We present new observations of the (6,6) and (9,9) inversion transitions of the hydronium ion toward Sagittarius B2(N) and W31C. Sensitive observations toward Sagittarius B2(N) show that the high, ~ 500 K, rotational temperatures characterizing the p
opulation of the highly-excited metastable H3O+ rotational levels are present over a wide range of velocities corresponding to the Sagittarius B2 envelope, as well as the foreground gas clouds between the Sun and the source. Observations of the same lines toward W31C, a line of sight that does not intersect the Central Molecular Zone, but instead traces quiescent gas in the Galactic disk, also imply a high rotational temperature of ~ 380 K, well in excess of the kinetic temperature of the diffuse Galactic interstellar medium. While it is plausible that some fraction of the molecular gas may be heated to such high temperatures in the active environment of the Galactic center, characterized by high X-ray and cosmic ray fluxes, shocks and high degree of turbulence, this is unlikely in the largely quiescent environment of the Galactic disk clouds. We suggest instead that the highly-excited states of the hydronium ion are populated mainly by exoergic chemical formation processes and temperature describing the rotational level population does not represent the physical temperature of the medium. The same arguments may be applicable to other symmetric top rotors, such as ammonia. This offers a simple explanation to the long-standing puzzle of the presence of a pervasive, hot molecular gas component in the central region of the Milky Way. Moreover, our observations suggest that this is a universal process, not limited to the active environments associated with galactic nuclei.
(Abridged) Water is a key tracer of dynamics and chemistry in low-mass protostars, but spectrally resolved observations have so far been limited in sensitivity and angular resolution. In this first systematic survey of spectrally resolved water emiss
ion in low-mass protostellar objects, H2O was observed in the ground-state transition at 557 GHz with HIFI on Herschel in 29 embedded Class 0 and I protostars. Complementary far-IR and sub-mm continuum data (including PACS data from our program) are used to constrain the spectral energy distribution of each source. H2O intensities are compared to inferred envelope and outflow properties and CO 3-2 emission. H2O emission is detected in all objects except one. The line profiles are complex and consist of several kinematic components. The profiles are typically dominated by a broad Gaussian emission feature, indicating that the bulk of the water emission arises in outflows, not the quiescent envelope. Several sources show multiple shock components in either emission or absorption, thus constraining the internal geometry of the system. Furthermore, the components include inverse P-Cygni profiles in 7 sources (6 Class 0, 1 Class I) indicative of infalling envelopes, and regular P-Cygni profiles in 4 sources (3 Class I, 1 Class 0) indicative of expanding envelopes. Bullets moving at >50 km/s are seen in 4 Class 0 sources; 3 of these are new detections. In the outflow, the H2O/CO abundance ratio as a function of velocity is nearly the same for all sources, increasing from 10^-3 at <5 km/s to >10^-1 at >10 km/s. The H2O abundance in the outer envelope is low, ~10^-10. The different H2O profile components show a clear evolutionary trend: in the Class 0 sources, emission is dominated by outflow components originating inside an infalling envelope. When the infall diminishes during the Class I phase, the outflow weakens and H2O emission disappears.
We report a detection of the fundamental rotational transition of hydrogen fluoride in absorption towards Orion KL using Herschel/HIFI. After the removal of contaminating features associated with common molecules (weeds), the HF spectrum shows a P-Cy
gni profile, with weak redshifted emission and strong blue-shifted absorption, associated with the low-velocity molecular outflow. We derive an estimate of 2.9 x 10^13 cm^-2 for the HF column density responsible for the broad absorption component. Using our best estimate of the H2 column density within the low-velocity molecular outflow, we obtain a lower limit of ~1.6 x 10^-10 for the HF abundance relative to hydrogen nuclei, corresponding to 0.6% of the solar abundance of fluorine. This value is close to that inferred from previous ISO observations of HF J=2--1 absorption towards Sgr B2, but is in sharp contrast to the lower limit of 6 x 10^-9 derived by Neufeld et al. (2010) for cold, foreground clouds on the line of sight towards G10.6-0.4.
We performed a sensitive search for the ground-state emission lines of ortho- and para-water vapor in the DM Tau protoplanetary disk using the Herschel/HIFI instrument. No strong lines are detected down to 3sigma levels in 0.5 km/s channels of 4.2 mK
for the 1_{10}--1_{01} line and 12.6 mK for the 1_{11}--0_{00} line. We report a very tentative detection, however, of the 1_{10}--1_{01} line in the Wide Band Spectrometer, with a strength of T_{mb}=2.7 mK, a width of 5.6 km/s and an integrated intensity of 16.0 mK km/s. The latter constitutes a 6sigma detection. Regardless of the reality of this tentative detection, model calculations indicate that our sensitive limits on the line strengths preclude efficient desorption of water in the UV illuminated regions of the disk. We hypothesize that more than 95-99% of the water ice is locked up in coagulated grains that have settled to the midplane.
High resolution molecular line observations of CS, HCO+, C18O and N2H+ were obtained toward the starless globule FeSt 1-457 in order to investigate its kinematics and chemistry. The HCO+ and CS spectra show clear self-reversed and asymmetric profiles
across the face of the globule. The sense of the observed asymmetry is indicative of the global presence of expansion motions in the outer layers of the globule. These motions appear to be subsonic and significantly below the escape velocity of the globule. Comparison of our observations with near-infrared extinction data indicate that the globule is gravitationally bound. Taken together these considerations lead us to suggest that the observed expansion has its origin in an oscillatory motion of the outer layers of the globule which itself is likely in a quasi-stable state near hydrostatic equilibrium. Analysis of the observed linewidths of CO and N2H+ confirm that thermal pressure is the dominant component of the clouds internal support. A simple calculation suggests that the dominant mode of pulsation would be an l = 2 mode with a period of 0.3 Myr. Deformation of the globule due to the large amplitude l = 2 oscillation may be responsible for the double-peaked structure of the core detected in high resolution extinction maps. Detailed comparison of the molecular-line observations and extinction data provides evidence for significant depletion of C18O and perhaps HCO+ while N2H+ may be undepleted to a cloud depth of about 40 magnitudes of visual extinction.
High resolution molecular line observations of CS, HCO+, C18O and N2H+ were obtained toward the starless globule FeSt 1-457 in order to investigate its kinematics and chemistry. The HCO+ and CS spectra show clear self-reversed and asymmetric profiles
across the face of the globule. The sense of the observed asymmetry is indicative of the global presence of expansion motions in the outer layers of the globule. These motions appear to be subsonic and significantly below the escape velocity of the globule. Comparison of our observations with near-infrared extinction data indicate that the globule is gravitationally bound. Taken together these considerations lead us to suggest that the observed expansion has its origin in an oscillatory motion of the outer layers of the globule which itself is likely in a quasi-stable state near hydrostatic equilibrium. Analysis of the observed linewidths of CO and N2H+ confirm that thermal pressure is the dominant component of the clouds internal support. A simple calculation suggests that the dominant mode of pulsation would be an l = 2 mode with a period of 0.3 Myr. Deformation of the globule due to the large amplitude l = 2 oscillation may be responsible for the double-peaked structure of the core detected in high resolution extinction maps. Detailed comparison of the molecular-line observations and extinction data provides evidence for significant depletion of C18O and perhaps HCO+ while N2H+ may be undepleted to a cloud depth of about 40 magnitudes of visual extinction.
