion models, we find that both a solar-metallicity W7 and a zero-metallicity delayed-detonation model provide a reasonable fit to the spectrum of SN 2011iv from the UV to the NIR.
In this first paper in a series we present 1298 low-redshift (zleq0.2) optical spectra of 582 Type Ia supernovae (SNe Ia) observed from 1989 through 2008 as part of the Berkeley SN Ia Program (BSNIP). 584 spectra of 199 SNe Ia have well-calibrated li
ght curves with measured distance moduli, and many of the spectra have been corrected for host-galaxy contamination. Most of the data were obtained using the Kast double spectrograph mounted on the Shane 3 m telescope at Lick Observatory and have a typical wavelength range of 3300-10,400 Ang., roughly twice as wide as spectra from most previously published datasets. We present our observing and reduction procedures, and we describe the resulting SN Database (SNDB), which will be an online, public, searchable database containing all of our fully reduced spectra and companion photometry. In addition, we discuss our spectral classification scheme (using the SuperNova IDentification code, SNID; Blondin & Tonry 2007), utilising our newly constructed set of SNID spectral templates. These templates allow us to accurately classify our entire dataset, and by doing so we are able to reclassify a handful of objects as bona fide SNe Ia and a few other objects as members of some of the peculiar SN Ia subtypes. In fact, our dataset includes spectra of nearly 90 spectroscopically peculiar SNe Ia. We also present spectroscopic host-galaxy redshifts of some SNe Ia where these values were previously unknown. [Abridged]
We report on our progress in computing the excitation spectrum in Lattice QCD. We focus on the isospin 0, 1 and 2 channels using the stochastic LapH algorithm for the quark propagators. For the isospin-0 channel, a new glueball operator constructed f
rom the stochastic LapH operator is included in the variational basis along with the isoscalar meson and pi-pi operators. A representative signal for each channel is presented and the feasibility of extending the calculations to larger lattices is discussed.
Supernova (SN) 2009ig was discovered 17 hours after explosion by the Lick Observatory Supernova Search, promptly classified as a normal Type Ia SN (SN Ia), peaked at V = 13.5 mag, and was equatorial, making it one of the foremost supernovae for inten
sive study in the last decade. Here, we present ultraviolet (UV) and optical observations of SN 2009ig, starting about 1 day after explosion until around maximum brightness. Our data include excellent UV and optical light curves, 25 premaximum optical spectra, and 8 UV spectra, including the earliest UV spectrum ever obtained of a SN Ia. SN 2009ig is a relatively normal SN Ia, but does display high-velocity ejecta - the ejecta velocity measured in our earliest spectra (v ~ -23,000 km/s for Si II 6355) is the highest yet measured in a SN Ia. The spectral evolution is very dramatic at times earlier than 12 days before maximum brightness, but slows after that time. The early-time data provide a precise measurement of 17.13 +/- 0.07 days for the SN rise time. The optical color curves and early-time spectra are significantly different from template light curves and spectra used for light-curve fitting and K-corrections, indicating that the template light curves and spectra do not properly represent all Type Ia supernovae at very early times. In the age of wide-angle sky surveys, SNe like SN 2009ig that are nearby, bright, well positioned, and promptly discovered will still be rare. As shown with SN 2009ig, detailed studies of single events can provide significantly more information for testing systematic uncertainties related to SN Ia distance estimates and constraining progenitor and explosion models than large samples of more distant SNe.
We present observations of supernova (SN) 2008ge, which is spectroscopically similar to the peculiar SN 2002cx, and its pre-explosion site that indicate that its progenitor was probably a white dwarf. NGC 1527, the host galaxy of SN 2008ge, is an S0
galaxy with no evidence of star formation or massive stars. Astrometrically matching late-time imaging of SN 2008ge to pre-explosion HST imaging, we constrain the luminosity of the progenitor star. Since SN 2008ge has no indication of hydrogen or helium in its spectrum, its progenitor must have lost its outer layers before exploding, requiring that it be a white dwarf, a Wolf-Rayet star, or a lower-mass star in a binary system. Observations of the host galaxy show no signs of individual massive stars, star clusters, or H II regions at the SN position or anywhere else, making a Wolf-Rayet progenitor unlikely. Late-time spectroscopy of SN 2008ge show strong [Fe II] lines with large velocity widths compared to other members of this class at similar epochs. These previously unseen features indicate that a significant amount of the SN ejecta is Fe (presumably the result of radioactive decay of 56Ni generated in the SN), further supporting a thermonuclear explosion. Placing the observations of SN 2008ge in the context of observations of other objects in the class of SN, we suggest that the progenitor was most likely a white dwarf.
