We employ doubly-resonant two-photon excitation into the 74S Rydberg state to spectroscopically measure the dynamic scalar polarizability, alpha 0, and tensor polarizability, alpha 2, of rubidium 5P3/2. To reach the necessary high intensities, we emp
loy a cavity-generated 1064 nm optical-lattice light field, allowing us to obtain intensities near 2x10^11 W/m^2. In the evaluation of the data we use a self-referencing method that renders the polarizability measurement largely free from the intensity calibration of the laser light field. We obtain experimental values alpha 0 =-1149 (pm 2.5 percent) and alpha 2 = 563 (pm 4.2 percent), in atomic units. Methods and results are supported by simulations.
In ponderomotive spectroscopy an amplitude-modulated optical standing wave is employed to probe Rydberg-atom transitions, utilizing a ponderomotive rather than a dipole-field interaction. Here, we engage nonlinearities in the modulation to drive dipo
le-forbidden transitions up to the fifth order. We reach transition frequencies approaching the sub-THz regime. We also demonstrate magic-wavelength conditions, which result in symmetric spectral lines with a Fourier-limited feature at the line center. Applicability to precision measurement is discussed.
Spectroscopy is an essential tool in understanding and manipulating quantum systems, such as atoms and molecules. The model describing spectroscopy includes a multipole-field interaction, which leads to established spectroscopic selection rules, and
an interaction that is quadratic in the field, which is often neglected. However, spectroscopy using the quadratic (ponderomotive) interaction promises two significant advantages over spectroscopy using the multipole-field interaction: flexible transition rules and vastly improved spatial addressability of the quantum system. For the first time, we demonstrate ponderomotive spectroscopy by using optical-lattice-trapped Rydberg atoms, pulsating the lattice light at a microwave frequency, and driving a microwave atomic transition that would otherwise be forbidden by established spectroscopic selection rules. This new ability to measure frequencies of previously inaccessible transitions makes possible improved determinations of atomic characteristics and constants underlying physics. In the spatial domain, the resolution of ponderomotive spectroscopy is orders of magnitude better than the transition frequency (and the corresponding diffraction limit) would suggest, promising single-site addressability in a dense particle array for quantum control and computing applications. Future advances in technology may allow ponderomotive spectroscopy to be extended to ground-state atoms and trapped molecules.
