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Thermodynamic Properties and Elementary Excitations in Quantum Sine-Gordon Spin System KCuGaF6

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 Added by Toshio Ono
 Publication date 2007
  fields Physics
and research's language is English




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Thermodynamic properties and elementary excitations in $S=1/2$ one-dimensional Heisenberg antiferromagnet KCuGaF$_6$ were investigated by magnetic susceptibility, specific heat and ESR measurements. Due to the Dzyaloshinsky-Moriya interaction with alternating $D$-vectors and/or the staggered $g$-tensor, the staggered magnetic field is induced when subjected to external magnetic field. Specific heat in magnetic field clearly shows the formation of excitation gap, which is attributed to the staggered magnetic field. The specific heat data was analyzed on the basis of the quantum sine-Gordon (SG) model. We observed many ESR modes including one soliton and three breather excitations characteristic of the quantum SG model.



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The material copper pyrimidine dinitrate (Cu-PM) is a quasi-one-dimensional spin system described by the spin-1/2 XXZ Heisenberg antiferromagnet with Dzyaloshinskii-Moriya interactions. Based on numerical results obtained by the density-matrix renormalization group, exact diagonalization, and accompanying electron spin resonance (ESR) experiments we revisit the spin dynamics of this compound in an applied magnetic field. Our calculations for momentum and frequency-resolved dynamical quantities give direct access to the intensity of the elementary excitations at both zero and finite temperature. This allows us to study the system beyond the low-energy description by the quantum sine-Gordon model. We find a deviation from the Lorentz invariant dispersion for the single-soliton resonance. Furthermore, our calculations only confirm the presence of the strongest boundary bound state previously derived from a boundary sine-Gordon field theory, while composite boundary-bulk excitations have too low intensities to be observable. Upon increasing the temperature, we find a temperature-induced crossover of the soliton and the emergence of new features, such as interbreather transitions. The latter observation is confirmed by our ESR experiments on Cu-PM over a wide range of the applied field.
We report the results of muon-spin spectroscopy ($mu^+$SR) measurements on the staggered molecular spin chain [pym-Cu(NO$_3$)$_2$(H$_2$O)$_2$] (pym = pyrimidine), a material previously described using sine-Gordon field theory. Zero-field $mu^+$SR reveals a long range magnetically-ordered ground state below a transition temperature $T_mathrm{N}=0.22(1)$ K. Using longitudinal-field (LF) $mu^+$SR we investigate the dynamic response in applied magnetic fields $0< B < 500$ mT and find evidence for ballistic spin transport. Our LF $mu^+$SR measurements on the chiral spin chain [Cu(pym)(H$_2$O)$_4$]SiF$_6 cdot $H$_2$O instead demonstrate one-dimensional spin diffusion and the distinct spin transport in these two systems likely reflects differences in their magnetic excitations.
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