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Register a new userChemical modelling of dust-gas chemistry within AGB outflows III. Photoprocessing of the ice and return to the ISM
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To explain the properties of dust in the interstellar medium (ISM), the presence of a refractory organic mantle is necessary. The outflows of AGB stars are among the main contributors of stellar dust to the ISM. We present the first study of the refractory organic contribution of AGB stars to the ISM. Based on laboratory experiments, we included a new reaction in our extended chemical kinetics model: the photoprocessing of volatile complex ices into inert refractory organic material. The refractory organic feedback of AGB outflows to the ISM is estimated using observationally motivated parent species and grids of models of C-rich and O-rich outflows. Refractory organic material is mainly inherited from the gas phase through accretion onto the dust and subsequent photoprocessing. Grain-surface chemistry, initiated by photodissociation of ices, produces only a minor part and takes place in a sub-monolayer regime in almost all outflows. The formation of refractory organic material increases with outflow density and depends on the initial gas-phase composition. While O-rich dust is negligibly covered by refractory organics, C-rich dust has an average coverage of $3-9%$, but can be as high as $8-22%$. Although C-rich dust does not enter the ISM bare, its average coverage is too low to influence its evolution in the ISM or significantly contribute to the coverage of interstellar dust. This study opens up questions on the coverage of other dust-producing environments. It highlights the need for an improved understanding of dust formation and for models specific to density structures within the outflow.
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Chemical modelling of AGB outflows is typically focused on either non-thermodynamic equilibrium chemistry in the inner region or photon-driven chemistry in the outer region. We include, for the first time, a comprehensive dust-gas chemistry in our AGB outflow chemical kinetics model, including both dust-gas interactions and grain-surface chemistry. The dust is assumed to have formed in the inner region, and follows an interstellar-like dust-size distribution. Using radiative transfer modelling, we obtain dust temperature profiles for different dust types in an O-rich and a C-rich outflow. We calculate a grid of models, sampling different outflow densities, drift velocities between the dust and gas, and dust types. Dust-gas chemistry can significantly affect the gas-phase composition, depleting parent and daughter species and increasing the abundance of certain daughter species via grain-surface formation followed by desorption/sputtering. Its influence depends on four factors: outflow density, dust temperature, initial composition, and drift velocity. The largest effects are for higher density outflows with cold dust and O-rich parent species, as these species generally have a larger binding energy. At drift velocities larger than $sim 10$ km s$^{-1}$, ice mantles undergo sputtering; however, they are not fully destroyed. Models with dust-gas chemistry can better reproduce the observed depletion of species in O-rich outflows. When including colder dust in the C-rich outflows and adjusting the binding energy of CS, the depletion in C-rich outflows is also better reproduced. To best interpret high-resolution molecular line observations from AGB outflows, dust-gas interactions are needed in chemical kinetics models.
AGB stars are, together with supernovae, the main contributors of stellar dust to the interstellar medium (ISM). Dust grains formed by AGB stars are thought to be large. However, as dust nucleation and growth within their outflows are still not understood, the dust-grain size distribution (GSD) is unknown. This is an important uncertainty regarding our knowledge of the chemical and physical history of interstellar dust, as AGB dust forms $sim$ 70% of the starting point of its evolution. We expand on our chemical kinetics model, which uniquely includes a comprehensive dust-gas chemistry. The GSD is now allowed to deviate from the commonly assumed canonical Mathis et al. (1977) distribution. We find that the specific GSD can significantly influence the dust-gas chemistry within the outflow. Our results show that the level of depletion of gas-phase species depends on the average grain surface area of the GSD. Gas-phase abundance profiles and their possible depletions can be retrieved from observations of molecular emission lines when using a range of transitions. Due to degeneracies within the prescription of GSD, specific parameters cannot be retrieved, only (a lower limit to) the average grain surface area. Nonetheless, this can discriminate between dust composed of predominantly large or small grains. We show that when combined with other observables such as the spectral energy distribution and polarised light, depletion levels from molecular gas-phase abundance profiles can constrain the elusive GSD of the dust delivered to the ISM by AGB outflows.
Aims. Formamide (HCONH2) is the simplest molecule containing the peptide bond first detected in the gas phase in Orion-KL and SgrB2. In recent years, it has been observed in high temperature regions such as hot corinos, where thermal desorption is responsible for the sublimation of frozen mantles into the gas phase. The interpretation of observations can benefit from information gathered in the laboratory, where it is possible to simulate the thermal desorption process and to study formamide under simulated space conditions such as UV irradiation. Methods. Here, two laboratory analyses are reported: we studied formamide photo-stability under UV irradiation when it is adsorbed by space relevant minerals at 63 K and in the vacuum regime. We also investigated temperature programmed desorption of pure formamide ice in the presence of TiO2 dust before and after UV irradiation. Results. Through these analyses, the effects of UV degradation and the interaction between formamide and different minerals are compared.We find that silicates, both hydrates and anhydrates, offer molecules a higher level of protection from UV degradation than mineral oxides. The desorption temperature found for pure formamide is 220 K. The desorption temperature increases to 250 K when the formamide desorbs from the surface of TiO2 grains. Conclusions. Through the experiments outlined here, it is possible to follow the desorption of formamide and its fragments, simulate the desorption process in star forming regions and hot corinos, and constrain parameters such as the thermal desorption temperature of formamide and its fragments and the binding energies involved. Our results offer support to observational data and improve our understanding of the role of the grain surface in enriching the chemistry in space.
The most metal-poor, high redshift damped Lyman-alpha systems (DLAs) provide a window to study some of the first few generations of stars. In this paper, we present a novel model to investigate the chemical enrichment of the near-pristine DLA population. This model accounts for the mass distribution of the enriching stellar population, the typical explosion energy of their supernovae, and the average number of stars that contribute to the enrichment of these DLAs. We conduct a maximum likelihood analysis of these model parameters using the observed relative element abundances ([C/O], [Si/O], and [Fe/O]) of the 11 most metal-poor DLAs currently known. We find that the mass distribution of the stars that have enriched this sample of metal-poor DLAs can be well-described by a Salpeter-like IMF slope at M > 10 M_sun and that a typical metal-poor DLA has been enriched by < 72 massive stars (95 per cent confidence), with masses < 40 M_sun. The inferred typical explosion energy (E_exp = 1.8^{+0.3}_{-0.2}x10^51 erg) is somewhat lower than that found by recent works that model the enrichment of metal-poor halo stars. These constraints suggest that some of the metal-poor DLAs in our sample may have been enriched by Population II stars. Using our enrichment model, we also infer some of the typical physical properties of the most metal-poor DLAs. We estimate that the total stellar mass content is log10(M_*/M_sun) = 3.5^{+0.3}_{-0.4} and the total gas mass is log10(M_gas/M_sun) = 7.0^{+0.3}_{-0.4} for systems with a relative oxygen abundance [O/H] ~ -3.0.
We study the evolution of extremely metal-poor AGB stars, with metallicities down to [Fe/H]=-5, to understand the main evolutionary properties, the efficiency of the processes able to alter their surface chemical composition and to determine the gas and dust yields. We calculate two sets of evolutionary sequences of stars in the 1-7.5Msun mass range, evolved from the pre-main sequence to the end of the AGB phase. To explore the extremely metal-poor chemistries we adopted the metallicities Z=3x10^{-5} and Z=3x10^{-7} which correspond, respectively to [Fe/H]=-3 and [Fe/H]=-5. The results from stellar evolution modelling are used to calculate the yields of the individual chemical species. We also modelled dust formation in the wind, to determine the dust produced by these objects. The evolution of AGB stars in the extremely metal-poor domain explored here proves tremendously sensitive to the initial mass of the star. M<2Msun stars experience several third dredge-up events, which favour the gradual surface enrichment of C12 and the formation of significant quantities of carbonaceous dust, of the order of 0.01Msun. The C13 and nitrogen yiel are found to be significantly smaller than in previous explorations of low-mass, metal-poor AGB stars, owing to the weaker proton ingestion episodes experienced during the initial AGB phases. M>5Msun stars experience hot bottom burning and their surface chemistry reflects the equilibria of a very advanced proton-capture nucleosynthesis; little dust production takes place in their wind. Intermediate mass stars experience both third dredge-up and hot bottom burning: they prove efficient producers of nitrogen, which is formed by proton captures on C12 nuclei of primary origin dredged-up from the internal regions.
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