Pre-thermalization in a non-integrable quantum spin chain after a quench

We study the dynamics of a quantum Ising chain after the sudden introduction of a non-integrable long-range interaction. Via an exact mapping onto a fully-connected lattice of hard-core bosons, we show that a pre-thermal state emerges and we investigate its features by focusing on a class of physically relevant observables. In order to gain insight into the eventual thermalization, we outline a diagrammatic approach which complements the study of the previous quasi-stationary state and provides the basis for a self-consistent solution of the kinetic equation. This analysis suggests that both the temporal decay towards the pre-thermal state and the crossover to the eventual thermal one may occur algebraically.

Statistics of the work done by splitting a one-dimensional quasi-condensate

Motivated by experiments on splitting one-dimensional quasi-condensates, we study the statistics of the work done by a quantum quench in a bosonic system. We discuss the general features of the probability distribution of the work and focus on its behaviour at the lowest energy threshold, which develops an edge singularity. A formal connection between this probability distribution and the critical Casimir effect in thin classical films shows that certain features of the edge singularity are universal as the post-quench gap tends to zero. Our results are quantitatively illustrated by an exact calculation for non-interacting bosonic systems. The effects of finite system size, dimensionality, and non-zero initial temperature are discussed in detail.

Large deviations and universality in quantum quenches

We study the large deviations statistics of the intensive work done by changing globally a control parameter in a thermally isolated quantum many-body system. We show that, upon approaching a critical point, large deviations well below the mean work display universal features related to the critical Casimir effect in the corresponding classical system. Large deviations well above the mean are, instead, of quantum nature and not captured by the quantum-to-classical correspondence. For a bosonic system we show that in this latter regime a transition from exponential to power-law statistics, analogous to the equilibrium Bose-Einstein condensation, may occur depending on the parameters of the quench and on the spatial dimensionality.

Quantum quenches as classical critical films

We study the unitary time evolution of the order parameter of a quantum system after a sudden quench in the parameter driving the transition. By mapping the dynamics onto the imaginary time path-integral in a film geometry we derive the full mean-field non-equilibrium phase diagram for a one-component order parameter. The recently discovered non-equilibrium transition is identified with the shifted critical point in films and therefore it is generally expected to occur in more than one spatial dimension. We also find that anharmonic oscillations of the order parameter are a general feature of the mean-field quench dynamics.

Critical Casimir forces steered by patterned substrates

Among the various kinds of effective forces in soft matter, the spatial range and the direction of the so-called critical Casimir force - which is generated by the enhanced thermal fluctuations close to a continuous phase transition - can be controlled and reversibly modified to an uncommonly large extent. In particular, minute temperature changes of the fluid solvent, which provides the near-critical thermal fluctuations, lead to a significant change of the range and strength of the effective interaction among the solute particles. This feature allows one to control, e.g., the aggregation of colloidal dispersions or the spatial distribution of colloids in the presence of chemically or topographically patterned substrates. The spatial direction of the effective force acting on a solute particle depends only on the surface properties of the immersed particles and can be spatially modulated by suitably patterned surfaces. These critical Casimir forces are largely independent of the specific materials properties of both the solvent and the confining surfaces. This characteristic universality of critical phenomena allows systematic and quantitative theoretical studies of the critical Casimir forces in terms of suitable representative and simplified models. Here we highlight recent theoretical and experimental advances concerning critical Casimir forces with a particular emphasis on the numerous possibilities of controlling these forces by substrate patterns.

Dynamic crossover in the persistence probability of manifolds at criticality

We investigate the persistence properties of critical d-dimensional systems relaxing from an initial state with non-vanishing order parameter (e.g., the magnetization in the Ising model), focusing on the dynamics of the global order parameter of a d-dimensional manifold. The persistence probability P(t) shows three distinct long-time decays depending on the value of the parameter zeta = (D-2+eta)/z which also controls the relaxation of the persistence probability in the case of a disordered initial state (vanishing order parameter) as a function of the codimension D = d-d and of the critical exponents z and eta. We find that the asymptotic behavior of P(t) is exponential for zeta > 1, stretched exponential for 0 <= zeta <= 1, and algebraic for zeta < 0. Whereas the exponential and stretched exponential relaxations are not affected by the initial value of the order parameter, we predict and observe a crossover between two different power-law decays when the algebraic relaxation occurs, as in the case d=d of the global order parameter. We confirm via Monte Carlo simulations our analytical predictions by studying the magnetization of a line and of a plane of the two- and three-dimensional Ising model, respectively, with Glauber dynamics. The measured exponents of the ultimate algebraic decays are in a rather good agreement with our analytical predictions for the Ising universality class. In spite of this agreement, the expected scaling behavior of the persistence probability as a function of time and of the initial value of the order parameter remains problematic. In this context, the non-equilibrium dynamics of the O(n) model in the limit n->infty and its subtle connection with the spherical model is also discussed in detail.

Colloidal aggregation and critical Casimir forces

A recent Letter [Phys. Rev. Lett. 103, 156101 (2009)] reports the experimental observation of aggregation of colloidal particles dispersed in a liquid mixture of heavy water and 3-methylpyridine. The experimental data are interpreted in terms of a model which accounts solely for the competing effects of the interparticle electrostatic repulsion and of the attractive critical Casimir force. Here we show, however, that the reported aggregation actually occurs within ranges of values of the correlation length and of the Debye screening length ruled out by the proposed model and that a significant part of the experimental data presented in the Letter cannot be consistently interpreted in terms of such a model.

The Casimir effect: from quantum to critical fluctuations

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum). A similar effect emerges in statistical physics, where the force acting, e.g., on colloidal particles immersed in a binary liquid mixture is affected by the classical thermal fluctuations occurring in the surrounding medium. The resulting Casimir-like force acquires universal features upon approaching a critical point of the medium and becomes long-ranged at criticality. In turn, this universality allows one to investigate theoretically the temperature dependence of the force via representative models and to stringently test the corresponding predictions in experiments. In contrast to QED, the Casimir force resulting from critical fluctuations can be easily tuned with respect to strength and sign by surface treatments and temperature control. We present some recent advances in the theoretical study of the universal properties of the critical Casimir force arising in thin films. The corresponding predictions compare very well with the experimental results obtained for wetting layers of various fluids. We discuss how the Casimir force between a colloidal particle and a planar wall immersed in a binary liquid mixture has been measured with femto-Newton accuracy, comparing these experimental results with the corresponding theoretical predictions.

Relaxation phenomena at criticality

The collective behaviour of statistical systems close to critical points is characterized by an extremely slow dynamics which, in the thermodynamic limit, eventually prevents them from relaxing to an equilibrium state after a change in the thermodynamic control parameters. The non-equilibrium evolution following this change displays some of the features typically observed in glassy materials, such as ageing, and it can be monitored via dynamic susceptibilities and correlation functions of the order parameter, the scaling behaviour of which is characterized by universal exponents, scaling functions, and amplitude ratios. This universality allows one to calculate these quantities in suitable simplified models and field-theoretical methods are a natural and viable approach for this analysis. In addition, if a statistical system is spatially confined, universal Casimir-like forces acting on the confining surfaces emerge and they build up in time when the temperature of the system is tuned to its critical value. We review here some of the theoretical results that have been obtained in recent years for universal quantities, such as the fluctuation-dissipation ratio, associated with the non-equilibrium critical dynamics, with particular focus on the Ising model with Glauber dynamics in the bulk. The non-equilibrium dynamics of the Casimir force acting in a film is discussed within the Gaussian model.