Simple molecules like H2CO and CH3OH in protoplanetary disks are the starting point for the production of more complex organic molecules. So far, the observed chemical complexity in disks has been limited due to freeze out of molecules onto grains in
the bulk of the cold outer disk. Complex molecules can be studied more directly in transitional disks with large inner holes, as these have a higher potential of detection, through UV heating of the outer disk and the directly exposed midplane at the wall. We use Atacama Large Millimeter/submillimeter Array (ALMA) Band 9 (~680 GHz) line data of the transitional disk Oph IRS 48, previously shown to have a large dust trap, to search for complex molecules in regions where planetesimals are forming. We report the detection of the H2CO 9(1,8)-8(1,7) line at 674 GHz, which is spatially resolved as a semi-ring at ~60 AU radius centered south from the star. The inferred H2CO abundance is ~10^{-8} derived by combining a physical disk model of the source with a non-LTE excitation calculation. Upper limits for CH3OH lines in the same disk give an abundance ratio H2CO/CH3OH>0.3, which points to both ice formation and gas-phase routes playing a role in the H2CO production. Upper limits on the abundances of H13CO+, CN and several other molecules in the disk are also derived and found to be consistent with full chemical models. The detection of the H2CO line demonstrates the start of complex organic molecules in a planet-forming disk. Future ALMA observations should be able to push down the abundance detection limits of other molecules by 1-2 orders of magnitude and test chemical models of organic molecules in (transitional) disks.
(Abridged) Disks are observed around pre-main sequence stars, but how and when they form is still heavily debated. While disks around young stellar objects have been identified through thermal dust emission, spatially and spectrally resolved molecula
r line observations are needed to determine their nature. We present subarcsecond observations of dust and gas toward four Class I low-mass young stellar objects in Taurus. The 13CO and C18O J=2-1 transitions at 220 GHz were observed with the Plateau de Bure Interferometer at a spatial resolution of ~0.8 and analyzed using uv-space position velocity diagrams to determine the nature of their observed velocity radient. Rotationally supported disks (RSDs) are detected around 3 of the 4 Class I sources studied. The derived masses identify them as Stage I objects; i.e., their stellar mass is higher than their envelope and disk masses. The outer radii of the Keplerian disks toward our sample of Class I sources are <~ 100 AU. The lack of on-source C18O emission for TMR1 puts an upper limit of 50 AU on its size. Flattened structures at radii > 100 AU around these sources are dominated by infalling motion (v propto r^-1). A large-scale envelope model is required to estimate the basic parameters of the flattened structure from spatially resolved continuum data. Similarities and differences between the gas and dust disk are discussed. Combined with literature data, the sizes of the RSDs around Class I objects are best described with evolutionary models with an initial rotation of 10^-14 Hz and slow sound speeds. Based on the comparison of gas and dust disk masses, little CO is frozen out within 100 AU in these disks. RSDs with radii up to 100 AU are present around Class I embedded objects. Larger surveys of both Class 0 and I objects are needed to determine whether most disks form late or early in the embedded phase.
(Abridged) Transition disks are recognized by the absence of emission of small dust grains inside a radius of up to several 10s of AUs. Due to the lack of angular resolution and sensitivity, the gas content of such dust holes has not yet been determi
ned, but is of importance to constrain the mechanism leading to the dust holes. Transition disks are thought to currently undergo the process of dispersal, setting an end to the giant planet formation process. We present new high-resolution observations with the Atacama Large Millimeter/ submillimeter Array (ALMA) of gas lines towards the transition disk Oph IRS 48 previously shown to host a large dust trap. ALMA has detected the $J=6-5$ line of $^{12}$CO and C$^{17}$O around 690 GHz (434 $mu$m) at a resolution of $sim$0.25$$ corresponding to $sim$30 AU (FWHM). The observed gas lines are used to set constraints on the gas surface density profile. New models of the physical-chemical structure of gas and dust in Oph IRS 48 are developed to reproduce the CO line emission together with the spectral energy distribution (SED) and the VLT-VISIR 18.7 $mu$m dust continuum images. Integrated intensity cuts and the total spectrum from models having different trial gas surface density profiles are compared to observations. Using the derived surface density profiles, predictions for other CO isotopologues are made, which can be tested by future ALMA observations of the object. The derived gas surface density profile points to the clearing of the cavity by one or more massive planet/companion rather than just photoevaporation or grain-growth.
The statistics of discovered exoplanets suggest that planets form efficiently. However, there are fundamental unsolved problems, such as excessive inward drift of particles in protoplanetary disks during planet formation. Recent theories invoke dust
traps to overcome this problem. We report the detection of a dust trap in the disk around the star Oph IRS 48 using observations from the Atacama Large Millimeter/submillimeter Array (ALMA). The 0.44-millimeter-wavelength continuum map shows high-contrast crescent-shaped emission on one side of the star originating from millimeter-sized grains, whereas both the mid-infrared image (micrometer-sized dust) and the gas traced by the carbon monoxide 6-5 rotational line suggest rings centered on the star. The difference in distribution of big grains versus small grains/gas can be modeled with a vortex-shaped dust trap triggered by a companion.
We present a large, comprehensive survey of rovibrational CO line emission at 4.7 micron from 69 protoplanetary disks, obtained with CRIRES on the ESO Very Large Telescope at the highest available spectral resolving power (R=95,000, v=3.2 km/s). The
CO fundamental band (Delta v=1) is a well-known tracer of warm gas in the inner, planet-forming regions of gas-rich disks around young stars, with the lines formed in the super-heated surfaces of the disks at radii of 0.1-10 AU. Our high spectral resolution data provide new insight into the kinematics of the inner disk gas. Pure double-peaked Keplerian profiles are surprisingly uncommon, beyond the frequency expected based on disk inclination. The majority of the profiles are consistent with emission from a disk plus a slow (few km/s) molecular disk wind. This is evidenced by analysis of different categories as well as an overall tendency for line profiles to have excess blue emission. Weak emission lines from isotopologues and vibrationally excited levels are readily detected. In general, 13CO lines trace cooler gas than the bulk 12CO emission and may arise from further out in the disk, as indicated by narrower line profiles. A high fraction of the sources show vibrationally excited emission (~50%) which is correlated with accretion luminosity, consistent with ultra-violet (UV) fluorescent excitation. Disks around early-type Herbig AeBe stars have narrower lines, on average, than their lower-mass late-type counterparts, due to their increased luminosity. Evolutionary changes in CO are also seen. Removal of the protostellar envelope between class I and II results in the disappearance of the strong absorption lines and CO ice feature characteristic of class I spectra. However, CO emission from class I and II objects is similar in detection frequency, excitation and line shape, indicating that inner disk characteristics are established early.
Photodissociation is the dominant removal process of molecules in any region exposed to intense ultraviolet (UV) radiation. This includes diffuse and translucent interstellar clouds, dense photon-dominated regions, high velocity shocks, the surface l
ayers of protoplanetary disks, and cometary and exoplanetary atmospheres. The rate of photodissociation depends on the cross sections for absorption into a range of excited electronic states, as well as on the intensity and shape of the radiation field at each position into the region of interest. Thus, an acccurate determination of the photodissociation rate of even a simple molecule like water or carbon monoxide involves many detailed considerations ranging from its electronic structure to its dissociation dynamics and the specifics of the radiation field that the molecule is exposed to. In this review chapter, each of these steps in determining photodissociation rates is discussed systematically and examples are provided.
Herschel-HIFI observations of high-J lines (up to J_u=10) of 12CO, 13CO and C18O are presented toward three deeply embedded low-mass protostars in NGC1333. The observations show several energetic components including shocked and quiescent gas. Radiat
ive transfer models are used to quantify the C18O envelope abundance which require a jump in the abundance at an evaporation temperature, T_ev ~25 K, providing new direct evidence of a CO ice evaporation zone around protostars. The abundance in the outermost part of the envelope, X_0, is within the canonical value of 2x10^-4; however the inner abundance, X_in, is found around a factor of 3-5 lower than X_0.
Molecules containing one or a few hydrogen atoms and a heavier atom (hydrides) have been predicted to trace FUV radiation. In some chemical models, FUV emission by the central object or protostar of a star forming region greatly enhances some of the
hydride abundances. Two massive regions, W3 IRS5 and AFGL 2591, have been observed in hydride lines by HIFI onboard the {it Herschel Space Observatory}. We use published results as well as new observations of CH$^+$ towards W3 IRS5. Molecular column densities are derived from ground state absorption lines, radiative transfer modeling or rotational diagrams. Models assuming no internal FUV are compared with two-dimensional models including FUV irradiation of outflow walls. We confirm that the effect of FUV is clearly noticeable and greatly improves the fit. The most sensitive molecules to FUV irradiation are CH$^+$ and OH$^+$, enhanced in abundance by many orders of magnitude. Modeling in addition also full line radiative transfer, Bruderer et al (2010b) achieve good agreement of a two-dimensional FUV model with observations of CH$^+$ in AFGL 2591. It is concluded that CH$^+$ and OH$^+$ are good FUV tracers in star-forming regions.
Young stars are formed within dusty discs. The grains in the disc are originally of the same size as interstellar dust. Models predict that these grains will grow in size through coagulation. Observations of the silicate features at micron wavelength
s are consistent with growth to micron sizes whereas the slope of the SED at longer wavelengths traces growth up to mm sizes. We here look for a correlation between these two grain growth indicators. A large sample of T-Tauri and Herbig-Ae/Be stars was observed with the Spitzer Space Telescope at 5-13 micron; a subsample was observed at mm wavelengths. We complement this subsample with data from the literature to maximise the overlap between micron and mm observations and search for correlations. Synthetic spectra are produced to determine which processes may produce the dust evolution. Dust disc masses in the range <1 to 7 x 10^-4 MSun are obtained. Most sources have a mm spectral slope consistent with grain growth. There is a tentative correlation between the 10-micron silicate feature and the mm slope of the SED. The observed sources seem to be grouped per star-forming region in the micron-vs-mm diagram. The modelling results show that the 10-micron feature becomes flatter and subsequently the mm slope becomes shallower. Grain size distributions shallower than that of the ISM and/or bright central stars are required to explain specific features. Settling of larger grains towards the disc midplane affects the 10-micron feature, but hardly the mm slope. The tentative correlation between the strength of the 10-micron feature and the mm slope suggests that the inner and outer disc evolve simultaneously. Dust with a mass dominated by mm-sized grains is required to explain the shallowest mm slopes. Other processes besides grain growth may also be responsible for the removal of small grains.
