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Context: The presence of water in the wind of the extreme carbon star IRC+10216 has been confirmed by the Herschel telescope. The regions where the high-J H2O lines have been detected are close to the star at radii r geq 15 Rast. Aims: We investigate the formation of water and related molecules in the periodically-shocked inner layers of IRC+10216 where dust also forms and accelerates the wind. Methods: We describe the molecular formation by a chemical kinetic network involving carbon-and oxygen-based molecules. We then apply this network to the physical conditions pertaining to the dust-formation zone which experiences the passage of pulsation- driven shocks between 1 and 5 Rast. We solve for a system of stiff, coupled, ordinary, and differential equations. Results: Non-equilibrium chemistry prevails in the dust-formation zone. H2O forms quickly above the photosphere from the synthesis of hydroxyl OH induced by the thermal fragmentation of CO in the hot post-shock gas. The derived abundance with respect to H2 at 5 Rast is 1.4times10-7, which excellently agrees the values derived from Herschel observations. The non-equilibrium formation process of water will be active whatever the stellar C/O ratio, and H2O should then be present in the wind acceleration zone of all stars on the Asymptotic Giant Branch.
Aims. We model the chemistry of the inner wind of the carbon star IRC+10216 and consider the effect of periodic shocks induced by the stellar pulsation on the gas to follow the non-equilibrium chemistry in the shocked gas layers. We consider a very c
We present the detection of C4H2 for first time in the envelope of the C-rich AGB star IRC+10216 based on high spectral resolution mid-IR observations carried out with the Texas Echelon-cross-Echelle Spectrograph (TEXES) mounted on the Infrared Teles
We present high spectral resolution mid-IR observations of SiS towards the C-rich AGB star IRC+10216 carried out with the Texas Echelon-cross-Echelle Spectrograph mounted on the NASA Infrared Telescope Facility. We have identified 204 ro-vibrational
A single dish monitoring of millimeter maser lines SiS J=14-13 and HCN nu_2 = 1^f J=3-2 and several other rotational lines is reported for the archetypal carbon star IRC+10216. Relative line strength variations of 5%~30% are found for eight molecular
IRC +10216 is the prototypical carbon star exhibiting an extended molecular circumstellar envelope. Its spectral properties are therefore the template for an entire class of objects. The main goal is to systematically study the $lambda$ $sim$1.3 cm s