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We demonstrate the measurement and manipulation of the temperature of cold CO molecules in a microchip environment. Through the use of time-resolved spatial imaging, we are able to observe the phase-space distribution of the molecules, and hence dedu ce the corresponding temperature. We do this both by observing the expansion of the molecular ensemble in time and through the use of numerical trajectory simulations. Furthermore, we demonstrate the adiabatic cooling of the trapped molecular sample and discuss this process.
Polar molecules in selected quantum states can be guided, decelerated and trapped using electric fields created by microstructured electrodes on a chip. Here we explore how non-adiabatic transitions between levels in which the molecules are trapped a nd levels in which the molecules are not trapped can be suppressed. We use 12-CO and 13-CO (a 3-Pi(1), v=0) molecules, prepared in the upper Lambda-doublet component of the J=1 rotational level, and study the trap loss as a function of an offset magnetic field. The experimentally observed suppression (enhancement) of the non-adiabatic transitions for 12-CO (13-CO) with increasing magnetic field is quantitatively explained.
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