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Register a new userDust-gas chemistry in AGB outflows: Chemical modelling of dust-gas chemistry within AGB outflows I. Effect on the gas-phase chemistry
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Chemical modelling of AGB outflows is typically focused on either non-thermodynamic equilibrium chemistry in the inner region or photon-driven chemistry in the outer region. We include, for the first time, a comprehensive dust-gas chemistry in our AGB outflow chemical kinetics model, including both dust-gas interactions and grain-surface chemistry. The dust is assumed to have formed in the inner region, and follows an interstellar-like dust-size distribution. Using radiative transfer modelling, we obtain dust temperature profiles for different dust types in an O-rich and a C-rich outflow. We calculate a grid of models, sampling different outflow densities, drift velocities between the dust and gas, and dust types. Dust-gas chemistry can significantly affect the gas-phase composition, depleting parent and daughter species and increasing the abundance of certain daughter species via grain-surface formation followed by desorption/sputtering. Its influence depends on four factors: outflow density, dust temperature, initial composition, and drift velocity. The largest effects are for higher density outflows with cold dust and O-rich parent species, as these species generally have a larger binding energy. At drift velocities larger than $sim 10$ km s$^{-1}$, ice mantles undergo sputtering; however, they are not fully destroyed. Models with dust-gas chemistry can better reproduce the observed depletion of species in O-rich outflows. When including colder dust in the C-rich outflows and adjusting the binding energy of CS, the depletion in C-rich outflows is also better reproduced. To best interpret high-resolution molecular line observations from AGB outflows, dust-gas interactions are needed in chemical kinetics models.
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AGB stars are, together with supernovae, the main contributors of stellar dust to the interstellar medium (ISM). Dust grains formed by AGB stars are thought to be large. However, as dust nucleation and growth within their outflows are still not understood, the dust-grain size distribution (GSD) is unknown. This is an important uncertainty regarding our knowledge of the chemical and physical history of interstellar dust, as AGB dust forms $sim$ 70% of the starting point of its evolution. We expand on our chemical kinetics model, which uniquely includes a comprehensive dust-gas chemistry. The GSD is now allowed to deviate from the commonly assumed canonical Mathis et al. (1977) distribution. We find that the specific GSD can significantly influence the dust-gas chemistry within the outflow. Our results show that the level of depletion of gas-phase species depends on the average grain surface area of the GSD. Gas-phase abundance profiles and their possible depletions can be retrieved from observations of molecular emission lines when using a range of transitions. Due to degeneracies within the prescription of GSD, specific parameters cannot be retrieved, only (a lower limit to) the average grain surface area. Nonetheless, this can discriminate between dust composed of predominantly large or small grains. We show that when combined with other observables such as the spectral energy distribution and polarised light, depletion levels from molecular gas-phase abundance profiles can constrain the elusive GSD of the dust delivered to the ISM by AGB outflows.
To explain the properties of dust in the interstellar medium (ISM), the presence of a refractory organic mantle is necessary. The outflows of AGB stars are among the main contributors of stellar dust to the ISM. We present the first study of the refractory organic contribution of AGB stars to the ISM. Based on laboratory experiments, we included a new reaction in our extended chemical kinetics model: the photoprocessing of volatile complex ices into inert refractory organic material. The refractory organic feedback of AGB outflows to the ISM is estimated using observationally motivated parent species and grids of models of C-rich and O-rich outflows. Refractory organic material is mainly inherited from the gas phase through accretion onto the dust and subsequent photoprocessing. Grain-surface chemistry, initiated by photodissociation of ices, produces only a minor part and takes place in a sub-monolayer regime in almost all outflows. The formation of refractory organic material increases with outflow density and depends on the initial gas-phase composition. While O-rich dust is negligibly covered by refractory organics, C-rich dust has an average coverage of $3-9%$, but can be as high as $8-22%$. Although C-rich dust does not enter the ISM bare, its average coverage is too low to influence its evolution in the ISM or significantly contribute to the coverage of interstellar dust. This study opens up questions on the coverage of other dust-producing environments. It highlights the need for an improved understanding of dust formation and for models specific to density structures within the outflow.
We study the evolution of extremely metal-poor AGB stars, with metallicities down to [Fe/H]=-5, to understand the main evolutionary properties, the efficiency of the processes able to alter their surface chemical composition and to determine the gas and dust yields. We calculate two sets of evolutionary sequences of stars in the 1-7.5Msun mass range, evolved from the pre-main sequence to the end of the AGB phase. To explore the extremely metal-poor chemistries we adopted the metallicities Z=3x10^{-5} and Z=3x10^{-7} which correspond, respectively to [Fe/H]=-3 and [Fe/H]=-5. The results from stellar evolution modelling are used to calculate the yields of the individual chemical species. We also modelled dust formation in the wind, to determine the dust produced by these objects. The evolution of AGB stars in the extremely metal-poor domain explored here proves tremendously sensitive to the initial mass of the star. M<2Msun stars experience several third dredge-up events, which favour the gradual surface enrichment of C12 and the formation of significant quantities of carbonaceous dust, of the order of 0.01Msun. The C13 and nitrogen yiel are found to be significantly smaller than in previous explorations of low-mass, metal-poor AGB stars, owing to the weaker proton ingestion episodes experienced during the initial AGB phases. M>5Msun stars experience hot bottom burning and their surface chemistry reflects the equilibria of a very advanced proton-capture nucleosynthesis; little dust production takes place in their wind. Intermediate mass stars experience both third dredge-up and hot bottom burning: they prove efficient producers of nitrogen, which is formed by proton captures on C12 nuclei of primary origin dredged-up from the internal regions.
Context. Water together with O2 are important gas phase ingredients to cool dense gas in order to form stars. On dust grains, H2 O is an important constituent of the icy mantle in which a complex chemistry is taking place, as revealed by hot core observations. The formation of water can occur on dust grain surfaces, and can impact gas phase composition. Aims. The formation of molecules such as OH, H2 O, HO2, H2 O2, as well as their deuterated forms and O2 and O3 is studied in order to assess how the chemistry varies in different astrophysical environments, and how the gas phase is affected by grain surface chemistry. Methods. We use Monte Carlo simulations to follow the formation of molecules on bare grains as well as the fraction of molecules released into the gas phase. We consider a surface reaction network, based on gas phase reactions, as well as UV photo-dissociation of the chemical species. Results. We show that grain surface chemistry has a strong impact on gas phase chemistry, and that this chemistry is very different for different dust grain temperatures. Low temperatures favor hydrogenation, while higher temperatures favor oxygenation. Also, UV photons dissociate the molecules on the surface, that can reform subsequently. The formation-destruction cycle increases the amount of species released into the gas phase. We also determine the time scales to form ices in diffuse and dense clouds, and show that ices are formed only in shielded environments, as supported by observations.
We present asymptotic giant branch (AGB) models of metallicity $Z=10^{-4}$ and $Z=3times 10^{-4}$, with the aim of understanding how the gas enrichment and the dust production change in very metal-poor environments and to assess the general contribution of AGB stars to the cosmic dust yield. The stellar yields and the dust produced are determined by the change in the surface chemical composition, with a transition occurring at $sim 2.5~M_{odot}$. Stars of mass $M < 2.5~M_{odot}$ reach the carbon stage and produce carbon dust, whereas their higher mass counterparts produce mainly silicates and alumina dust; in both cases the amount of dust manufactured decreases towards lower metallicities. The $Z=10^{-4}$ models show a complex and interesting behaviour on this side, because the efficient destruction of the surface oxygen favours the achievement of the C-star stage, independently of the initial mass. The present results might indicate that the contribution from this class of stars to the overall dust enrichment in metal-poor environments is negligible at redshifts $z>5$.
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