Condensation of dust in the ejecta of type II-P supernovae

Aims: We study the production of dust in Type II-P supernova by coupling the gas-phase chemistry to the dust nucleation and condensation phases. We consider two supernova progenitor masses with homogeneous and clumpy ejecta to assess the chemical type and quantity of dust that forms. Grain size distributions are derived as a function of post-explosion time. Methods: The chemistry of the gas phase and the simultaneous formation of dust clusters are described by a chemical network. The formation of key species (CO, SiO) and dust clusters of silicates, alumina, silica, metal carbides and sulphides, pure metals, and amorphous carbon is considered. The master equations describing the chemistry of the nucleation phase are coupled to a dust condensation formalism based on Brownian coagulation. Results: Type II-P supernovae produce dust grains of various chemical compositions and size distributions as a function of time. The grain size distributions gain in complexity with time, are slewed towards large grains, and differ from the usual MRN power-law distribution used for interstellar dust. Gas density enhancements in the form of clumps strongly affect the dust chemical composition and the grain size distributions. Silicates and pure metallic grains are highly dependent on clumpiness. Specifically, clumpy ejecta produce grains over 0.1 micron, and the final dust mass reaches 0.14 Msun. Conversely, carbon and alumina dust masses are controlled by the mass yields of alumina and carbon in the zones where the dust is produced. Several dust components form in the ejecta and the total dust mass gradually builds up over a time span of 3 to 5 years post-outburst. This gradual growth provides a possible explanation for the discrepancy between the small dust masses formed at early post-explosion times and the high dust masses derived from recent observations of supernova remnants.

Dust production in Supernovae

Supernovae have long been proposed to be efficient dust producers in galaxies. Observations in the mid-infrared indicate that dust forms a few hundred days after the stellar explosion. Yet, the chemical type and the amount of dust produced by supernovae are not well quantified. In this review, we summarise our current knowledge of dust formation derived from observations of supernovae, present the various theoretical models on dust synthesis and their predictions, and discuss these results in the context of the most recent observations of dust in supernova remnants.

Molecules and dust in Cas A: I - Synthesis in the supernova phase and processing by the reverse shock in the clumpy remnant

Aims: We study the chemistry of the Type IIb supernova ejecta that led to the Cas A supernova remnant to assess the chemical type and quantity of dust that forms and evolves in the remnant phase. We later model a dense oxygen-rich ejecta knot that is crossed by the reverse shock in Cas A to study the evolution of the clump gas phase and the possibility to reform dust clusters in the post-reverse shock gas. Methods: A chemical network including all processes efficient at high gas temperatures and densities is considered. The formation of key bimolecular species (CO, SiO) and dust clusters is described. Stiff, coupled, ordinary, differential equations are solved for the conditions pertaining to both the SN ejecta and the post-reverse shock gas. Results: We find that the ejecta of Type IIb SNe are unable to form large amounts of molecules and dust clusters as opposed to their Type II-P counterparts because of their diffuse ejecta. The gas density needs to be increased by several orders of magnitude to allow the formation of dust clusters. We show that the chemical composition of the dust clusters changes drastically and gains in chemical complexity with increasing gas density. Hence, the ejecta of the Cas A supernova progenitor must have been in the form of dense clumps to account for the dust chemical composition and masses inferred from infrared observations of Cas A. We show that the ejecta molecules in a clump that is processed by the reverse shock reform in the post-reverse shock gas with lower abundances than those of the initial ejecta clump, except SiO. These molecules include CO, SiS and O2. Dust clusters are destroyed by the reverse shock and do not reform in the post-reverse shock gas, even for the highest gas density. These results indicate that the synthesis of dust grains from the gas phase in the dense knots of Cas A and in other supernova remnants is unlikely.

The chemically controlled synthesis of dust in type II-P supernovae

We study the formation of molecules and dust clusters in the ejecta of solar metallicity, Type II-P supernovae using a chemical kinetic approach. We follow the evolution of molecules and small dust cluster masses from day 100 to day 1500 after explosion. We consider stellar progenitors with initial mass of 12, 15, 19 and 25 Msun that explode as supernovae with stratified ejecta. The molecular precursors to dust grains comprise molecular chains, rings and small clusters of silica, silicates, metal oxides, sulphides and carbides, pure metals, and carbon, where the nucleation of silicate clusters is described by a two-step process of metal and oxygen addition. We study the impact of the 56Ni mass on the type and amount of synthesised dust. We predict that large masses of molecules including CO, SiO, SiS, O2, and SO form in the ejecta. We show that the discrepancy between the small dust masses detected at infrared wavelengths some 500 days post-explosion and the larger amounts of dust recently detected with Herschel in supernova remnants can be explained by the non-equilibrium chemistry linked to the formation of molecules and dust clusters in the ejected material. Dust gradually builds up from small (~10^{-5} Msun) to large masses (~5x 10^{-2} Msun) over a 5 yr period after explosion. Subsequent dust formation and/or growth is hampered by the shortage of chemical agents participating in the dust nucleation and the long time scale for accretion. The results highlight the dependence of the dust chemical composition and mass on the amount of 56Ni synthesised during the explosion. This dependence may partly explain the diversity of epochs at which dust forms in supernovae. More generally, our results indicate that type II-P supernovae are efficient but moderate dust producers with an upper limit on the mass of synthesised dust ranging from ~ 0.03 to 0.09 Msun.

The chemistry of dust formation in red supergiants

Massive stars in their late stages of evolution as Red Supergiants experience mass loss. The resulting winds show various degrees of dynamical and chemical complexity and produce molecules and dust grains. This review summarises our knowledge of the molecular and dust components of the wind of Red Supergiants, including VY CMa and Betelgeuse. We discuss the synthesis of dust as a non-equilibrium process in stellar winds, and present the current knowledge of the chemistry involved in the formation of oxygen-rich dust such as silicates and metal oxides.

The inner wind of IRC+10216 revisited: New exotic chemistry and diagnostic for dust condensation in carbon stars

Aims. We model the chemistry of the inner wind of the carbon star IRC+10216 and consider the effect of periodic shocks induced by the stellar pulsation on the gas to follow the non-equilibrium chemistry in the shocked gas layers. We consider a very complete set of chemical families, including hydrocarbons and aromatics, hydrides, halogens and phosphorous-bearing species. Derived abundances are compared to the latest observational data from large surveys and Herschel. Results. The shocks induce a non-equilibrium chemistry in the dust formation zone of IRC+10216 where the collision destruction of CO in the post-shock gas triggers the formation of O-bearing species (H2O, SiO). Most of the modelled abundances agree very well with the latest values derived from Herschel data on IRC+10216. Hydrides form a family of abundant species that are expelled into the intermediate envelope. In particular, HF traps all the atomic fluorine in the dust formation zone. Halogens are also abundant and their chemistry is independent of the C/O ratio of the star. Therefore, HCl and other Cl-bearing species should also be present in the inner wind of O-rich AGB or supergiant stars. We identify a specific region ranging from 2.5 R* to 4 R*, where polycyclic aromatic hydrocarbons form and grow. The estimated carbon dust-to-gas mass ratio derived from the mass of aromatics ranges from 1.2 x 10^(-3) to 5.8 x 10^{-3} and agrees well with existing observational values. The aromatic formation region is located outside hot layers where SiC2 is produced as a bi-product of silicon carbide dust synthesis. Finally, we predict that some molecular lines will show flux variation with pulsation phase and time (e.g., H2O) while other species will not (e.g., CO). These variations merely reflect the non-equilibrium chemistry that destroys and reforms molecules over a pulsation period in the shocked gas of the dust formation zone.

Molecules in supernova ejecta

The first molecules detected at infrared wavelengths in the ejecta of a Type II supernova, namely SN1987A, consisted of CO and SiO. Since then, confirmation of the formation of these two species in several other supernovae a few hundred days after explosion has been obtained. However, supernova environments appear to hamper the synthesis of large, complex species due to the lack of microscopically-mixed hydrogen deep in supernova cores. Because these environments also form carbon and silicate dust, it is of importance to understand the role played by molecules in the depletion of elements and how chemical species get incorporated into dust grains. In the present paper, we review our current knowledge of the molecular component of supernova ejecta, and present new trends and results on the synthesis of molecules in these harsh, explosive events.

Water in IRC+10216: a genuine formation process by shock-induced chemistry in the inner wind

Context: The presence of water in the wind of the extreme carbon star IRC+10216 has been confirmed by the Herschel telescope. The regions where the high-J H2O lines have been detected are close to the star at radii r geq 15 Rast. Aims: We investigate the formation of water and related molecules in the periodically-shocked inner layers of IRC+10216 where dust also forms and accelerates the wind. Methods: We describe the molecular formation by a chemical kinetic network involving carbon-and oxygen-based molecules. We then apply this network to the physical conditions pertaining to the dust-formation zone which experiences the passage of pulsation- driven shocks between 1 and 5 Rast. We solve for a system of stiff, coupled, ordinary, and differential equations. Results: Non-equilibrium chemistry prevails in the dust-formation zone. H2O forms quickly above the photosphere from the synthesis of hydroxyl OH induced by the thermal fragmentation of CO in the hot post-shock gas. The derived abundance with respect to H2 at 5 Rast is 1.4times10-7, which excellently agrees the values derived from Herschel observations. The non-equilibrium formation process of water will be active whatever the stellar C/O ratio, and H2O should then be present in the wind acceleration zone of all stars on the Asymptotic Giant Branch.