[Abridged] Fullerenes have been recently detected in various circumstellar and interstellar environments, raising the question of their formation pathway. It has been proposed that they can form by the photo-chemical processing of large polycyclic ar
omatic hydrocarbons (PAHs). Following our previous work on the evolution of PAHs in the NGC 7023 reflection nebula, we evaluate, using photochemical modeling, the possibility that the PAH C$_{66}$H$_{20}$ (i.e. circumovalene) can lead to the formation of C$_{60}$ upon irradiation by ultraviolet photons. The chemical pathway involves full dehydrogenation, folding into a floppy closed cage and shrinking of the cage by loss of C$_2$ units until it reaches the symmetric C$_{60}$ molecule. At 10 from the illuminating star and with realistic molecular parameters, the model predicts that 100% of C$_{66}$H$_{20}$ is converted into C$_{60}$ in $sim$ 10$^5$ years, a timescale comparable to the age of the nebula. Shrinking appears to be the kinetically limiting step of the whole process. Hence, PAHs larger than C$_{66}$H$_{20}$ are unlikely to contribute significantly to the formation of C$_{60}$, while PAHs containing between 60 and 66 C atoms should contribute to the formation of C$_{60}$ with shorter timescales, and PAHs containing less than 60 C atoms will be destroyed. Assuming a classical size distribution for the PAH precursors, our model predicts absolute abundances of C$_{60}$ are up to several $10^{-4}$ of the elemental carbon, i.e. less than a percent of the typical interstellar PAH abundance, which is consistent with observational studies. According to our model, once formed, C$_{60}$ can survive much longer than other fullerenes because of the remarkable stability of the C$_{60}$ molecule at high internal energies.Hence, a natural consequence is that C$_{60}$ is more abundant than other fullerenes in highly irradiated environments.
The far-IR range is a critical wavelength range to characterize the physical and chemical processes that transform the interstellar material into stars and planets. Objects in the earliest phases of stellar and planet evolution release most of their
energy at these long wavelengths. In this contribution we briefly summarise some of the most relevant scientific advances achieved by the Herschel Space Observatory in the field. We also anticipate those that will be made possible by the large increase in sensitivity of SPICA cooled telescope. It is concluded that only through sensitive far-IR observations much beyond Herschel capabilities we will be able to constrain the mass, the energy budget and the water content of hundreds of protostars and planet-forming disks.
As part of a far-infrared (FIR) spectral scan with Herschel/PACS, we present the first detection of the hydroxyl radical (OH) towards the Orion Bar photodissociation region (PDR). Five OH rotational Lambda-doublets involving energy levels out to E_u/
k~511 K have been detected (at ~65, ~79, ~84, ~119 and ~163um). The total intensity of the OH lines is I(OH)~5x10^-4 erg s^-1 cm^-2 sr^-1. The observed emission of rotationally excited OH lines is extended and correlates well with the high-J CO and CH^+ J=3-2 line emission (but apparently not with water vapour), pointing towards a common origin. Nonlocal, non-LTE radiative transfer models including excitation by the ambient FIR radiation field suggest that OH arises in a small filling factor component of warm (Tk~160-220 K) and dense (n_H~10^{6-7} cm^-3) gas with source-averaged OH column densities of ~10^15 cm^-2. High density and temperature photochemical models predict such enhanced OH columns at low depths (A_V<1) and small spatial scales (~10^15 cm), where OH formation is driven by gas-phase endothermic reactions of atomic oxygen with molecular hydrogen. We interpret the extended OH emission as coming from unresolved structures exposed to far-ultraviolet (FUV) radiation near the Bar edge (photoevaporating clumps or filaments) and not from the lower density interclump medium. Photodissociation leads to OH/H2O abundance ratios (>1) much higher than those expected in equally warm regions without enhanced FUV radiation fields.
Polycyclic Aromatic Hydrocarbons (PAHs) are considered as a major constituent of interstellar dust. They have been proposed as the carriers of the Aromatic Infrared Bands (AIBs) observed in emission in the mid-IR. They likely have a significant contr
ibution to various features of the extinction curve such as the 220 nm bump,the far-UV rise and the diffuse interstellar bands. Emission bands are also expected in the far-IR, which are better fingerprints of molecular identity than the AIBs. They will be searched for with the Herschel Space Observatory. Rotational emission is also expected in the mm range for those molecules which carry significant dipole moments. Despite spectroscopic studies in the laboratory, no individual PAH species could be identified. This emphasises the need for an investigation on where interstellar PAHs come from and how they evolve due to environmental conditions: ionisation and dissociation upon UV irradiation, interactions with electrons, gas and dust. There is also evidence for PAH species to contribute to the depletion of heavy atoms from the gas phase, in particular Si and Fe. This paper illustrates how laboratory work can be inspired from observations. In particular there is a need for understanding the chemical properties of PAHs and PAH-related species, including very small grains, in physical conditions that mimic those found in interstellar space. This motivates a joint effort between astrophysicists, physicists and chemists. Such interdisciplinary studies are currently performed, taking advantage of the PIRENEA set-up, a cold ion trap dedicated to astrochemistry.
In this Paper we analyze the mid-infrared (mid-IR) emission of very small dust particles in a sample of 12 protoplanetary disks to see how they are connected to interstellar dust particles and to investigate the possibility that their emission can be
used as a probe of the physical conditions and evolution of the disk. We define a basis made of three mid-IR template spectra PAH$^0$, PAH$^+$ and VSGs that were derived from the analysis of reflection nebulae, and an additional PAH$^x$ spectrum that was introduced by Joblin et al. (2008) for the analysis of the spectra of planetary nebulae. From the optimization of the fit of 12 star+disk spectra, using a linear combination of the 4 template spectra, we found that an additional small grain component with a broad feature at 8.3 $mu$m is needed. We find that the fraction of VSG emission in disks decreases with increasing stellar temperature. VSGs appear to be destroyed by UV photons at the surface of disks, thus releasing free PAH molecules, which are eventually ionized as it is observed in photodissociation regions. On the opposite, we observe that the fraction of PAH$^x$ increases with increasing star temperature except in the case of B stars where they are absent. We argue that this is compatible with the identification of PAH$^x$ as large ionized PAHs, most likely emitting in regions of the disk that are close to the star. Finally, we provide a UV-dependant scheme to explain the evolution of PAHs and VSGs in protoplanetary disks. We show that A stars modify the size spectrum of PAHs and VSGs in favor of large PAHs while B stars destroy even the largest PAHs up to large radii in the disk. These results allow us to put new constrains on the properties of two sources: IRS 48 and Gomezs Hamburger which are poorly characterized.
It has been shown that the diversity of the aromatic emission features can be rationalized into different classes of objects, in which differences between circumstellar and interstellar matter are emphasised. We probe the links between the mid-IR emi
tters observed in planetary nebulae (PNe) and their counterparts in the interstellar medium in order to probe a scenario in which the latter have been formed in the circumstellar environment of evolved stars. The mid-IR (6-14 um) emission spectra of PNe and compact HII regions were analysed on the basis of previous work on photodissociation regions (PDRs). Galactic, Large Magellanic Cloud (LMC), and Small Magellanic Cloud (SMC) objects were considered in our sample.We show that the mid-IR emission of PNe can be decomposed as the sum of six components. Some components made of polycyclic aromatic hydrocarbon (PAH) and very small grain (VSG) populations are similar to those observed in PDRs. Others are fitted in an evolutionary scenario involving the destruction of the aliphatic component observed in the post-AGB stage, as well as strong processing of PAHs in the extreme conditions of PNe that leads to a population of very large ionized PAHs. This species called PAH^x are proposed as the carriers of a characteristic band at 7.90 um. This band can be used as part of diagnostics that identify PNe in nearby galaxies and is also observed in galactic compact HII regions. These results support the formation of the aromatic very small dust particles in the envelopes of evolved stars, in the Milky Way, as well as in the LMC and SMC, and their subsequent survival in the interstellar medium.
Extended Red Emission (ERE) was recently attributed to the photo-luminescence of either doubly ionized Polycyclic Aromatic Hydrocarbons (PAH$^{++}$), or charged PAH dimers. We analysed the visible and mid-infrared (mid-IR) dust emission in the North-
West and South photo-dissociation regions of the reflection nebula NGC 7023.Using a blind signal separation method, we extracted the map of ERE from images obtained with the Hubble Space Telescope, and at the Canada France Hawaii Telescope. We compared the extracted ERE image to the distribution maps of the mid-IR emission of Very Small Grains (VSGs), neutral and ionized PAHs (PAH$^0$ and PAH$^+$) obtained with the Spitzer Space Telescope and the Infrared Space Observatory. ERE is dominant in transition regions where VSGs are being photo-evaporated to form free PAH molecules, and is not observed in regions dominated by PAH$^+$. Its carrier makes a minor contribution to the mid-IR emission spectrum. These results suggest that the ERE carrier is a transition species formed during the destruction of VSGs. Singly ionized PAH dimers appear as good candidates but PAH$^{++}$ molecules seem to be excluded.
